Search Results (147)

Water pollution by organic dyes poses serious environmental and health challenges, demanding efficient and selective remediation methods. In this study, we engineered tailored organo-clay nanocomposites by modifying montmorillonite with hexadecyltrimethylammonium bromide (HTAB) and intercalating polyethylene glycol (PEG) chains of two distinct molecular weights (PEG200 and PEG4000). Comprehensive characterization techniques (XRD, FTIR, SEM, zeta potential, and TGA) confirmed the successful modification of the composites. Notably, PEG4000 promoted significant interlayer expansion, as evidenced by the shift of the (00l) reflection corresponding to the basal spacing d, indicating an increase in basal spacing. This expansion contributed to the formation of a well-ordered porous framework with uniformly distributed pores. In contrast, PEG200 produced smaller pores with a more uniform distribution but induced less pronounced interlayer expansion. Adsorption tests demonstrated rapid kinetics, achieving equilibrium in under 15 min, and impressive capacities: 420 mg/g of methylene blue (MB) adsorbed on PEG200/MMT@HTAB, and 385 mg/g of Congo red (CR) on PEG4000/MMT@HTAB. The crucial role of PEG chain length in adsorption selectivity was assessed, showing that shorter PEG chains favored methylene blue adsorption by producing narrower pores and faster kinetics, while longer PEG chains enhanced CR uptake via a stable, interconnected pore network that facilitates diffusion of larger dye molecules. Thermodynamic and Dubinin–Radushkevich analyses confirmed that the adsorption was spontaneous, exothermic, and predominantly driven by physical adsorption mechanisms involving weak van der Waals and dipole interactions. These findings highlight the potential of PEG-modified montmorillonite nanocomposites as cost-effective, efficient, and tunable adsorbents for rapid and selective removal of organic dyes in wastewater treatment. Full article

Additively manufactured continuous fibre-reinforced polymers (CFRPs) offer promising mechanical properties for engineering applications, including aerospace and automotive load-bearing structures. However, challenges such as weak interlayer bonding and low strength compared to traditional composites remain. This paper presents an experimental investigation into the effects of nitrogen (N₂) purging during printing and thermal annealing after printing on the tensile performance of additively manufactured CFRPs. Tensile tests were conducted on Onyx specimens produced by material extrusion and reinforced with continuous carbon fibre filaments (CFF), glass fibre filaments (GFF), or Kevlar fibre filaments (KFF). Results showed that N₂-purging and post-annealing had different effects on the tensile properties of various CFRPs. Particularly, N₂-purging, post-annealing, and their combination enhanced both the Young’s modulus and ultimate tensile strength (UTS) of KFF/Onyx specimens. For GFF/Onyx specimens, both treatments had a minor effect on the Young’s modulus but enhanced UTS. CFF/Onyx specimens exhibited improved Young’s modulus with N₂-purging, while both treatments reduced UTS. The different response of the CFRPs was associated with diverse governing failure mechanisms, as proved by microstructural and fracture surface inspection. Additionally, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analyses also revealed the thermal behaviour and crystal structures that influence the mechanical properties of CFRPs. Full article

The Zigui Basin, located in the Three Gorges Reservoir Area, has developed numerous landslides due to its interlayering of sandstone and mudstone, geological structure, and reservoir operations. This study identifies a fourth type of landslide failure mode: an oblique-dip slope wedge (OdSW) landslide, based on the Wanshuitian landslide. Following four heavy rainfall events from 3 to 13 July 2024, this landslide exhibited significant deformation on the 17th and was completely destroyed within 40 min. The dimensions of the landslide were 350 m in length, 160 m in width, and 20 m in thickness, with a volume estimated at 8.0 × 10⁵ m³. The characteristics of landslide deformation and the changes in moisture content within the shallow slide body were ascertained using unmanned aerial vehicles, moisture meters, and mobile phone photography. The landslide was identified to have occurred within the weathered residual layer of mudstone, situated between two sandstone layers, with the eastern boundary defined by an inclined rock layer. Upon transitioning into the accelerated deformation stage, the landslide initially exhibited uniform overall sliding deformation, culminating in accelerated deformation destruction. The dip structure created terrain disparities, resulting in a step-like terrain on the left bank and gentler slopes on the right bank, with interbedded soil and rock in a shallow layer, because the interlayered soft and hard geological conditions caused varied weathering and erosion patterns on the riverbank slopes. The interbedded weak–hard stratum layer fostered the development of the oblique-dip slope wedge landslide. Based on the improved Green–Ampt model, we developed a stability prediction methodology for an oblique-dip slope wedge landslide and determined the rainfall infiltration depth threshold of the Wanshuitian landslide (9.8 m). This study aimed not merely to sharpen the evolution mechanism and stability prediction of the Wanshuitian landslide but also to formulate more effective landslide-monitoring strategies and emergency management measures. Full article

