Search Results (170)

Particle accelerators are powerful tools in fundamental research, medicine, and industry that provide high-energy beams that can be used to study matter and to enable advanced applications. The state-of-the-art particle accelerators are fundamentally constructed from superconducting radio-frequency (SRF) cavities, which act as resonant structures for the acceleration of charged particles. The performance of such cavities is governed by inherent superconducting material properties such as the transition temperature, critical fields, penetration depth, and other related parameters and material quality. For the last few decades, bulk niobium has been the preferred material for SRF cavities, enabling accelerating gradients on the order of ~50 MV/m; however, its intrinsic limitations, high cost, and complicated manufacturing have motivated the search for alternative strategies. Among these, sputter-deposited superconducting thin films offer a promising route to address these challenges by reducing costs, improving thermal stability, and providing access to numerous high-T_c superconductors. This review focuses on progress in sputtered superconducting materials for SRF applications, in particular Nb, NbN, NbTiN, Nb₃Sn, Nb₃Al, V₃Si, Mo–Re, and MgB₂. We review how deposition process parameters such as deposition pressure, substrate temperature, substrate bias, duty cycle, and reactive gas flow influence film microstructure, stoichiometry, and superconducting properties, and link these to RF performance. High-energy deposition techniques, such as HiPIMS, have enabled the deposition of dense Nb and nitride films with high transition temperatures and low surface resistance. In contrast, sputtering of Nb₃Sn offers tunable stoichiometry when compared to vapour diffusion. Relatively new material systems, such as Nb₃Al, V₃Si, Mo-Re, and MgB₂, are just a few of the possibilities offered, but challenges with impurity control, interface engineering, and cavity-scale uniformity will remain. We believe that future progress will depend upon energetic sputtering, multilayer architectures, and systematic demonstrations at the cavity scale. Full article

In view of the need to increase the durability of working tools exposed to intense friction, this study analysed hybrid coatings (TiAlCN, AlTiCN, AlCrTiN, TiN, CrN) with a DLC (Diamond-Like Carbon) layer, deposited using PVD (Physical Vapour Deposition) methods (arc evaporation and magnetron sputtering). The structural characteristics of the coatings were determined using SEM (Scanning Electron Microscope) and AFM (Atomic Force Microscope) microscopy, as well as Raman spectroscopy, which confirmed the compact structure and amorphous nature of the DLC layer. Tribological tests were performed using a ball-on-disc test, revealing that DLC hybrid coatings significantly reduce the coefficient of friction (stabilisation in the range of 0.10 to 0.14 due to DLC graphitisation), limiting tool wear even under increased load. The SEM-EDS (Scanning Electron Microscope-Energy Dispersive Spectroscopy) microscopic examination revealed that the dominant wear mechanisms are abrasive and adhesive damage, and the AlCrTiN/DLC system is characterised by low wear and high adhesion (L_c = 10⁵ N), making it the optimal configuration for the given loads. Microhardness tests showed that high hardness does not always automatically translate into increased wear resistance (e.g., the AlTiCN coating with 4220 HV showed the highest wear), while coating systems with moderate hardness (TiAlCN/DLC, CrN/DLC) achieved very low wear values (~0.17 × 10⁻⁵ mm³/Nm), which highlights the importance of synergy between the hardness of the sublayer and the low friction of DLC in the design of protective coatings. Full article

Vanadium nitride (VN) ceramic layers were deposited on 304L stainless steel specimens by direct current (DC) magnetron sputtering in an Ar/N₂ gas mixture at substrate temperatures of 250 °C, 300 °C, and 350 °C. The obtained films were evaluated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). The results showed the existence of VN and V₂N phases in the as-deposited coatings. It was found that the surface roughness parameter (Ra = 10 nm) decreased with increasing substrate temperatures up to 350 °C. The highest hardness (10.6 GPa) was achieved in the layer produced at 300 °C. The low values of plastic and elastic deformation, as well as a low friction coefficient (0.38), led to an enhancement in the coatings’ tribological properties. The film’s thickness increased with increasing temperature due to the presence of nucleation centers in the films. The highest thickness (557 nm) was achieved in the layer deposited at 350 °C. The electrochemical tests exhibited reliable protection against corrosion in strongly aggressive electrolytes. It has been proven that the temperature significantly affects the ceramic coatings’ structural, morphological, tribological, and corrosion properties. Full article

The IREQ (Insulation REQuired) index is the only reliable and effective model for predicting and evaluating the protection given by a clothing ensemble in cold environments. Even with the growth of studies aimed at assessing the thermophysical characteristics of clothing, IREQ remained unaltered from Holmér’s original formulation four decades prior. This paper focuses on the effect of the evaluation of the clothing area factor and the resultant vapour resistance on the assessment of cold environments via IREQ. Obtained results reveal meaningful variations in the duration limit exposure (up to 5 h), whereas IREQ values remain unchanged. Observed phenomena could be interesting when discussing the revision of the ISO 11079 standard, which prescribes using IREQ for the determination and interpretation of cold stress. Full article

