Search Results (68)

Transport and vehicle traffic are closely connected with particulate matter (PM) pollution, inducing various fractions into the atmosphere, some of them forming significant deposits on the surface of the car. They are washed away during carwash-inducing slurries collecting the PM deposits, which are characteristic of a large area. Crystalline PM matter was investigated by XRD coupled with polarized optical microscopy (POM). Organic matters were investigated by Fourier-Transform Infrared spectrometry (FTIR) and gas chromatography, GC-MS. Their microstructure and elemental composition were investigated by SEM-EDX. The crystalline features contain mainly quartz, calcite, and clay (muscovite and kaolinite) particles having traces of goethite and lepidocrocite. Slurry particle size distribution was established by sieving on the following meshes: 63 µm, 125 µm, 250 µm, 500 µm, 1000 µm, 2000 µm, and 4000 µm. Coarse fractions of 250–4000 μm are dominated by quartz and calcite particles. The quartz and calcite amount decreases with particle size, while the muscovite and kaolinite amount increases in the finest fractions of 0–125 μm. Organic matter was evidenced, firstly, by FTIR spectroscopy, revealing mostly CH₂; C=O, and NH₄ bonds that are more intense for the fine particulate fractions. The organic deposits form mainly amorphous crusts associated with micro- and nano-plastic particles related to the phthalates and traces of the washing detergents. Atomic Force Microscopy revealed their size range between 60 and 90 nm and evidenced nanoparticles within samples. The nanofractions adhere to the bigger particles in humid environments, assuring their immobilization to reduce their hazardous potential. Carwash slurry blending with fertile soil ensures proper grass seed germination and growth at mixtures of up to 60% slurry, allowing its sustainable reconversion as soil for landfill and dump rehabilitation, preventing the PM emission hazard. Blended compositions containing more than 60% slurry have noxious effects on the grass seeds, inhibiting their germination. Full article

The first member of the Qingshankou Formation (Qing Member 1) is rich in oil and gas resources and represents the first lacustrine transgression period, during which the lake basin area reached its maximum. This study utilizes major and trace element analyses, along with pyrolysis, to investigate the sedimentary environment and mechanisms of organic matter enrichment in the hydrocarbon source rocks of the Heiyupao Depression Qing Member 1. The results indicate that the hydrocarbon source rocks in this area exhibit good to excellent organic richness, mainly comprising Type I and Type II₁ organic matter, and are at a high stage of maturity. Furthermore, the paleoclimate conditions during the Qing Member 1 period in the study area were characterized by a warm and humid climate, with an open lake basin and freshwater to brackish water conditions. The water was low in oxygen, suboxic to anoxic, and had relatively high primary productivity. Multiple marine transgressions occurred during the Qing Member 1, transporting substantial nutrients into the lake, which promoted algal blooms in the water. The correlation analysis of TOC content in the Qing Member 1 shale and various indicators shows that the enrichment of organic matter in the study area is primarily influenced by paleoproductivity and paleosalinity, while paleoclimate, paleoredox conditions, and paleowater are not the main controlling factors for organic matter enrichment in the area. Organic matter only accumulates under relatively high salinity and paleoproductivity conditions. Event-driven marine transgressions also play an essential role in enhancing paleoproductivity. Therefore, the organic matter enrichment model in the study area is more aligned with a productivity-driven model. Finally, a comprehensive organic matter enrichment model of hydrocarbon source rocks in the Qing Member 1 of the Heiyupao Depression is proposed. Full article

