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Keywords = waste battery management

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14 pages, 2868 KiB  
Article
Environmentally Sustainable Anode Material for Lithium-Ion Batteries Derived from Cattle Bone Waste: A Full-Cell Analysis with a LiFePO4 Cathode
by Muhammad Shajih Zafar, Pejman Salimi, Marco Ricci, Jasim Zia and Remo Proietti Zaccaria
Sustainability 2025, 17(7), 3005; https://doi.org/10.3390/su17073005 - 28 Mar 2025
Viewed by 247
Abstract
Modern society relies heavily on energy, driving global research into sustainable energy storage and conversion technologies. Concurrently, the increasing volume of waste generated by industrial and commercial activities emphasizes the need for effective waste management strategies. Carbonization emerges as a promising solution, converting [...] Read more.
Modern society relies heavily on energy, driving global research into sustainable energy storage and conversion technologies. Concurrently, the increasing volume of waste generated by industrial and commercial activities emphasizes the need for effective waste management strategies. Carbonization emerges as a promising solution, converting waste into energy and valuable end products such as biochar. This study explores an approach for valorizing bone-based food waste, presenting innovative pathways for managing the escalating issue of food waste. We investigate carbon derived from cattle bone waste, carbonized at 800 °C (CBW8), to design sustainable full-cell lithium-ion batteries (FLIBs). FLIBs featuring CBW8 as the anode material and LiFePO4 as the cathode exhibit exceptional cycling life, even at high current rates. The cell demonstrates a high specific capacity of 165 mAh g−1 at 0.5 C, maintaining stable performance over 1800 cycles at various C-rates. This work not only advances the field of sustainable energy and waste management, but also opens new avenues for eco-friendly technological applications. Full article
(This article belongs to the Special Issue Biomass Transformation and Sustainability)
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24 pages, 2214 KiB  
Article
Challenges Faced by Lithium-Ion Batteries in Effective Waste Management
by Anna Luiza Santos, Wellington Alves and Paula Ferreira
Sustainability 2025, 17(7), 2893; https://doi.org/10.3390/su17072893 - 26 Mar 2025
Viewed by 338
Abstract
Electric vehicles are regarded as key players in reducing CO2 emissions. However, managing the end-of-life (EoL) of lithium-ion batteries (LIBs) poses significant environmental and technical challenges. This presents a daunting task for governments, companies, and academics when discussing and developing initiatives for [...] Read more.
Electric vehicles are regarded as key players in reducing CO2 emissions. However, managing the end-of-life (EoL) of lithium-ion batteries (LIBs) poses significant environmental and technical challenges. This presents a daunting task for governments, companies, and academics when discussing and developing initiatives for the EoL of LIBs. As more LIBs reach the end of their vehicular use, it becomes essential to identify key challenges. This research aims to analyze possible pathways, identify LIBs’ challenges in reaching the appropriate destinations, and propose actions to overcome these obstacles. Additionally, this study addresses those responsible for each challenge. A narrative review was employed as a methodological approach to achieve the proposed objectives, utilizing available literature on EoL LIB management. The research findings highlight various challenges, including safety, commercialization, and disassembly. To address these issues, this work recommends strategies such as extended producer responsibility, automation, and regulation. The study also emphasizes the necessity for a collaborative effort, particularly highlighting the key roles of government and industry in developing regulations, implementing effective waste management strategies, and driving market expansion, while academia contributes through research and technological advancements. The research contributes to a better understanding of sustainable LIB management, advocating for responsible disposal and reducing environmental and economic impacts. Full article
(This article belongs to the Section Sustainable Transportation)
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27 pages, 6513 KiB  
Article
Assessing Lead Waste and Secondary Resources in Major Consumer Nations: A Vanishing Resource or a Toxic Legacy?
by Sebastien M. R. Dente, Jian Zhang and Seiji Hashimoto
Resources 2025, 14(4), 52; https://doi.org/10.3390/resources14040052 - 24 Mar 2025
Viewed by 124
Abstract
This study applies a dynamic material flow analysis to track lead flows, in-use stocks, secondary reserves, and recycling trends across eleven major economies from 1950 to 2018. The results show the global lead cycle has shifted from a variety of industrial applications to [...] Read more.
