Resources, Volume 12, Issue 1 (January 2023) – 16 articles

Due to the large volume and mass of materials used, the construction industry is one of the sectors with the highest environmental impact. However, to provide good quality, affordable, and low-energy housing, the business case must be maintained. Accordingly, we aimed to develop and test a calculator to measure the ecological footprint of the embodied carbon in materials used in construction projects in a standardized way, without the need for environmental or even civil engineering expertise, and thus in a way that is accessible to SMEs. The novelty of our research is that although there are calculators for measuring the environmental impact (e.g., carbon footprint) of the construction industry, and there is a methodology for calculating the ecological footprint of construction, there is no free, easy-to-use, online calculator for calculating the ecological footprint of embodied carbon in materials available to all enterprises. In other words, this approach extends our previously developed corporate ecological footprint calculator with the environmental impacts of material usage. The study summarises the baseline research for an ecological footprint calculator, tested on two new condominium buildings and the energy renovation of five condominium buildings, built with a prefabricated technology typical in Hungary and other post-socialist countries. Based on our results and in accordance with former literature sources, most of the ecological footprint of new construction projects is determined by materials with high mass and volume, in particular, concrete, steel, and masonry; so it is not necessary to take into account all construction materials in a calculator in a detailed way. We also conclude that renovation and ongoing maintenance, as well as preservation, are recommended for structurally sound buildings, as embodied carbon in materials in the case of an energy upgrade of an existing condominium building has an environmental impact of 0.3–0.8 global hectares per dwelling, depending on the technical content, while in the construction of a new building, this value is between 10.49–14.22 global hectares. Our results can help investors and clients in their decisions, and policymakers in determining urban development directions. Full article

Las Loras UNESCO Global Geopark (UGGp) is geologically diverse, particularly in relation to water-derived features: springs, karst springs, travertine buildings, waterfalls, caves. In this work, the interactions between geology, geomorphology, structures and hydrogeology are analyzed. As a result of this study, a first conceptual model of the hydrogeological functioning at Las Loras UGGp is presented. The most plausible hypothesis is that the system is formed by two superimposed aquifer systems, separated by an aquitard formed by Lower Cretaceous material. The deep lower aquifer formed by the Jurassic limestones only outcrops on the northern and southern edges of the Geopark and in a small arched band to the south of Aguilar de Campoo. It forms a basement subject to intense deformation. The upper aquifer system, formed by outcropping materials from the Upper Cretaceous, is a free aquifer. It is formed by a multilayered aquifer system that is highly compartmentalized, constituting individual moorland and lora units acting as a separate recharge–discharge system. This model explains the base level of the permanent rivers and the abundant springs, important components of the water cycle and representing a contribution to the rich geological heritage of the location. Full article

The Atlantic margin of South America is considered passive and stable. However, there are some local points of discordance within the Brazilian coastal region with more than 7490 km of extension, where there is only one tectonic relief. These sites are located in a marginal sedimentary basin in which there is a small area of Quaternary tectonic relief, which makes it scientifically relevant at an international level. The present work proposes using two methods for quantifying the geomorphological heritage of this area. The main difference between the methods is the use of aesthetic values together with scientific ones as central values in one of the methods, while the other method focuses only on scientific values. The quantitative evaluation performed here allowed for the identification of seven geomorphosites with one method and only four with the other. Considering the results obtained, meetings were held with civil society and with the state and local municipalities which presented the possibility of creating a geopark, given the area’s importance for understanding the history of the Earth and potential as a priority area for geoconservation. Full article