The clay mineralogy and major and trace element geochemistry of the sediments deposited at the lower reaches of 90 medium and minor rivers from five states along the west coast of India indicate distinct clay mineral assemblages in the Archean–Proterozoic (A-P) terrain and Deccan Trap (DT) terrain. The sediments from A-P terrain are dominated by kaolinite, with minor illite and gibbsite and traces of goethite, and those from DT terrain are dominated by smectite with minor illite, kaolinite and chlorite. The sediments are depleted of Si, Ca, Mg, Na and K relative to those of Post-Archean average Australian Shale. The SiO₂/Al₂O₃ ratio of the sediments suggests lateritic soils in the A-P terrain and non-lateritic, chemically weathered soils in the DT terrain. Weathering indices indicate strong weathering in the clay fractions of all sediments. The silt fractions of sediments from Goa, Maharashtra and Gujarat exhibit intermediate to weak weathering and influence by hydraulic sorting processes and source rock characteristics. The total trace element content (∑TE) was higher in the silt fractions than in clay fractions of all sediments, and peaks of high ∑TE occur in the silt fractions of Kerala and Maharashtra. The silt fractions exhibit relatively high Th, U, La, Zr and Hf from A-P terrain, and high Sc, Cr, Co, Ni, V and Ga from DT terrain. The Th/U and Rb/Sr ratios are controlled by the intensity of weathering and lithology of source rocks. The standard plots using trace elements reveal that the clay fractions of sediments are more mafic from both the terrains, while silt fractions exhibit intermediate provenance between felsic and mafic sources. Since mafic component-dominated clays are transported to the adjacent seas and oceans, it would be a challenge to identify the provenance of clays from granitic terrain in the oceans using trace element chemistry. Full article

Carbon capture, utilization and storage are facilitated through carbon dioxide (CO₂) transport. Pipe transportation is the main method for transporting CO₂. However, hydrate blockages reduce transport efficiency in the pipelines, and the throttling devices are the main location of hydrate blockages. In this paper, the mechanism of hydrate formation in the throttling of CO₂-containing trace moisture was investigated. The throttling device in a pipe was mimicked using a cylindrical orifice plate. The work also studied the effects of moisture content, upstream pressure and upstream temperature on hydrate formation. The results indicate that the Joule–Thomson cooling effect is a key contributor, and promotes the condensation of trace moisture, resulting in the free water necessary for hydrate nucleation. Under the effect of gas flow back-mixing, it is easy for the hydrate to adhere to the inner surface of the pipe behind the orifice plate. When the moisture content in the gas increases from 123 μmol/mol to 1024 μmol/mol, the hydrate induction time decreases from infinity to 792 s. However, the moisture content has no effect on the adhesion strength of the hydrate to the inner surface of the pipe. When the initial upstream pressure increases from 2.0 MPa to 3.5 MPa, the hydrate induction time decreases from infinity to 306 s. When the upstream temperature decreases from 291.15 K to 285.15 K, the hydrate induction time decreases from infinity to 330 s. With the decrease in the initial upstream temperature, the adhesion of hydrate particles to the inner surface of the pipe is promoted. This study provides experimental evidence for the characteristics of hydrate formation in the process of CO₂ throttling. Full article

The ability of bacteria to recycle exogenous amino acid-based peptides and amino sugars for peptidoglycan biosynthesis was extensively investigated using optical imaging. In particular, fluorescent AeK–NBD was effectively utilized to study the peptidoglycan recycling pathway in Gram-negative bacteria. Based on these promising results, we were inspired to develop the radioactive AeK conjugate [⁶⁸Ga]Ga-DOTA-AeK for the in vivo localization of bacterial infection using PET/CT. An easy-to-implement radiolabeling procedure for DOTA-AeK with [⁶⁸Ga]GaCI₃ followed by solid-phase purification was successfully established to obtain [⁶⁸Ga]Ga-DOTA-AeK with a radiochemical purity of ≥95%. [⁶⁸Ga]Ga-DOTA-AeK showed good stability over time with less protein binding under physiological conditions. The bacterial incorporation of [⁶⁸Ga]Ga-DOTA-AeK and its fluorescent Aek-NBD analog were investigated in live and heat-killed Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Unfortunately, no conclusive in vitro intracellular uptake of [⁶⁸Ga]Ga-DOTA-AeK was observed for E. coli or S. aureus live and heat-killed bacterial strains (p > 0.05). In contrast, AeK-NBD showed significantly higher intracellular incorporation in live bacteria compared to the heat-killed control (p < 0.05). Preliminary biodistribution studies of [⁶⁸Ga]Ga-DOTA-AeK in a dual-model of chronic infection and inflammation revealed limited localization at the infection site with non-specific accumulation in response to inflammatory markers. Finally, our study demonstrates proof that the intracellular incorporation of AeK is necessary for successful bacteria-specific imaging using PET/CT. Therefore, Ga-68 was not a suitable radioisotope for tracing the bacterial uptake of AeK tripeptide, as it required chelation with a bulky metal chelator such as DOTA, which may have limited its active membrane transportation. An alternative for optimization is to explore diverse chemical structures of AeK that would allow for radiolabeling with ¹⁸F or ¹¹C. Full article

