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Molecules 2013, 18(8), 9850-9900; doi:10.3390/molecules18089850

Breathing Some New Life into an Old Topic: Chalcogen-Nitrogen π-Heterocycles as Electron Acceptors

1
Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, 630090 Novosibirsk, Russia
2
Department of Physics, National Research University—Novosibirsk State University, 630090 Novosibirsk, Russia
3
Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia
4
Institute of Organic Chemistry, Russian Academy of Sciences, 630090 Novosibirsk, Russia
Dedicated to the memory of Prof. Charles W. Rees (1927–2006).
*
Author to whom correspondence should be addressed.
Received: 3 July 2013 / Revised: 13 August 2013 / Accepted: 14 August 2013 / Published: 16 August 2013
(This article belongs to the Special Issue Chalcogen-Nitrogen Chemistry)

Abstract

Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts—candidate building blocks of molecule-based electrical and magnetic functional materials. View Full-Text
Keywords: organic electron acceptors; radical-anion salts; charge-transfer complexes organic electron acceptors; radical-anion salts; charge-transfer complexes
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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Lonchakov, A.V.; Rakitin, O.A.; Gritsan, N.P.; Zibarev, A.V. Breathing Some New Life into an Old Topic: Chalcogen-Nitrogen π-Heterocycles as Electron Acceptors. Molecules 2013, 18, 9850-9900.

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