Biomass has a high potential to contribute towards resolving the energy deficit. Processing biomass into solid fuels enhances its use in various bioenergy conversion technologies. The quality of densified biomass depends on several variables. The investigation of the effect of densification parameters on briquette quality is necessary for process optimization. This study investigates the influence of die temperature (100, 120, 140 °C) and feeding speed (2.4, 2.9, 3.3 mm s⁻¹) on the quality of briquettes produced from poplar using a hydraulic biomass briquetting machine. The density of the briquettes ranged between 746.7 and 916.8 kg m⁻³, the mechanical durability ranged from 97.4 to 98.4%, and the water resistance index was between 91.6 and 96.1%. The results show that the temperature was statistically significant (p < 0.05) on the density, mechanical durability and water resistance of biomass briquettes. The feeding speed was statistically significant (p < 0.05) on the density and water resistance. The interaction of temperature and feeding speed was statistically significant (p < 0.05) on all properties considered. The results obtained in this study are useful for optimizing the quality of briquettes produced using the hydraulic piston press. Full article

This study focused on bio-oil production by thermochemical liquefaction. For the reaction, the burnt pine heartwood was used as feedstock material, 2-Ethylhexanol (2-EHEX) was used as a solvent, p-Toluenesulfonic acid (pTSA) was used as a catalyst, and the solvent for washing was acetone. The procedure consisted of a moderate-acid-catalysed liquefaction process, and it was applied at three different temperatures, 120, 140, and 160 °C, and at 30, 105, and 180 min periods with 1%, 5.5%, and 10% (m/m) catalyst concentration of overall mass. Optimal results showed a bio-oil yield of 86.03% and a higher heating value (HHV) of 36.41 MJ/kg, which was 1.96 times more than the HHV of the burnt pine heartwood. A reaction surface methodology (Box–Behnken design) was performed for the liquefaction reaction optimisation. Reaction temperature, reaction time and catalyst concentration were chosen as independent variables. The obtained model showed good results with a high adjusted R-squared (0.988) and an excellent p-value (less than 0.001). The liquefied products were characterised by Fourier Transformed Infrared (FTIR) and thermogravimetric analysis (TGA), and also Scanning electron microscopy (SEM) was carried out to validate the impact of the morphological changes on the surface area of the solid samples. This study shows an excellent opportunity to validate a method to upcycle woody wastes via acid-catalysed liquefaction. In particular, this approach is of great interest to produce bio-oil with a good yield, recovering part of the values lost during wildfires. Full article

The usage of plastic materials in our daily life is increasing day by day. These plastic materials are somehow beneficial for us, but the disposal of waste plastic materials has become a serious problem. The use of plastic not only enhances road construction but also helps extend the life of roads and improves the environment. Waste plastics use in roads increases durability and also reduces water retention. This research reviews the use of waste plastics in asphalt pavement. In this study, the properties such as Marshall stability, flow, resilient modulus, fatigue, etc., are studied to boost the usage of waste plastic in asphalt pavements. It is concluded that with the use of waste plastic in asphalt pavement, the quality of roads will be enhanced, and it will also be very beneficial for our environment. The other major advantage is that it will be very cost-effective for underdeveloped countries. Full article

In this paper, a novel application of industrial waste, namely red mud (RM), in the abatement of two malodorous and harmful sulfur compounds, dimethyl disulfide (DMDS) and methyl mercaptan (MM), is presented. The effects of calcination and activations with hydrochloric acid or a mixture of hydrochloric and orthophosphoric acid on the properties and performance of RM are compared using laboratory-scale experiments. The RM-based materials were characterized by XRF, XRD, FE-SEM, N₂-physisorption, TGA/DTA, and FTIR analyses. RM exhibits very promising catalytic properties in the abatement of both DMDS and MM. The hydrochloric acid-activated RM was the most active in both cases, which was explained by its rather high specific surface area (144 m² g⁻¹), higher contents of Fe₂O₃ and TiO_2, as well as lower content of phosphorus. For both DMDS and MM, the main oxidation products were sulfur dioxide, carbon monoxide, and carbon dioxide. DMDS was observed as a reaction intermediate in MM oxidation. While the final conversions of DMDS and MM were high, the oxidation was not complete, indicated by the formation of carbon monoxide. Nevertheless, the modified RM appears as a very interesting alternative to the existing DMDS and MM abatement catalysts. Full article