This study applies a dynamic material flow analysis to track lead flows, in-use stocks, secondary reserves, and recycling trends across eleven major economies from 1950 to 2018. The results show the global lead cycle has shifted from a variety of industrial applications to a predominant reliance on lead–acid batteries. By 2018, China had become the dominant actor, accounting for 82% of global lead extraction and holding 47% of total in-use stocks (58.3 Mt). Despite regulatory efforts to phase out dissipative uses, the global domestic processed output in 2018 reached 1429 kt, surpassing 1976 levels (1148 kt). At the same time, end-of-life lead waste increased to 7717 kt, yet only 48% was successfully recovered, exposing inefficiencies in current recycling and circular economy initiatives. Secondary reserves also varied widely, with China (18.5 Mt) and the US (9.9 Mt) leading in absolute terms, while Europe maintained the highest per capita reserves. The growing competition from lithium-ion batteries raises questions about the long-term role of lead in industry. If demand declines, the accumulation of unmanaged legacy stocks could become a significant environmental challenge. To address these issues, improvements in recycling systems, stricter waste management policies, and the development of sustainable alternatives are needed. Full article
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23 pages, 1091 KiB  
Review
Cryogenics in Renewable Energy Storage: A Review of Technologies
by Arian Semedo, João Garcia and Moisés Brito
Energies 2025, 18(6), 1543; https://doi.org/10.3390/en18061543 - 20 Mar 2025
Viewed by 346
Abstract
The increase in the exploration of renewable energy sources intensifies the need for efficient storage solutions to mitigate the inherent intermittence of these sources. Among the available technologies, cryogenic energy storage (CES) systems stand out as a major and promising technology due to [...] Read more.
The increase in the exploration of renewable energy sources intensifies the need for efficient storage solutions to mitigate the inherent intermittence of these sources. Among the available technologies, cryogenic energy storage (CES) systems stand out as a major and promising technology due to their high scalability, energy efficiency, and potential for integration with other systems. This paper deals with cryogenic approaches, focused on Liquid Air Energy Storage (LAES). Several topics are addressed, including the characterization of the CES systems, their working principle, with special relevance to efficiency and temperature/entropy diagram, the conception and the technical challenges, design, and construction of CES. LAES demonstrates energy efficiencies ranging from 45% to 70%, potentially reaching up to 75% with the integration of complementary technologies, with capital costs ranging from 900 EUR/kW to 1750/EUR/kW. Carbon dioxide (CO2)-based systems, while more energy-efficient (40% to 60%), face significant barriers due to high infrastructure costs. Additionally, hybrid configurations that combine advanced thermal cycles and waste heat management achieve efficiencies between 55% and 80%, showing adaptability in complex energy scenarios. In comparison with alternatives such as batteries and Compressed Air Energy Storage (CAES), despite economic and technological limitations, CES systems have a promising role in the global energy transition, particularly with anticipated advancements that will enhance their competitiveness and economic viability. Full article
(This article belongs to the Section D: Energy Storage and Application)
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22 pages, 7199 KiB  
Article
Deep Reinforcement Learning-Based Energy Management Strategy for Green Ships Considering Photovoltaic Uncertainty
by Yunxiang Zhao, Shuli Wen, Qiang Zhao, Bing Zhang and Yuqing Huang
J. Mar. Sci. Eng. 2025, 13(3), 565; https://doi.org/10.3390/jmse13030565 - 14 Mar 2025
Viewed by 310
Abstract
Owing to the global concern regarding fossil energy consumption and carbon emissions, the power supply for traditional diesel-driven ships is being replaced by low-carbon power sources, which include hydrogen energy generation and photovoltaic (PV) power generation. However, the uncertainty of shipboard PV power [...] Read more.