Three-dimensional concrete printing (3DCP) is an emerging additive manufacturing technology with increasing application potential in the construction industry, offering advantages such as reduced labor requirements, shortened construction time, and material efficiency. However, structural integrity remains a challenge, particularly due to weak interlayer bonding resulting from the layered manufacturing process. This study investigates the mechanical performance and anisotropy of 3D-printed mineral-based composites with respect to the time interval between successive layers. Specimens were printed with varying interlayer intervals (0, 25, and 50 min) and tested in different loading directions. Flexural, compressive, and tensile strengths (direct and splitting methods) were measured both parallel and perpendicular to the layer orientation. Results showed a clear degradation in mechanical properties with increasing interlayer time, particularly in the direction perpendicular to the layers. Flexural strength decreased by over 25% and direct tensile strength by up to 40% with a 25 min interval. Compressive strength also declined, though less dramatically. Compared to cast specimens, printed elements showed 3–4 times lower compressive strength, highlighting the significant impact of interlayer cohesion. This study confirms that both the time between layers and the loading direction strongly influence mechanical behavior, underlining the anisotropic nature of 3DCP elements and the need for process optimization to ensure structural reliability. Full article

As 3D concrete printing emerges as a transformative construction method, its structural safety remains hindered by unresolved issues of mechanical anisotropy and interlayer defects. To address this, we systematically investigate the failure mechanisms and mechanical performance of basalt fiber-reinforced 3D-printed magnesite concrete. A total of 30 cube specimens (50 mm × 50 mm × 50 mm)—comprising three types (Corner, Stripe, and R-a-p)—were fabricated and tested under compressive and splitting tensile loading along three orthogonal directions using a 2000 kN electro-hydraulic testing machine. The results indicate that 3D-printed concrete exhibits significantly lower strength than cast-in-place concrete, which is attributed to weak interfacial bonds and interlayer pores. Notably, the R-a-p specimen’s Z-direction compressive strength is 38.7% lower than its Y-direction counterpart. To complement the mechanical tests, DIC, CT scanning, and SEM analyses were conducted to explore crack development, internal defect morphology, and microstructure. A finite element model based on the experimental data successfully reproduced the observed failure processes. This study not only enhances our understanding of anisotropic behavior in 3D-printed concrete but also offers practical insights for print-path optimization and sustainable structural design. Full article

The growing accumulation of plastic packaging waste poses severe environmental and health challenges. To address these issues, significant research has been devoted to developing biodegradable films; however, their weak mechanical and barrier properties limit their practical utility. This study introduces an innovative multilayer film production method, combining electrospun polycaprolactone (PCL) fibers with a chitosan matrix. Two configurations were investigated: (1) nonwoven PCL layers placed between chitosan sheets and (2) a chitosan sheet sandwiched between two nonwoven PCL layers. Both systems were evaluated using PCL fibers derived from medical-grade and technical-grade polymers. The chitosan/polycaprolactone/chitosan (CH/PCL/CH) configuration demonstrated superior performance, achieving enhanced interlayer cohesion and significantly improved mechanical strength, durability, and barrier properties. Notably, this configuration achieved tensile strength and elongation at break values of 57.1 MPa and 36.3%, respectively—more than double those of pure chitosan films. This breakthrough underscores the potential of multilayered biopolymer films as eco-friendly packaging solutions, offering exceptional promise for sustainable applications in the food packaging industry. Full article