The challenge of achieving and measuring urban water sustainability is hard because of its complex nature. The sustainability of urban drinking water system (UDWS) is no exception, as integration of technical, environmental, social, economic, and institutional elements of sustainability is defying and perplexing in terms of its application and evaluation. This paper deals with the technical aspects related to the design, construction, operation, and maintenance factors of a UDWS. Measurement of the status of such factors is almost impossible in generic formats. Therefore, a list of measurable sub factors was developed through an extensive literature survey and refined by involving appropriate stakeholders. This led to the development of a hierarchy from criteria to factors and from factors to sub factors, making a case for the utilization of an analytic hierarchy process (AHP) for multicriteria analysis (MCA). Appropriate stakeholders were included in this research to address the issues for which there were major gaps in the literature. A set of guidelines were developed for the evaluation of the status of various sub factors in a quantitative format. It is concluded that a trans disciplinary framework, the involvement of stakeholders, and guidelines for adopting appropriate processes and techniques may improve the sustainability of stressed urban water systems. Full article

The geodiversity of loess areas is reflected in the characteristic dataset of loess landforms, with the dominance of several types of valley forms (mainly gullies). The availability of satellite elevation data and high-resolution aerial topography scanning data provides an opportunity for quantitative assessment of geomorphodiversity. This is done through the analysis of topographic texture, delimitation and statistical characterization of the topographic parameters of erosional landforms, such as volume and degree of dissection (density of valleys) or the degree of ‘coverage’ of the area by valley forms. An important factor affecting the accuracy of the estimation is the accuracy of the underlying digital terrain model (DTM). This study compares three digital terrain models, with cell sizes of 30, 10 and 1 m, generated from satellite altimetry data and airborne laser scanning (ALS) data. The subregion of Szczebrzeszyn Roztocze (Western Roztocze Region, SE Poland), i.e., one of the most typical loess relief regions in Poland, was selected as the study area. Selected topographic texture analyses were carried out using the SLRM (Simple Local Relief Model) algorithm. Delimitation of valleys was performed by delineating the extent of slope change in two key steps: (1) detection of areas below the average topographic surface; (2) delimitation using supervised classification of DTMs. The results of the study show that the accuracy of delimitation of valleys increases inversely proportional to the DTMs resolution. Automated topographic texture analysis allows delimitation and extraction, as well as statistical analysis of parameters of valleys. Finally, two indicators have been proposed, Relative Valley Area (RVA) and Area-normalised Valley Cubature (AVC), which can be used in geomorphodiversity studies of a geologically homogeneous area. The dimensionless RVA index can also be expressed as a percentage (%) of the area of valley forms in a basic field of 1 km². Furthermore, the AVC index shows the dynamic character of the main relief features of the analysed area. Full article

The protective effect of olive mill pomace (OMP) loaded ethylcellulose microparticles as an alternative to synthetic antioxidants against the oxidation of olive oils was assessed. OMP extract was obtained by an optimized two-step solid-liquid extraction; encapsulation was performed by double emulsion solvent evaporation technique considering a theoretical loading content in phenolic compounds of 5% (w/w). The changes in the peroxide values, the p-anisidine values, the total oxidation values, the free fatty acids content, the total antioxidant activity, and the total phenolic content were synchronized under storage at 62 °C. The results of oxidative stability were compared with plain oils, oils enriched with synthetic antioxidants, and oils fortified with OMP extract. The encapsulation efficiency of phenolic compounds was 96.0 ± 0.3%. The fortification of olive oils with microparticles retarded the appearance of peroxides, reduced the content of secondary oxidation products, and slowed down hydrolysis processes. The microparticles were efficiently designed to sustain the release of antioxidants to control the oxidative status of oil samples, retarding the free fatty acids formation rather than synthetic antioxidants. The results of this study bring new perspectives regarding the potential use of encapsulated extracts rich in antioxidants as an alternative to synthetic antioxidants to improve oil oxidative stability. Full article