Owing to the global concern regarding fossil energy consumption and carbon emissions, the power supply for traditional diesel-driven ships is being replaced by low-carbon power sources, which include hydrogen energy generation and photovoltaic (PV) power generation. However, the uncertainty of shipboard PV power generation due to weather changes and ship motion variations has become an essential factor restricting the energy management of all-electric ships. In this paper, a deep reinforcement learning-based optimization algorithm is proposed for a green ship energy management system (EMS) coupled with hydrogen fuel cells (HFCs), lithium batteries, PV generation, an electric power propulsion system, and service loads. The focus of this study is reducing the total operation cost and improving energy efficiency by jointly optimizing power generation and voyage scheduling, considering shipboard PV uncertainty. To verify the effectiveness of the proposed method, real-world data for a hybrid hydrogen- and PV-driven ship are selected for conducting case studies under various sailing conditions. The numerical results demonstrate that, compared to those obtained with the Double DQN algorithm, the PPO algorithm, and the DDPG algorithm without considering the PV system, the proposed DDPG algorithm reduces the total economic cost by 1.36%, 0.96%, and 4.42%, while effectively allocating power between the hydrogen fuel cell and the lithium battery and considering the uncertainty of on-board PV generation. The proposed approach can reduce energy waste and enhance economic benefits, sustainability, and green energy utilization while satisfying the energy demand for all-electric ships. Full article
(This article belongs to the Special Issue Advanced Technologies for New (Clean) Energy Ships—2nd Edition)
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21 pages, 1658 KiB  
Article
A Comprehensive Analysis of the Economic Implications, Challenges, and Opportunities of Electric Vehicle Adoption in Indonesia
by Natalina Damanik, Risa Saraswani, Dzikri Firmansyah Hakam and Dea Mardha Mentari
Energies 2025, 18(6), 1384; https://doi.org/10.3390/en18061384 - 11 Mar 2025
Viewed by 914
Abstract
Electric vehicles (EVs) are a recognized solution for lowering greenhouse gas emissions and decreasing oil dependency, especially in Indonesia. Existing studies have explored the economic impact, challenges, and opportunities of EV adoption separately, lacking a holistic analysis. This study addresses this gap by [...] Read more.
Electric vehicles (EVs) are a recognized solution for lowering greenhouse gas emissions and decreasing oil dependency, especially in Indonesia. Existing studies have explored the economic impact, challenges, and opportunities of EV adoption separately, lacking a holistic analysis. This study addresses this gap by providing a comprehensive assessment of the economic implications, challenges, and opportunities of EV adoption in Indonesia through a systematic literature review of 65 peer-reviewed articles, industry reports, and reputable publications from 2016 to 2024. The document analysis involved keyword-based literature selection, content analysis of economic metrics, and synthesis into key thematic areas. The findings reveal that EV sales in Indonesia have been rising annually, influenced by cost, driving range, environmental impact, technological features, charging infrastructure, battery, and government policies and incentives. EV adoption has positively impacted Indonesia’s GDP, attracted Foreign Direct Investment (FDI), created jobs, and reduced fuel consumption and imports. However, several challenges persist, including high EV costs, inadequate charging infrastructure, societal readiness, battery replacement costs and waste management, and limited model variety. Despite these challenges, opportunities exist in the form of market growth, FDI from nickel resources, energy security, job creation, and industrial expansion. Recommendations for creating a conducive EV ecosystem are provided for relevant stakeholders. Full article
(This article belongs to the Special Issue Electric Vehicles for Sustainable Transport and Energy: 2nd Edition)
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30 pages, 2480 KiB  
Review
High-Volume Battery Recycling: Technical Review of Challenges and Future Directions
by Sheikh Rehman, Maher Al-Greer, Adam S. Burn, Michael Short and Xinjun Cui
Batteries 2025, 11(3), 94; https://doi.org/10.3390/batteries11030094 - 28 Feb 2025
Viewed by 1507
Abstract
The growing demand for lithium-ion batteries (LIBs), driven by their use in portable electronics and electric vehicles (EVs), has led to an increasing volume of spent batteries. Effective end-of-life (EoL) management is crucial to mitigate environmental risks and prevent depletion of valuable raw [...] Read more.