As open-pit mining extends to greater depths, slope stability is becoming a critical factor in ensuring safe production. This issue is particularly pronounced in geological settings with weak interlayers, where sudden slope failures are more likely to occur, demanding precise and reliable stability assessment methods. In this study, a typical open-pit slope with weak interlayers was investigated. Acoustic testing and ground-penetrating radar were employed to identify rock mass structural features and delineate loose zones, enabling detailed rock mass zoning and the development of numerical simulation models for stability analysis. The results indicate that (1) the slope exhibits poor overall integrity, dominated by blocky to fragmented structures with well-developed joints and significant weak interlayers, posing a severe threat to stability; (2) in the absence of support, the slope’s dissipated energy, displacement, and plastic zone volume all exceeded the failure threshold (Δ < 0), and the safety factor was only 0.962, indicating a near-failure state; after implementing support measures, the safety factor increased to 1.31, demonstrating a significant improvement in stability; (3) prior to excavation, the energy damage index (ds) in the 1195–1240 m platform zone reached 0.82, which dropped to 0.48 after reinforcement, confirming the effectiveness of support in reducing energy damage and enhancing slope stability; (4) field monitoring data of displacement and anchor rod forces further validated the stabilizing effect of the support system, providing strong assurance for safe mine operation. By integrating cusp catastrophe theory with energy-based analysis, this study establishes a comprehensive evaluation framework for slope stability under complex geological conditions, offering substantial practical value for deep open-pit mining projects. Full article

The characteristics of interlayer oxidation zones constrain sandstone-type uranium mineralization. This study conducted a quantitative characterization of the interlayer oxidation zones in the uranium-bearing reservoir of the Saihan Formation in the central Wulanchabu Subbasin of the Erlian Basin through sand dispersion system mapping, the analysis of sedimentary debris components, environmentally sensitive parameters, and elemental geochemical characteristics. The formation mechanisms and controlling factors of interlayer oxidation zones were investigated, along with uranium mineralization patterns. Research findings reveal that the sandbodies in the study area primarily consist of red sandstone, yellow sandstone, gray ore-bearing sandstone, and primary gray sandstone, representing strong oxidation zones, weak oxidation zones, transitional zones, and reduction zones, respectively. Although the mineral debris content shows minimal variation among different zones, feldspar dissolution is more prevalent in oxidized zones. During interlayer oxidation, environmentally sensitive parameters exhibit an ascending trend from strong oxidation zones through weak oxidation zones and reduction zones to mineralized transitional zones. Four transition metal elements (Co, Ni, Zn, and Mo) demonstrate enrichment in mineralized transitional zones. The development of interlayer oxidation zones is directly controlled by reservoir heterogeneity and sedimentary environments. Oxidation subzones primarily occur in sandbodies with moderate thickness (40–80 m), sand content ratios of 40%–80%, and 2–10 or 10–18 mudstone barriers (approximately 20 m thick), mainly in braided river channels and channel margin deposits. Reduction zones develop in thicker sandbodies (~100 m) with higher sand contents (~80%), fewer mudstone barriers (2–8 layers), greater thickness (40–80 m), and predominantly channel margin deposits. Transitional zones mainly occur in braided distributary channels and floodplain deposits. When oxygen-bearing uranium fluids infiltrate reservoirs, oxygen reacts with reductants like organic matter, whereFe²⁺ oxidizes to Fe³⁺, S²⁻ reacts with oxygen, and U⁴⁺ oxidizes to U⁶⁺, migrating as uranyl complexes. As oxygen depletes, Fe³⁺ reduces to Fe²⁺, combining with S²⁻ to form pyrite between mineral grains. Uranyl complexes reduce to precipitate as pitchblende, while some U⁴⁺ reacts with SiO₄⁴⁻, forming coffinite, occurring as colloids around quartz debris or pyrite. The concurrent enrichment of certain transition metal elements occurs during this process. Full article

