Development of Palladium and Platinum Decorated Granulated Carbon Nanocomposites for Catalytic Chlorate Elimination
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Characterization Techniques
2.3. Synthesis of the Nitrogen-Doped Bamboo-Like Carbon Nanotubes (N-BCNTs)
2.4. Preparation of Catalyst Supports and Pd-Pt Containing Catalysts
2.5. Catalytic Hydrogenation of Chlorate Ions
3. Results and Discussion
3.1. Characterization of the Catalyst Supports
3.2. Characterization of the Noble Metal Containing Catalysts
3.3. Comparison of the Catalytic Activity of the Developed Catalysts in Chlorate Hydrogenation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Sample | SSA (m2/g) |
---|---|
Pd-Pt/GCNC | 75 |
Pd-Pt/GCNC 5× used | 81 |
Pd-Pt/Ni-GCNC | 214 |
Pd-Pt/Ni-GCNC 5× used | 192 |
Pd-Pt/Fe-GCNC | 177 |
Pd-Pt/Fe-GCNC 5× used | 179 |
Weight % | |||||
---|---|---|---|---|---|
Ca | Fe | Ni | Pd | Pt | |
GCNC | 2.66 ± 0.22 | - | 3.87 ± 0.21 | - | - |
Ni-GCNC | - | - | 21.66 ± 0.77 | - | - |
Fe-GCNC | - | 17.76 ± 0.36 | 3.23 ± 0.11 | - | - |
Pd-Pt/GCNC | 2.11 ± 0.13 | - | 3.56 ± 0.10 | 3.03 ± 0.18 | 0.38 ± 0.03 |
Pd-Pt/GCNC5× used | 0.24 ± 0.01 | - | 3.16 ± 0.16 | 3.54 ± 0.22 | 0.42 ± 0.02 |
Pd-Pt/Ni-GCNC | - | - | 21.07 ± 0.55 | 2.68 ± 0.42 | 0.45 ± 0.01 |
Pd-Pt/Ni-GCNC5× used | - | - | 12.72 ± 0.86 | 1.41 ± 0.11 | 0.15 ± 0.01 |
Pd-Pt/Fe-GCNC | - | 13.69 ± 4.27 | 3.19 ± 0.25 | 2.38 ± 0.28 | 0.28 ± 0.03 |
Pd-Pt/Fe-GCNC5× used | - | 9.20 ± 0.89 | 3.22 ± 0.12 | 1.64 ± 0.16 | 0.20 ± 0.02 |
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Sikora, E.; Muránszky, G.; Kristály, F.; Fiser, B.; Farkas, L.; Viskolcz, B.; Vanyorek, L. Development of Palladium and Platinum Decorated Granulated Carbon Nanocomposites for Catalytic Chlorate Elimination. Int. J. Mol. Sci. 2022, 23, 10514. https://doi.org/10.3390/ijms231810514
Sikora E, Muránszky G, Kristály F, Fiser B, Farkas L, Viskolcz B, Vanyorek L. Development of Palladium and Platinum Decorated Granulated Carbon Nanocomposites for Catalytic Chlorate Elimination. International Journal of Molecular Sciences. 2022; 23(18):10514. https://doi.org/10.3390/ijms231810514
Chicago/Turabian StyleSikora, Emőke, Gábor Muránszky, Ferenc Kristály, Béla Fiser, László Farkas, Béla Viskolcz, and László Vanyorek. 2022. "Development of Palladium and Platinum Decorated Granulated Carbon Nanocomposites for Catalytic Chlorate Elimination" International Journal of Molecular Sciences 23, no. 18: 10514. https://doi.org/10.3390/ijms231810514