The growing demand for lithium-ion batteries (LIBs), driven by their use in portable electronics and electric vehicles (EVs), has led to an increasing volume of spent batteries. Effective end-of-life (EoL) management is crucial to mitigate environmental risks and prevent depletion of valuable raw materials like lithium (Li), cobalt (Co), nickel (Ni), and manganese (Mn). Sustainable, high-volume recycling and material recovery are key to establishing a circular economy in the battery industry. This paper investigates challenges and proposes innovative solutions for high-volume LIB recycling, focusing on automation for large-scale recycling. Key issues include managing variations in battery design, chemistry, and topology, as well as the availability of sustainable raw materials and low-carbon energy sources for the recycling process. The paper presents a comparative study of emerging recycling techniques, including EV battery sorting, dismantling, discharge, and material recovery. With the expected growth in battery volume by 2030 (1.4 million per year by 2040), automation will be essential for efficient waste processing. Understanding the underlying processes in battery recycling is crucial for enabling safe and effective recycling methods. Finally, the paper emphasizes the importance of sustainable LIB recycling in supporting the circular economy. Our proposals aim to overcome these challenges by advancing automation and improving material recovery techniques. Full article
(This article belongs to the Special Issue Lithium-Ion Battery Recycling)
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19 pages, 5232 KiB  
Article
Study on Performance of Integrated Thermal Management Strategy for Hybrid Electric Vehicles Under Low-Temperature Conditions
by Bofeng Xue, Yingchao Zhou, Peizhen Chen, Xinrui Meng and Junxian Zhang
Processes 2025, 13(3), 651; https://doi.org/10.3390/pr13030651 - 25 Feb 2025
Viewed by 421
Abstract
In cold environments, traditional independent thermal management systems heavily rely on inefficient Positive Temperature Coefficient (PTC) heaters, which exacerbate range anxiety in vehicles. In this study, an energy management-based control strategy for an integrated thermal management system (ITMS) designed for hybrid electric vehicles [...] Read more.
In cold environments, traditional independent thermal management systems heavily rely on inefficient Positive Temperature Coefficient (PTC) heaters, which exacerbate range anxiety in vehicles. In this study, an energy management-based control strategy for an integrated thermal management system (ITMS) designed for hybrid electric vehicles (HEVs) is proposed. By coupling the four thermal flow circuits of the entire vehicle and integrating driving modes with heating demands, this strategy achieves full vehicle-level integrated control. Through optimizing the distribution and utilization of heat within the vehicle, this enhances the heating performance of the air source heat pump. The simulation results demonstrate that the proposed strategy significantly reduces the power consumption of the heat pump and improves heating efficiency for both the battery and the cabin. By utilizing waste heat from the motor and the engine, the ITMS increases the heating capacity of the heat pump, particularly in low-temperature environments. Compared to traditional thermal management systems, the ITMS control strategy achieves substantial improvements in both heating time and energy efficiency. Specifically, the system reduces battery heating time by 55.94% and enhances the overall heating performance of the vehicle. Furthermore, the strategy reduces fuel consumption by 5.18%, demonstrating its potential to improve the energy efficiency of HEVs in cold climates. Full article
(This article belongs to the Section Energy Systems)
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26 pages, 7775 KiB  
Review
Efficient Recycling Processes for Lithium-Ion Batteries
by Sabyasachi Paul and Pranav Shrotriya
Materials 2025, 18(3), 613; https://doi.org/10.3390/ma18030613 - 29 Jan 2025
Cited by 1 | Viewed by 959
Abstract
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life [...] Read more.
