Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
Abstract
:1. Introduction
2. Results
3. Materials and Methods
3.1. Monomer Synthesis: Thiol-ene Addition of Cysteamine to Methyl Oleate
3.2. General Procedure for Polymerizations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | mol% Catalyst a | Ratio MO-cys:DA | Temp (°C) | Time (h) | Conversion b (%) | DP b |
---|---|---|---|---|---|---|---|
1 | CalB | 0.004 | 1:0 | 80 | 20 | >85 | >6 |
2 | CalB | 0.004 | 1:0 | 140 | 20 | >95 | >20 |
3 | TBD | 5 | 1:0 | 80 | 20 | >85 | >6 |
4 | TBD | 5 | 1:0 | 140 | 20 | >95 | >20 |
5 | CalB | 0.004 | 2:1 | 80 | 4 | >98 | 2 |
6 | CalB | 0.004 | 4:1 | 80 | 4 | >98 | 4 |
7 | - c | - | 1:0 | 80 | 20 | 20 | - |
8 | - c | - | 1:0 | 140 | 20 | 30 | - |
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Finnveden, M.; Hendil-Forssell, P.; Claudino, M.; Johansson, M.; Martinelle, M. Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides. Polymers 2019, 11, 1730. https://doi.org/10.3390/polym11111730
Finnveden M, Hendil-Forssell P, Claudino M, Johansson M, Martinelle M. Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides. Polymers. 2019; 11(11):1730. https://doi.org/10.3390/polym11111730
Chicago/Turabian StyleFinnveden, Maja, Peter Hendil-Forssell, Mauro Claudino, Mats Johansson, and Mats Martinelle. 2019. "Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides" Polymers 11, no. 11: 1730. https://doi.org/10.3390/polym11111730