A wave of energy efficiency-focused activity has spread across Europe in recent years, with ambitious goals for improving the energy performance of existing buildings through various directives. Among these existing buildings, there are older structures with heritage-protected facades. Some of the protected facades consist of timber plank frame walls, which were common in Norway in the 19th and early 20th centuries. Internal insulation is an option for increasing the energy efficiency of such walls while preserving their protected facades. However, this approach alters the moisture performance of the wall and introduces a potential risk for mould growth, which must be assessed. To better understand the performance of these walls, the $s_d$ values of traditional types of building paper have been tested, as timber plank frame walls comprise vertical planks covered in building paper. In addition, the risk of mould growth in timber plank frame walls has been evaluated using the one-dimensional simulation tool WUFI^® Pro by modelling the wall with internal retrofitting and varying input parameters. The types of building paper used have a wide range of vapour resistance values (diffusion-equivalent air layer thicknesses, $s_d$ values), which range from 0.008 m to 5.293 m. Adding 50 mm of interior insulation generally resulted in a low risk of mould growth, except in cases involving the use of a moisture-adaptive vapour barrier (MAVB). The MAVB did not result in an acceptable mould growth risk in any of the tested scenarios. Full article

Growing demand for chemically resistant, thermally stable, and anti-icing coatings has intensified interest in boron nitride (BN)-based materials and surface coatings. In this study, BN coatings were developed on mild steel (MS) via chemical vapour deposition (CVD) at 1200 °C for 15, 30, and 60 min, and their structural, surface, and water-repellent characteristics were evaluated. X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) spectroscopy confirmed the successful formation of BN, while water contact angle measurements indicated high hydrophobicity, demonstrating excellent barrier properties. Scanning electron microscopy (SEM) revealed morphological evolution from flower- and needle-like BN structures in the sample placed in the CVD furnace for 15 min to dense, coral-like, and tubular networks in the samples placed for 30 and 60 min. These findings highlight that BN coatings, particularly the one obtained after 30 min of deposition, have a high hydrophobic character following the Cassie–Baxter model and can be used for corrosion resistance and anti-icing on MS, making them ideal for industrial applications requiring long-lasting protection. Full article

The detection of volatile organic compound (VOC) biomarkers from the volatolome for the anticipated diagnosis of severe diseases such as cancers is made difficult due to the presence of high quantities of H₂O in the collected samples. It has been shown that water molecules tend to compete or combine themselves with analytes, which requires either their removal or the development of more sensitive and discriminant sensors. In this later prospect, a positive effect of poly(hedral oligomeric silsesquioxanes) (POSS) is sought out to enhance the sensitivity of carbon nanotube-based quantum resistive vapour sensors (vQRS). POSS, once copolymerized with methyl methacrylate or styrene, can be used as nano-spacers amplifying the disconnection of the nano-junctions due to swelling of the polymer upon the diffusion of VOC. The amplitude of this phenomenon, which is at the origin of the chemo-resistive behaviour of vQRS, was compared with that of homologue transducers made of poly(styrene) (PS) and poly(methyl methacrylate) (PMMA)-coated carbon nanotube (CNT) random networks. The presence of POSS in PS-based sensors has enhanced their sensitivity by 213 times for toluene, by 268 times for acetone, by 4 times for ethanol, and by 187 times for cyclohexane. Similarly, the presence of POSS in PMMA chains increases the sensitivity of sensors to cyclohexane by 10 times, to ethanol by 45 times, to toluene by 244 times, and to acetone and butanone by 4 times. All transducers were made by spray layer by layer (sLbL) to obtain a hierarchically structured conducting architecture. The transducers’ surface was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) to observe the CNT coating and dispersion level in the matrix. All sensors were tested with twenty-one VOC part of lung and skin cancer biomarkers by using a dynamic vapour analysis (DVA). The vQRS based on POSS copolymers demonstrated much larger chemo-resistive responses (A_R) than the sensors based only on pure polymers and were found to be very selective towards cyclohexane and hexene-1. The PMMA-co-POSS/CNT sensor was able to detect down to 12 ppm of VOC with a very high signal-to-noise ratio (SNR) and to discriminate six VOC among them all with a PCA (principal component analysis) projection. Full article