High concrete gravity dams, particularly Roller-Compacted Concrete (RCC) types, face long-term safety challenges due to weak interlayer formation and crack propagation. This study presented a comprehensive evaluation of safety monitoring indexes for the Guxian high RCC dam (currently under construction) using both numerical and mathematical models. A finite element method (FEM) is employed with a strength reduction approach to assess dam stability considering weak layers. In parallel, a fracture mechanical model is used to investigate the safety of the Guxian dam based on failure assessment diagrams (FADs) for calculating the safety factor and the residual strength curve for calculating critical crack depth for two different crack locations, single-edge and center-through crack, to investigate the high possible risk associated with crack location on the dam safety. Additionally, the Guxian dam’s resistance to hydraulic fracture is assessed under two fracture mechanic failure modes, Mode I (open type) and Mode II (in-plane shear), by computing the ultimate overload coefficient using a proposed novel derived formula. The results show that weak layers reduce the dam’s safety index by approximately 20%, especially in lower sections with extensive interfaces. Single-edge cracks pose greater risk, decreasing the safety factor by 10% and reducing critical crack depth by 40% compared to center cracks. Mode II demonstrates higher resistance to hydraulic fracture due to greater shear strength and fracture energy, whereas Mode I represents the most critical failure scenario. The findings highlight the urgent need to incorporate weak layer behavior and hydraulic fracture mechanisms into dam safety monitoring, and to design regulations for high RCC gravity dams. Full article

Sudden coal and gas outbursts pose a significant hazard in deep-seated coal seam extraction, necessitating reliable risk assessment methods. Traditionally, assessments focus on gas-dynamic parameters, but experience shows they must be supplemented with tectonic factors such as fault-related disturbances, weak interlayers, and increased fracturing. Even minor faults in the Karaganda Basin can weaken the coal massif and trigger outbursts. The integration of 3D modeling enhances risk evaluation by incorporating both dynamic (gas-related) and static (tectonic) parameters. Based on exploratory drilling and geophysical studies, these models map coal seam geometry, fault positioning, and high-risk structural zones. In weakened coal areas, stress distribution changes can lead to avalanche-like gas releases, even under normal gas-dynamic conditions. An expert scoring system was used to convert geological and gas-dynamic data into a comprehensive risk index guiding preventive measures. An analysis of Karaganda Basin incidents (1959–2021) shows all outbursts occurred in geological disturbance zones, with 43% linked to fault proximity, 30% to minor tectonic shifts, and 21% to sudden coal seam changes. Advancing 3D modeling, geomechanical analysis, and microseismic monitoring will improve predictive accuracy, ensuring safer coal mining operations. Full article

Two-dimensional transition metal carbides/nitrides (MXenes) have shown potential in biosensors, cancer theranostics, microbiology, electromagnetic interference shielding, photothermal conversion, and thermal energy storage due to their unique electronic structure, ability to absorb a wide range of light, and tunable surface chemistry. In spite of the growing interest in MXenes, there are relatively few studies on their applications in phase-change materials for enhancing thermal conductivity and weak photo-responsiveness between 0 °C and 150 °C. Thus, this study aims to provide a current overview of recent developments, to examine how MXenes are made, and to outline the combined effects of different processes that can convert light into heat. This study illustrates the mechanisms that include enhanced broadband photon harvesting through localized surface plasmon resonance, electron–phonon coupling-mediated nonradiative relaxation, and interlayer phonon transport that optimizes thermal diffusion pathways. This study emphasizes that MXene-engineered 3D thermal networks can greatly improve energy storage and heat conversion, solving important problems with phase-change materials (PCMs), like poor heat conductivity and low responsiveness to light. This study also highlights the real-world issues of making MXene-based materials on a large scale, and suggests future research directions for using them in smart thermal management systems and solar thermal grid technologies. Full article

Rock slopes containing weak interlayers are highly prone to instability under the disturbance of blasting vibrations due to the influence of structural planes. To address the limitations of traditional models in predicting vibration attenuation for such slopes, this study conducted in situ blasting tests on sand–mudstone interbedded slopes from the Pinglu Canal project. Based on dimensional analysis, the Sadowsky formula was modified to incorporate both elevation difference (H/R) and soft interlayer dip angle (θ), resulting in an enhanced predictive model. Field data revealed that the proposed model significantly improved prediction accuracy, with determination coefficients (r²) increasing from 0.847 to 0.9946 in the vertical (Z) direction. Compared to traditional models, the root mean square error (RMSE) decreased by 96%, demonstrating superior capability in capturing vibration attenuation influenced by geological heterogeneity. Key findings reveal that steeper interlayer dip angles significantly accelerate PPV attenuation, particularly in the X direction. These findings provide a critical tool for optimizing blasting parameters in layered rock slopes, effectively mitigating collapse risks and enhancing construction safety. The model’s practicality was validated through its application in the Pinglu Canal project, offering a paradigm for similar engineering challenges in complex geological settings. Full article