In this study, a decentralized incineration facility was evaluated over a three-year period, focusing on performance aspects, such as the burning rate, ash production, fuel and electricity consumption, and ash composition, while processing animal by-products (ABPs). The total cost for ABP incineration was determined to be EUR 159 t⁻¹ ABP, with the major components being capital depreciation (42%), maintenance expenditures (26%), labor (18%), and transportation costs (9%). Liquified petroleum gas consumption ranged from 3 to 7 kg t⁻¹, while electricity use was between 15 and 20 kWh t⁻¹ incinerated ABP. The incineration process generated 7–10% (by weight) ABP ash, which was characterized by high calcium and phosphorus contents and low levels of hazardous trace elements. Leaching tests demonstrated the potential for recovering an alkaline supernatant for flue gas treatment and a phosphorus-rich slurry for fertilizer production. The findings suggest that energy recovery and valorization are crucial for minimizing the operational costs and the environmental impact, emphasizing the benefits of integrating advanced resource recovery techniques in ABP incineration facilities. Full article

This study leveraged 2019 online data of particulate matter (PM_2.5) and volatile organic compounds (VOCs) in Tianjin to analyze atmospheric pollution characteristics. PM_2.5 was found to be primarily composed of water-soluble ions, with nitrates as the dominant component, while VOCs were predominantly alkanes, followed by alkenes and aromatic hydrocarbons, with notable concentrations of propane, ethane, ethylene, toluene, and benzene. The receptor model identified six major sources of PM_2.5 and seven major sources of VOCs. The secondary source is the main contribution source, while motor vehicles and coal burning are important primary contribution sources in PM_2.5. And, industrial processes and natural gas volatilization were considered major contributors for VOCs. A health risk assessment indicated negligible non-carcinogenic risks but potential carcinogenic risks from trace metals As and Cr, and benzene within VOCs, underscoring the necessity for focused public health measures. A risk attribution analysis attributed As and Cr in PM to coal combustion and vehicular emissions. Benzene in VOCs primarily originates from fuel evaporation, and industrial and vehicular emissions. These findings underscore the potential for reducing health risks from PM and VOCs through enhanced regulation of emissions in coal, industry, and transportation. Such strategies are vital for advancing air quality management and safeguarding public health. Full article

Kaffir lime juice, often treated as production waste, can be a good source of terpenes. These compounds undergo various decomposition processes under the influence of external factors, especially during transportation and storage. In this paper, it was possible to monitor changes in the terpene profile of kaffir lime juice under different storage conditions, namely, 4 °C, 20 °C, and 35 °C. The identification of key decomposition products was achieved using gas chromatography–mass spectrometry (GC–MS) and a data mining protocol. It was followed by tracing those products in different storage conditions using a high-throughput proton transfer reaction mass spectrometry (PTR–MS) approach. Based on our findings, degradation pathways were presented, showing that the main products resulting from storage are p-cymene, p-cymenene, terpinene-4-ol, and α-terpineol. It was shown that conversion to p-cymenene occurs after 5 days of storage. Terpinene-4-ol and α-terpineol were found to be the final products of the conversion at all temperatures. Changes in the composition of terpenes are important from the point of view of their bioactive properties. Full article

The destructionof clouds by strong shocks and hot winds is the key process responsible for the transporting of metals and dust from the ISM to the ICM/IGM, and establishing the multiphase structure in and around galaxies. In this work, we perform a detailed analysis of this process using two different approaches for tracking the cloud material (gas and dust): the so-called ‘colored’ fluid, and the Lagrangian (trace) particles. We find that for the clouds in the hot phase ($T>{10}^5$ K), the two methods produce significantly different mass fractions and velocities of the cloud material. In contrast, the two methods produce similar results for the clouds that are in the warm/cold phases ($T<{10}^5$ K). We find that the Kelvin–Helmholtz instability is suppressed in the warm clouds of size ∼100 pc and metallicity Z> 0.1Z$duetoeffectivegascooling.ThiscausesadelayinthedestructionofsuchcloudsthatareinteractingwiththehotICMflow.Wedemonstratethatthedustparticlesthatareevacuatedfromtheir‘parent’cloudstothehotmediumshowdifferentdynamicswhencomparedtothatoftheLagrangian\left(trace\right)particles.Ourresultsindicatethatthedustgrainssweptouttothehotgasaredestroyed.$ Full article