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life LIBs to recover valuable resources and minimize the environmental impact. Pyrometallurgical and hydrometallurgical processes are the most common recycling methods but pose considerable difficulties. The energy-intensive pyrometallurgical recycling process results in the loss of critical materials such as lithium and suffers from substantial emissions and high costs. Solvent extraction, a hydrometallurgical method, offers energy-efficient recovery for lithium, cobalt, and nickel but requires hazardous chemicals and careful waste management. Direct recycling is an alternative to traditional methods as it preserves the cathode active material (CAM) structure for quicker and cheaper regeneration. It also offers environmental advantages of lower energy intensity and chemical use. Hybrid pathways, combining hydrometallurgical and direct recycling methods, provide a cost-effective, scalable solution for LIB recycling, maximizing material recovery with minimal waste and environmental risk. The success of recycling methods depends on factors such as battery chemistry, the scalability of recovery processes, and the cost-effectiveness of waste material recovery. Though pyrometallurgical and hydrometallurgical processes have secured their position in LIB recycling, research is proceeding toward newer approaches, such as direct and hybrid methods. These alternatives are more efficient both environmentally and in terms of cost with a broader perspective into the future. In this review, we describe the current state of direct recycling as an alternative to traditional pyrometallurgical and hydrometallurgical methods for recuperating these critical materials, particularly lithium. We also highlight some significant advancements that make these objectives possible. As research progresses, direct recycling and its variations hold great potential to reshape the way LIBs are recycled, providing a sustainable pathway for battery material recovery and reuse. Full article
(This article belongs to the Section Energy Materials)
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22 pages, 2361 KiB  
Review
Advances in Recycling Technologies of Critical Metals and Resources from Cathodes and Anodes in Spent Lithium-Ion Batteries
by Shuwen Wang, Yanrong Lai, Jingran Yang, Jiaxue Zhao, Yushan Zhang, Miaoling Chen, Jinfeng Tang, Junhua Xu and Minhua Su
Separations 2025, 12(1), 4; https://doi.org/10.3390/separations12010004 - 30 Dec 2024
Cited by 3 | Viewed by 1120
Abstract
With the rapid economic development and the continuous growth in the demand for new energy vehicles and energy storage systems, a significant number of waste lithium-ion batteries are expected to enter the market in the future. Effectively managing the processing and recycling of [...] Read more.
With the rapid economic development and the continuous growth in the demand for new energy vehicles and energy storage systems, a significant number of waste lithium-ion batteries are expected to enter the market in the future. Effectively managing the processing and recycling of these batteries to minimize environmental pollution is a major challenge currently facing the lithium-ion battery industry. This paper analyzes and compares the recycling strategies for different components of lithium-ion batteries, providing a summary of the main types of batteries, existing technologies at various pre-treatment stages, and recycling techniques for valuable resources such as heavy metals and graphite. Currently, pyrometallurgy and hydrometallurgy processes have matured; however, their high energy consumption and pollution levels conflict with the principles of the current green economy. As a result, innovative technologies have emerged, aiming to reduce energy consumption while achieving high recovery rates and minimizing the environmental impact. Nevertheless, most of these technologies are currently limited to the laboratory scale and are not yet suitable for large-scale application. Full article
(This article belongs to the Section Purification Technology)
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22 pages, 4954 KiB  
Article
Development of a Hydrogen Fuel Cell Hybrid Urban Air Mobility System Model Using a Hydrogen Metal Hydride Tank
by Sanghyun Yun, Seok Yeon Im and Jaeyoung Han
Energies 2025, 18(1), 39; https://doi.org/10.3390/en18010039 - 26 Dec 2024
Viewed by 1073
Abstract
Hydrogen fuel cell-based UAM (urban air mobility) systems are gaining significant attention due to their advantages of higher energy density and longer flight durations compared to conventional battery-based UAM systems. To further improve the flight times of current UAM systems, various hydrogen storage [...] Read more.
Hydrogen fuel cell-based UAM (urban air mobility) systems are gaining significant attention due to their advantages of higher energy density and longer flight durations compared to conventional battery-based UAM systems. To further improve the flight times of current UAM systems, various hydrogen storage methods, such as liquid hydrogen and hydrogen metal hydrides, are being utilized. Among these, hydrogen metal hydrides offer the advantage of high safety, as they do not require the additional technologies needed for high-pressure gaseous hydrogen storage or the maintenance of cryogenic temperatures for liquid hydrogen. Furthermore, because of the relatively slower dynamic response of hydrogen fuel cell systems compared to batteries, they are often integrated into hybrid configurations with batteries, necessitating an efficient power management system. In this study, a UAM system was developed by integrating a hydrogen fuel cell system with hydrogen metal hydrides and batteries in a hybrid configuration. Additionally, a state machine control approach was applied to a distribution valve for the endothermic reaction required for hydrogen desorption from the hydrogen metal hydrides. This design utilized waste heat generated by the fuel cell stack to facilitate hydrogen release. Furthermore, a fuzzy logic control-based power management system was implemented to ensure efficient power distribution during flight. The results show that approximately 43% of the waste heat generated by the stack was recovered through the tank system. Full article
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23 pages, 6734 KiB  
Article
A Study on the Battery Recycling Process and Risk Estimation
by Taeho Kim, Cheolhee Yoon and Seungho Jung
Int. J. Environ. Res. Public Health 2024, 21(12), 1649; https://doi.org/10.3390/ijerph21121649 - 10 Dec 2024
Cited by 2 | Viewed by 1116
Abstract
The demand for the use of secondary batteries is increasing rapidly worldwide in order to solve global warming and achieve carbon neutrality. Major minerals used to produce cathode materials, which are key raw materials for secondary batteries, are treated as conflict minerals due [...] Read more.