Starch films were obtained by solvent casting and thermoprocessing using glycerol as a plasticiser from a new starch source: tiger nut waste from horchata production. The tiger nut starch (TNS) films showed a barrier capacity to water vapour and gases in the typical range of other starch films, such as corn starch (CS) films, with a high barrier capacity to oxygen. The tensile properties of the films were affected by the processing method, exhibiting higher stiffness and resistance to break and lower stretchability than the more common CS films. Thermoprocessed TNS films were less water soluble than CS films, and their solubility was higher than that of cast TNS films. However, all films exhibited similar swelling power. Thermal stability was also similar for all TNS and CS films, showing the typical thermal degradation pattern of starch–glycerol films. Therefore, TNS obtained from horchata production waste can be used to obtain thermoplastic starch films for packaging applications, with characteristics comparable to the most common corn starch films. Full article

As energy-efficient buildings become central to climate change mitigation, the opportunity for interior and interstitial moisture accumulation and mould growth can increase. This study investigated the potential simulation-based mould growth risks associated with the current generation of insulated low-rise timber framed external wall systems within southeastern Australia. More than 8000 hygrothermal and bio-hygrothermal simulations were completed to evaluate seasonal moisture patterns and calculate mould growth potential for nine typical external wall systems. Results reveal that the combination of increased thermal insulation and air-tightness measures between the 2010 and 2022 specified building envelope energy efficiency regulations further increased predicted Mould Index values, particularly in cool-temperate climates. This was in part due to insufficient moisture management requirements, like an air space between the cladding and the weather resistive layer and/or the low-water vapour permeability of exterior weather resistive pliable membranes. By contrast, warmer temperate climates and drier cool-temperate climates exhibit consistently lower calculated Mould Index values. Despite the 2022 requirement for a greater water vapour-permeance of exterior pliable membranes, the external walls systems explored in this research had a higher calculated Mould Index than the 2010 regulatory compliant external wall systems. Lower air change rates significantly increased calculated interstitial mould growth risk, while the use of interior vapour control membranes proved effective in its mitigation for most external wall systems. The addition of ventilated cavity in combination with either or both an interior vapour control membrane and a highly vapour-permeable exterior pliable membranes further reduced risk. The findings underscore the need for tailored, climate-responsive design interventions to minimise surface and interstitial mould growth risk and building durability, whilst achieving high performance external wall systems. Full article

Thermal and moisture properties of the textile materials worn in close contact with the skin greatly contribute to the comfort of the workwear and of the personal protective clothing (PPC) assemblies they are part of. This study examines in depth the thermoregulatory properties of eighteen knitted fabrics used in polo shirts and T-shirts, which function as thermal underwear, standard workwear compliant with various regulations, or as base layers in PPC systems. Most of the fabrics specifically engineered for heat protection demonstrated superior air permeability (ranging from 700 to 1200 mm/s) and efficient moisture management (OMMC 0.5–0.7). Their drying time varied between 12 and 18 min, comparable to most commodity fibre blend fabrics investigated. Generally, the heat-protective fabrics were heavier and exhibited greater thermal and vapour resistance. However, despite minor variations in predicted thermal comfort, seventeen of the fabrics were classified in the same cluster. These findings offer valuable insights into the thermal and moisture management properties of knitted fabrics with various levels of protection, and the correlations found between their thermoregulatory and physical properties, such as mass and thickness, provide guidance for the development of innovative knitted materials for workwear that enhance wearer comfort. Full article

This study explores the in situ measurement of contact temperature in thermo-elastohydrodynamic lubrication (TEHL) within cylindrical roller thrust bearings (CRTBs) utilizing vapour-deposited resistive thin-film sensors. The sensors, optimized for compactness and high spatial resolution, were strategically embedded on the stationary bearing raceways near the outer, inner, and mean radius. This configuration enabled a precise measurement of temperature variations in both pure rolling and rolling–sliding regions of the CRTBs. The experimental results revealed a consistent decrease in temperature from the inner and outer radius zones towards the mean radius as the slip-to-roll ratio (SRR) decreased in these regions. Temperature profiles showed an early rise in the inlet zone attributed to thermal inlet shear. At higher speeds, a secondary temperature peak indicative of full-film lubrication was observed in the outlet zone immediately following the Hertzian contact. The study further shows the influence of surface pressure, shear rates, sliding friction, and circumferential speed on contact temperature dynamics, offering insights into their complex interplay. Additionally, viscosity variations due to different oil temperatures were found to critically affect the rate of temperature rise and the propensity for mixed friction phenomena. A higher viscosity resulted in an earlier onset of the temperature rise in the contact, while a lower viscosity and higher speeds promote mixed lubrication, leading to reduced contact film temperatures. These findings provide valuable insights into the behaviour of CRTB-lubricated contacts under various operating conditions and serve as crucial validation data for advanced TEHL computational models. Full article