Biogas produced by anaerobic digestion contains different types of contaminants, and it is preferable to eliminate those contaminants before biogas’ energetic valorization or upgrading to biomethane as they are harmful to human health and detrimental to combustion engines. This study presents the biogas cleanup system optimized by an Italian full-scale anaerobic digester treating food waste (FW) and represented by micro-oxygenation, chemical scrubber, cooling, and activated carbon sections. The cleaned biogas is upgraded to biomethane using a membrane-based upgrading unit and injected into the natural gas network for transport sector use. H₂S and volatile organic compound (VOC) concentration in raw biogas was reduced from an annual average value of 1207 ppm_v and 895 mg/Nm³, respectively, to below 0.1 mg/Nm³ in the final biomethane. In the summer, the H₂S average content in raw biogas was 833 ppm_v due to a greater presence of low-sulfur-containing vegetables in FW, while in the winter it was an average of 1581 ppm_v due to a larger portion of protein-containing FW. On the other hand, raw biogas VOC content in the winter was an average of 1149 mg/Nm³, with respect to 661 mg/Nm³ in the summer, due to the greater consumption of citrus fruits containing high amount of terpene compounds. The concentration of other trace contaminants, such as HCl, NH_3, and siloxanes, was lowered from 17, 36, and 0.6 mg/Nm³ in raw biogas, respectively, to below 0.1 mg/Nm³ in the final biomethane. All the considerations and evaluations underlying the technological and plant engineering choices together with the individuation of the best operating conditions are discussed. Full article

DNA analysis of traces from commonly found objects like knives, smartphones, tapes and garbage bags related to crime in aquatic environments is challenging for forensic DNA laboratories. The amount of recovered DNA may be affected by the water environment, time in the water, method for recovery, transport and storage routines of the objects before the objects arrive in the laboratory. The present study evaluated the effect of four storage conditions on the DNA retrieved from bloodstains, touch DNA, fingerprints and hairs, initially deposited on knives, smartphones, packing tapes, duct tapes and garbage bags, and submerged in lake water for three time periods. After retrieval, the objects were stored either through air-drying at room temperature, freezing at −30 °C, in nitrogen gas or in lake water. The results showed that the submersion time strongly influenced the amount and degradation of DNA, especially after the longest submersion time (21 days). A significant variation was observed in success for STR profiling, while mtDNA profiling was less affected by the submersion time interval and storage conditions. This study illustrates that retrieval from water as soon as possible and immediate storage through air-drying or freezing before DNA analysis is beneficial for the outcome of DNA profiling in crime scene investigations. Full article

The fossil fuel crisis is a major concern across the globe, and fossil fuels are being exhausted day by day. It is essential to promptly change from fossil fuels to renewable energy resources for transportation applications as they make a major contribution to fossil fuel consumption. Among the available energy resources, a fuel cell is the most affordable for transportation applications because of such advantages as moderate operating temperature, high energy density, and scalable size. It is a challenging task to optimize PEMFC operating parameters for the enhancement of performance. This paper provides a detailed study on the optimization of PEMFC operating parameters using a multilayer feed-forward neural network, a genetic algorithm, and the design of a multiport high-gain DC–DC converter for hybrid electric vehicle application, which is capable of handling both a 6 kW PEMFC and an 80 AH 12 V heavy-duty battery. To trace the maximum power from the PEMFC, the most recent SFO-based MPPT control technique is implemented in this research work. Initially, a multilayer feed-forward neural network is trained using a back-propagation algorithm with experimental data. Then, the optimization phase is separately carried out in a neural-power software environment using a genetic algorithm (GA). The simulation study was carried out using the MATLAB/R2022a platform to verify the converter performance along with the SFO-based MPPT controller. To validate the real-time test bench results, a 0.2 kW prototype model was constructed in the laboratory, and the results were verified. Full article