Organic farming is functionally integrated and serves as the foundation for circular agriculture. It guarantees resource efficiency in the deployment of nature-based initiatives to mitigate climate change. Organic farming is the most cost-efficient strategy for fighting climate change. Primarily the intensive generation of waste due to strong urbanization effects, the expression of consumer response is particularly powerful while purchasing organic items. This analysis’s major purpose is to examine which various aspects may be applied to consumers’ perspectives towards circular agriculture when buying organic foods. In this research, a well-constructed questionnaire was produced. Of the 1030 participants who participated in the survey, 1001 samples were examined. The major study question was, “Would the customer purchase organic food product that is good environment?” The second issue is, how do eco-label foods, knowledge about climate change, consumer education, and specific socio-demographic features impact the value of organic food consumption? According to the study’s findings, in the case of the studied customers, people’s concerns about climate change, trust, and eco-labels demonstrate a stronger preference for purchasing organic food. It is also a surprise that customer trust has a big effect on consumer buying intention. The new scientific result of the research is that, in the case of emerging countries, due to the significantly lower price level difference between organic products and traditional foods, the healthy properties of foods with an eco-label, as well as the communication of knowledge about climate change, have a significant effect on the level of consumption of organic foods. Full article

One of the factors limiting the possibility of the development of urban agglomerations is access to drinking water. Due to progressive climate change, the available water resources are limited. The paper proposes new indicators of limiting the development of agglomerations related to the availability of water resources and the production capacity of water treatment plants, a method for assessing the diversification of water resources (using the Pielou index), and a water loss balance was prepared based on International Water Association (IWA) standards. On the basis of the obtained results, the potential increase in the number of inhabitants indicators (∆P_R, ∆P_P) and the time for the development of agglomeration indicators (T_R, T_P), the directions of development of the studied agglomerations in terms of the possibility of water supply were indicated. The main problems were reducing the amount of water losses, appropriate management of the migration policy of the population, and the necessity to look for alternative sources of water. Full article

The most important raw material needed for food production is phosphorus (P), which cannot be replaced by other elements. P is listed as a Critical Raw Material (CRM) for the European Union (EU). It is an element essential for human nutrition and is used for fertiliser production. The key importance of P for human life is evidenced by the fact that if there were not enough P in fertilisers, we would only be able to feed 1/3 of the world’s population. Unfortunately, in Visegrad Group (V4) countries, Poland, Slovakia, Czech Republic, and Hungary, there is a lack of mineral deposits of phosphate rock. Therefore, there is a strong need to cover the demand for the P by importing from countries of varying stability, both economic and political, such as Russia, China, or Morocco. It is risky; if the borders for deliveries of goods are closed, it may be impossible to meet the needs of P. On the other hand, V4 countries have large secondary P resources in P-rich waste, which are lost due to P is not recovered on an industrial scale. The paper presents the importance of P raw materials in V4, the revision of primary and secondary P sources that can be used in agricultural systems, as well as the structure of import and export of P raw materials in these countries. In addition, examples of good phosphorus recovery practices in the V4 countries are presented. They include a list of initiatives dedicated to the sustainable management of P resources, and examples of P recovery projects. Implementation of P recovery for internal P-rich waste in V4 could ensure the safety of food production in this region. Such and similar initiatives may contribute to faster independence of the V4 countries from the import of P raw materials. Full article

With global efforts to mitigate climate change lagging behind what is necessary to achieve Paris Agreement global warming targets, global mean temperatures are increasing, and weather extremes are becoming more frequent and more severe. When mitigation falters, adaptation to current and anticipated future climate conditions becomes increasingly urgent. This study provides a novel collection of adaptive capacity and adaptation readiness indicators, which it aggregates into a composite adaptation index to assess the relative adaptation performance of nations. Adaptation performance is assessed using two complementary techniques, a distance to frontier analysis and a dominance analysis. Developed countries perform relatively well and developing countries perform relatively poorly in both exercises. Adaptation performance is found to be closely and positively related to both national income per capita and greenhouse gas emissions per capita, highlighting the inequities of global adaptation performance. These adaptation inequities are consistent with the IPCC assessment that nations most affected by climate change are those that are least able to adapt and contribute least to the problem, creating a need for assistance from developed countries. Full article