New sustainable materials have been developed to replace conventional plastics obtained from non-renewable sources. In this study, cellulose fibres from Posidonia oceanica (PO) were obtained by applying subcritical water extraction and bleaching with hydrogen peroxide or sodium chlorite. The PO fibres were used to obtain cellulose films, chitosan–cellulose composites, and PLA–cellulose laminates. These films were characterised as to their optical properties, mechanical performance, oxygen and water vapour permeability, thermal stability, and microstructure. The cellulose films exhibited low mechanical resistance, with different colouration depending on the degree of delignification. The composites had lower mechanical strength than pure chitosan films. The PO cellulose fibres had a similar, but attenuated, effect when laminated with PLA layers. The fibres improved the oxygen barrier capacity of chitosan films, although this effect only occurred in PLA laminates for cellulose purified with sodium chlorite. In no case did cellulose improve the water vapour barrier of the films compared to pure polymers. The thermal stability was not notably altered by the blending effect, thus reflecting the absence of significant interactions between the fibres and polymer. However, there is a need to improve the functionality of cellulose fibres from PO waste for their incorporation as fillers or laminates in biodegradable food packaging materials. Full article

According to the global strategy of Green course, the production of sustainable textiles using different biodegradable fibres has immense potential for the development of sustainable products. Using one of the most sustainable biobased pure hemp and polylactide fibers yarns, four new biodegradable three-layer weft knitted fabrics with good thermal comfort properties were developed. The inner layer (worn next to the skin) and the middle layer of the knits were formed of hydrophobic polylactide fibers, the outer layer of different amounts (36–55%) of hydrophilic natural hemp fibers. Biodegradable polylactide fiber yarns were used as a replacement for conventional petroleum-based synthetic fibers. Natural hemp fibers are one of the most sustainable fibers derived directly from Cannabis sativa L. plants. The properties of the knitted fabrics were analysed and compared under thermoregulatory-moisture management, thermal resistance, air and water vapour permeability-properties. The results showed that all newly developed knits are ascribed to ‘moisture management’ fabrics according to the summary grading of all indices of moisture management parameters. In addition, it was found that the highest overall moisture management capability is related to the quantity of natural hemp fiber composition in different knitting structures. Based on the overall moisture management capacity (OMMC) index and thermal resistance values of developed knitted fabrics, the performance levels for these materials contacting the skin and intended for the intermediate layer were determined. Full article

The primary goal of this review is to explore both the fundamental dynamics of moisture ingress and practical strategies for its mitigation. Moisture ingress remains a critical issue due to its impact on the structural integrity of buildings and the health and safety of occupants. This work adopts a systematic approach, focusing on key mechanisms of water transport—capillary action, vapour diffusion, and condensation—and how different parameters influence the process of moisture transport. Moisture ingress, whether through direct leakage, capillary action, air infiltration, or vapour diffusion, poses significant risks to the premature degradation of building envelope materials. In this study, emphasis has been placed on describing the methods for controlling liquid water movement, preventing condensation, and using moisture-resistant materials. Additionally in this study, the advanced design and hygrothermal performance simulation tools are examined; the use of such tools is considered essential for predicting and managing moisture-related issues in building envelopes. Finally, the significance of complying with moisture control standards and guidelines is highlighted, ensuring a comprehensive framework for effective moisture management in building design and maintenance. Beyond this review, key knowledge gaps in moisture control strategies have been identified, particularly in respect to material performance, the accuracy of predictive modeling, and the standardization of mitigation techniques. Addressing these gaps is essential for advancing building design, maintenance practices, and regulatory frameworks that together combine to enhance moisture resilience. Full article

In response to concerns over resource shortages and environmental impacts, biobased materials are increasing in popularity. This includes an interest in replacing traditional vapour control systems, including polyethene (PE) membranes. However, the susceptibility of these materials to moisture-related degradation poses challenges. This study examines the water vapour diffusion resistance of the vapour retarder and the wind shield as key properties. Examining wood frame walls designed with low water vapour diffusion resistance wind shields, this study analyses the necessary properties of the vapour retarder as a function of the properties of the wind shield. We evaluated exterior wood frame walls that were thermally insulated with materials including mineral wool and biobased options such as flax, grass, wood fibre, straw, and cellulose. Using WUFI Pro software, we determined the relations between properties necessary to prevent mould growth. Hygrothermal simulations determined the necessary properties of the vapour retarder as a function of the properties of the wind shield. Analyses were carried out in temperate cold climates. Wind shield diffusion tightnesses ranging from 0.01 to 1 (m²·s·GPa)/kg were evaluated. Assessments were performed for walls with a U-value of 0.15 and 0.10 W/(m²·K). The indoor humidity classes 1 to 3, as defined in EN ISO 13788, were used for the simulations. The results indicate that the necessary properties of the vapour retarder depend on the properties of the wind shield, as well as the insulation material, the indoor humidity, and the U-value. As the wind shield diffusion tightness decreases, the necessary vapour retarder diffusion tightness also decreases, eventually reaching a fixed value determined by the insulation material, the indoor humidity, and the U-value. Full article