The Red Sea, a significant ecoregion and vital marine transportation route, has experienced a consistent rise in air pollution in recent years. Hence, it is imperative to assess the spatial and temporal distribution of air quality parameters across the Red Sea and identify temporal trends. This study concentrates on utilizing multiple satellite observations to gather diverse meteorological data and vertical tropospheric columns of aerosols and trace gases, encompassing carbon monoxide (CO), nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and ozone (O₃). Furthermore, the study employs the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to analyze the backward trajectory of air mass movement, aiding in the identification of significant sources of air pollutants. A principal component analysis (PCA) with varimax rotation is applied to explore the relationship and co-variance between the aerosol index (AI), trace gas concentrations, and meteorological data. The investigation reveals seasonal and regional patterns in the tropospheric columns of trace gases and AI over the Red Sea. The correlation analysis indicates medium-to-low positive correlations (0.2 < r < 0.6) between air pollutants (NO₂, SO₂, and O₃) and meteorological parameters, while negative correlations (−0.3 < r < −0.7) are observed between O₃, aerosol index, and wind speed. The results from the HYSPLIT model unveil long-range trajectory patterns. Despite inherent limitations in satellite observations compared to in situ measurements, this study provides an encompassing view of air pollution across the Red Sea, offering valuable insights for future researchers and policymakers. Full article

In this work, a reliable and robust in situ non-matrix-matched calibration method is proposed for element composition determination in scheelite samples. With external calibration against the silicate glass standard reference material NIST SRM 610, the concentrations of both major elements (Ca and W) and trace elements (Si, Fe, Mo, Y, rare earth elements, etc.) in scheelite are determined using an ArF 193 nm excimer nanosecond laser ablation-inductively coupled plasma mass spectrometer (LA-ICP-MS). Here, the ablation was performed by hole drilling under a helium (He) environment using a laser spot size of 35 μm and a laser repetition of 5 Hz, and the aerosols were then transported to a quadrupole ICP-MS by a mixture of He and make-up gas argon (Ar) with a total gas flow rate of 1.6 L/min. Results showed that there was no apparent matrix effect between the NIST SRM 610 and scheelite by this proposed method. With internal standardization against W, the obtained concentrations of CaO and WO₃ were found to yield an average matrix CaO/WO₃ mass fraction ratio of 0.245 (2σ = 0.003, n = 19), which agreed well with the value of 0.243 (2σ = 0.002, n = 15) from electron probe microanalysis (EPMA). Furthermore, the accuracy of trace element analyses with this proposed non-matrix-matched calibration in situ method was evaluated by comparing the concentration results with those from bulk analysis by solution nebulizer ICP-MS (SN-ICP-MS). It was found that the quantification results from LA-ICP-MS and SN-ICP-MS were comparable, in particular showing a relative concentration bias of the total ∑REE+Y contents of less than 2%. This confirmed that scheelites can be accurately analyzed in situ by LA-ICP-MS without matrix-matched calibration standards. By using this developed in situ method, the element compositions in a series of scheelite samples from different W-associated deposits in China were successfully quantified, promising further genetic process investigation and associated geologic activities of the polymetallic resources. Full article

Raman spectroscopy is a type of inelastic scattering that provides rich information about a substance based on the coupling of the energy levels of their vibrational and rotational modes with an incident light. It has been applied extensively in many fields. As there is an increasing need for the remote detection of chemicals in planetary exploration and anti-terrorism, it is urgent to develop a compact, easily transportable, and fully automated remote Raman detection system for trace detection and identification of information, with high-level confidence about the target’s composition and conformation in real-time and for real field scenarios. Here, we present an unmanned vehicle-based remote Raman system, which includes a 266 nm air-cooling passive Q-switched nanosecond pulsed laser of high-repetition frequency, a gated ICMOS, and an unmanned vehicle. This system provides good spectral signals from remote distances ranging from 3 m to 10 m for simulating realistic scenarios, such as aluminum plate, woodblock, paperboard, black cloth, and leaves, and even for detected amounts as low as 0.1 mg. Furthermore, a convolutional neural network (CNN)-based algorithm is implemented and packaged into the recognition software to achieve faster and more accurate detection and identification. This prototype offers a proof-of-concept for an unmanned vehicle with accurate remote substance detection in real-time, which can be helpful for remote detection and identification of hazardous gas, explosives, their precursors, and so forth. Full article