The demand for the use of secondary batteries is increasing rapidly worldwide in order to solve global warming and achieve carbon neutrality. Major minerals used to produce cathode materials, which are key raw materials for secondary batteries, are treated as conflict minerals due to their limited reserves, and accordingly, research on the battery recycling industry is urgent for the sustainable secondary battery industry. There is a significant risk of accidents because there is a lack of prior research data on the battery recycling process and various chemicals are used in the entire recycling process. Therefore, for the safety management of related industries, it is necessary to clearly grasp the battery recycling process and to estimate the risk accordingly. In this study, the process was generalized using the information on the battery recycling process suggested in the preceding literature. And to estimate the relative risk of each battery recycling process, the RAC (Risk Assessment Code) matrix described in the US Department of Defense’s “MIL-STD-882E” was used. Severity was derived by using “NFPA 704”, and probability was derived by combining generalized event analysis for each process and the WEEE (Waste Electrical and Electronic Equipment) report. The results confirmed that the process using H2SO4 had the highest risk when extracting Li during the leaching process, and that dismantling and heat treatment had the lowest risk. Using the probability factor for each process calculated through the research, it is expected to be used in future battery recycling process research as basic data for quantitative risk assessment of the battery recycling process. Full article
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19 pages, 19953 KiB  
Article
A Diagnostic Approach to Improving the Energy Efficiency of Production Processes—2E-DAmIcS Methodology
by Adam Hamrol, Agnieszka Kujawińska, Krzysztof Brzozowski and Małgorzata Jasiulewicz-Kaczmarek
Energies 2024, 17(23), 5942; https://doi.org/10.3390/en17235942 - 26 Nov 2024
Viewed by 727
Abstract
This article presents the issue of energy waste in manufacturing processes, focusing on reducing unnecessary energy consumption and CO2 emissions. A significant challenge in modern production is identifying and minimizing energy waste, which not only increases operational costs but also contributes to [...] Read more.
This article presents the issue of energy waste in manufacturing processes, focusing on reducing unnecessary energy consumption and CO2 emissions. A significant challenge in modern production is identifying and minimizing energy waste, which not only increases operational costs but also contributes to environmental degradation. An improvement methodology referred to as 2E-DAmIcS is proposed. A distinguishing feature of the methodology is a risk map of energy waste in the production process. Application of the methodology is demonstrated using the example of a lead–acid battery production process. It is shown that even small but well-diagnosed changes to the process make it possible to significantly reduce energy consumption. The proposed methodology offers practical tools for managers and decision-makers in various industries to systematically identify and minimize energy waste. It highlights the importance of cross-disciplinary collaboration among specialists in technology, energy consumption, and statistical analysis to optimize energy use. By applying this approach, companies can achieve both financial savings and environmental benefits, contributing to more sustainable production practices. Full article
(This article belongs to the Section B: Energy and Environment)
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15 pages, 3772 KiB  
Article
The Recycling of Lithium from LiFePO4 Batteries into Li2CO3 and Its Use as a CO2 Absorber in Hydrogen Purification
by Zoltán Köntös and Ádám Gyöngyössy
Clean Technol. 2024, 6(4), 1504-1518; https://doi.org/10.3390/cleantechnol6040072 - 4 Nov 2024
Cited by 1 | Viewed by 2266
Abstract
The growing adoption of lithium iron phosphate (LiFePO4) batteries in electric vehicles (EVs) and renewable energy systems has intensified the need for sustainable management at the end of their life cycle. This study introduces an innovative method for recycling lithium from [...] Read more.