A new brazing process for thin-walled stainless steel was proposed by combining green and efficient Ni-Cr-P electrodeposition with brazing technology. Novel information was attained by analyzing the electrodeposited Ni-Cr-P interlayers and the brazed joints and characterizing them using a combination of advanced techniques. The incorporation mechanisms of impurities (i.e., oxygen and carbon) in the Ni-Cr-P interlayers electrodeposited from a Cr(III)–glycine solution were revealed. The oxygen mainly came from the Cr(III)–hydroxy complexes formed by the hydrolysis and olation between Cr(III) complexes and OH⁻ ions near the cathode. Glycine did not directly participate in the cathode reactions but decomposed on the anode surface. These byproducts (carbonyl compounds) were directly incorporated into the interlayers in a molecular pattern, forming a weak link to the metallic chromium. Brazing test results showed that a certain amount of Cr₂O₃ powder, formed by the decomposition of chromium hydroxides in the interlayers under high-temperature catalysis, would cause the degradation of the brazed joints. Using the step-wise brazing method, the brazing sheets were first annealed to eliminate the impurities by utilizing the strong reducing effect of hydrogen and the weak link characteristics between carbonyl compounds and metallic chromium atoms. An excellent joint with a shear strength of 63.0 MPa was obtained by subsequent brazing. The microstructural analysis showed that the brazed seam was mainly composed of a Ni-Fe-Cr solid solution, the Ni₃P eutectic phase, and small quantities of the Ni₅P₂ phase scattered in the Ni₃P eutectic phase. Fracture mode observations showed that the cracks extended along the interface between the brittle P-containing phase and the primary phase, resulting in fracture. Full article

The experimental study of shale fracture development is very important. As a channel of permeability, a fracture has a great influence on the development of shale gas. This study presents the results of a fracture evaluation in the Silurian Longmaxi Shale using the laboratory triaxial compression experiments and CT reconstruction, considering both mechanical properties and fracture network multi-dimensional quantitative characterization. The results indicate that the plastic deformation stage of shale lasts longer under high confining pressure, whereas radial deformation is restricted. Confining pressure has a nice linear connection with both compressive strength and elastic modulus. The 2D fractal dimension of radial and vertical cracks is 1.09–1.28 when the confining pressure is between 5 and 25 MPa. The 3D fractal dimension of the fracture is 2.08–2.16. There is a linear negative correlation at high confining pressure (R² > 0.80) and a weak linear association between the 3D fractal dimension of the fracture and confining pressure at low confining pressure. The fracture angle calculated by the volume weight of multiple main cracks has a linear relationship with the confining pressure (R² > 0.89), and its value is 73.90°–52.76°. The fracture rupture rate and fracture complexity coefficient are linearly negatively correlated with confining pressure (R² > 0.82). The Euler number can well characterize the connectivity of shale fractures, and the two show a strong linear positive correlation (R² = 0.98). We suggest that the bedding plane gap compression, radial deformation limitation, and interlayer effect weakening are efficient mechanisms for the formation of shale fracture networks induced by confining pressure, and that confining pressure plays a significant role in limiting and weakening the development of shale fractures, based on the quantitative characterization results of fractures. Full article

This study presents a precise and efficient methodology for evaluating the water-richness of the aquifer overlying the No. 3 coal seam in Hancheng Mine. A comprehensive assessment model was developed by integrating subjective and objective weighting through the sequential relationship analysis–entropy value method. This model facilitated the delineation of water-richness zones within the sandstone aquifer of the Shanxi Group associated with the No. 3 coal seam. Five key evaluation indices were selected based on the aquifer’s water-richness index: core recovery rate, thickness of water-rich sandstone, number of sand–mudstone interlayers, sandstone lithology coefficient, and the thickness ratio of brittle to plastic rock. Furthermore, an advanced evaluation model combining set pair analysis and variable fuzzy sets was established to assess the water-richness risk levels across the entire Hancheng mining area. The results reveal distinct spatial patterns in water-richness: the northeastern region exhibits strong water-richness, while the southwestern area is characterized by medium to weak water-richness over a broad expanse. Overall, the No. 3 coal seam in the Hancheng mining area is classified as having a medium risk level of water-richness. Full article