The growing adoption of lithium iron phosphate (LiFePO4) batteries in electric vehicles (EVs) and renewable energy systems has intensified the need for sustainable management at the end of their life cycle. This study introduces an innovative method for recycling lithium from spent LiFePO4 batteries and repurposing the recovered lithium carbonate (Li2CO3) as a carbon dioxide (CO2) absorber. The recycling process involves dismantling battery packs, separating active materials, and chemically treating the cathode to extract lithium ions, which produces Li2CO3. The efficiency of lithium recovery is influenced by factors such as leaching temperature, acid concentration, and reaction time. Once recovered, Li2CO3 can be utilized for CO2 capture in hydrogen purification processes, reacting with CO2 to form lithium bicarbonate (LiHCO3). This reaction, which is highly effective in aqueous solutions, can be applied in industrial settings to mitigate greenhouse gas emissions. The LiHCO3 can then be thermally decomposed to regenerate Li2CO3, creating a cyclic and sustainable use of the material. This dual-purpose process not only addresses the environmental impact of LiFePO4 battery disposal but also contributes to CO2 reduction, aligning with global climate goals. Utilizing recycled Li2CO3 decreases the demand for virgin lithium extraction, supporting a circular economy. Furthermore, integrating Li2CO3-based CO2 capture systems into existing industrial infrastructure provides a scalable and cost-effective solution for lowering carbon footprints while securing a continuous supply of lithium for future battery production. Future research should focus on optimizing lithium recovery methods, improving the efficiency of CO2 capture, and exploring synergies with other waste management and carbon capture technologies. This comprehensive strategy underscores the potential of lithium recycling to address both resource conservation and environmental protection challenges. Full article
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24 pages, 7352 KiB  
Article
Investigation of Engine Exhaust Heat Recovery Systems Utilizing Thermal Battery Technology
by Bo Zhu, Yi Zhang and Dengping Wang
World Electr. Veh. J. 2024, 15(10), 478; https://doi.org/10.3390/wevj15100478 - 21 Oct 2024
Viewed by 1570
Abstract
Over 50% of an engine’s energy dissipates via the exhaust and cooling systems, leading to considerable energy loss. Effectively harnessing the waste heat generated by the engine is a critical avenue for enhancing energy efficiency. Traditional exhaust heat recovery systems are limited to [...] Read more.
Over 50% of an engine’s energy dissipates via the exhaust and cooling systems, leading to considerable energy loss. Effectively harnessing the waste heat generated by the engine is a critical avenue for enhancing energy efficiency. Traditional exhaust heat recovery systems are limited to real-time recovery of exhaust heat primarily for engine warm-up and fail to fully optimize exhaust heat utilization. This paper introduces a novel exhaust heat recovery system leveraging thermal battery technology, which utilizes phase change materials for both heat storage and reutilization. This innovation significantly minimizes the engine’s cold start duration and provides necessary heating for the cabin during start-up. Dynamic models and thermal management system models were constructed. Parameter optimization and calculations for essential components were conducted, and the fidelity of the simulation model was confirmed through experiments conducted under idle warm-up conditions. Four distinct operational modes for engine warm-up are proposed, and strategies for transitioning between these heating modes are established. A simulation analysis was performed across four varying operational scenarios: WLTC, NEDC, 40 km/h, and 80 km/h. The results indicated that the thermal battery-based exhaust heat recovery system notably reduces warm-up time and fuel consumption. In comparison to the cold start mode, the constant speed condition at 40 km/h showcased the most significant reduction in warm-up time, achieving an impressive 22.52% saving; the highest cumulative fuel consumption reduction was observed at a constant speed of 80 km/h, totaling 24.7%. This study offers theoretical foundations for further exploration of thermal management systems in new energy vehicles that incorporate heat storage and reutilization strategies utilizing thermal batteries. Full article
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