Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)
Abstract
:1. Introduction
2. Metal Complexes with Substituted Derivatives of Boron Cluster Anions
2.1. Halogen Atoms
2.2. Hydroxy Substituent
2.3. Ammonium Substituents
2.4. Amino Group
2.5. Sulfonium Group
2.6. Sulfanyl Group
2.7. Oxonium Substituents
2.8. Opening of the Cyclic Substituent
2.9. S-thiocyanato Substituents
2.10. Diazo Substituents
2.11. Cyano-Substituents
2.12. Azaheterocycles as Substituents
2.13. Carboxy Groups as Substituents
2.14. Amide Groups as Substituents
2.15. Phthalocyanine Derivatives as Substituents
3. Metal Complexes with B-Substituted Derivatives of Carboranes
3.1. Derivatives with B–Hal Bonds
3.2. Derivatives with B–S Bonds
3.3. Derivatives with B–N Bonds
3.4. Derivatives with B–O Bonds
4. Conclusions
- (a)
- Metal complexes with substituted derivatives as counterions
- (b)
- Metal complexes with coordinated substituted derivatives
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Boron Cluster Anion as a Counterion | Coordination with the Formation of 3c2e MHB Bonds | Coordination by a Substituent | Combined Coordination: MHB + Substituent |
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[Ni(Bipy)3][B10H9OH] [Ni(Phen)3][B10H9OH] [Ni(Bipy)3][B12H11Cl] [Co(Phen)3][2-B10H9OC(H)O] [CuII(BPA)2(NCCH3)2][2-B10H9BPA]2 [CuII2(bipy)4(µ-CO3)][2-B10H9OH] [Ag(PPh3)4][B10H9NH3] [Ag(PPh3)4][2-B10H9S(CH2N(CO)2C6H4)2] [Ag(PPh3)4][2-B10H9O(CH2)5] [Ag(PPh3)4][2-B10H9O(CH2)4O] | [Et3NH][CuI[1-B10H9N2]2] [Ag(CH3CN)3]2[Ag2[2-B10H9F]2]n [Ag(PPh3)4][(PPh3)2Ag[B10H9Cl]] [Ag2(Ph3P)4[B12H11Cl]] [Ag2(Bipy)2[2-B10H9SH]] [Ag2(Bipy)2[2-B10H9S(CH2C(O)NH2]NO3 (Bu4N)[[(o-C6F4Hg)3]2[B12H11SCN]] (Bu4N)2[[(o-C6F4Hg)3][B12H11SCN]] [(PPh3)2ClRu[B12H11(NEt3)] [Pb[2-B10H9SH]] [Pb(Bipy)2[2-B10H9SH]] [Pb(Bipy)2[1-B10H9SMe2]2] | [Ph3MeP)]2[CpTiCl2[B12H11OH] [Ni(en)[2-B10H9O(CH2)2O(CH2)2NH(CH2)2NH2)]] [Na6(THF)15][Ni[B12H11NH2]]4 [Au(PPh3)[NH2–B12H11]] [RuH2[N2B10H8SMe2](Ph3P)3] [Ru[SB12H11](NH3)5] [(Cp)(dppe)Fe}2[1,10-B10H8(NC)2]·H2O phthalocyanine Al(III), Co(II), Zn(II) complexes Gd(III) and Hf(IV) complexes | [CuI(NCCH3)2[2-B10H9Bipy]] [Ag2(Ph3P)4[B10H9C(O)OCH3]] (Ph4P)2[Pb(Bipy)[2-B10H9OC(O)CH3]2]] [Pb(Bipy)[2-B10H9O(CH2CH2)2OEt]] [Pb(Bipy)(DMF)[2-B10H9OH)]] [Pb(Bipy)(2-B10H9(OCH2CH2)2OEt)] [Pb(Bipy)(DMF)[B10H9OH] [Pb(Bipy)2[2,6(9)-B10H8(OC(O)CH3)(OH)]]2 [Pb(Bipy)2[2,7(8)-B10H8(OC(O)CH3)2)] Bu3MeN[Ru(PPh3)2Cl[B12H11NH2]] Bu4N[Ru(dppb)Cl[B12H11NH2]] [Ru(PPh3)2CO[B12H11NH2]] MePPh3[Rh(PPh3)2[B12H11NH2]] [Rh(Me5Cp)[B12H11NHC(O)NMe2]] [Rh(Me5Cp)[B12H11NHC(O)Ph]] |
Boron Cluster Anion as a Counterion | Coordination with the Formation of 3c2e MHB Bonds | Coordination by a Substituent | Combined Coordination: MHB + Substituent |
---|---|---|---|
[Pd(dppe)2][CB11H11Cl]2]·3CH2Cl2 [(POCOP)Pd(C6D5Br)][HCB11Cl10OTf] [Ru(CH3CN)6][CB11H6Br6] [RhL][CB11H6Cl6] [RhL][CB11H6Br6] (L = diphenylphosphine ligands) [Co(Cp)2][1,2-(3-Ph-1-CH3-3-N3)-1-CB11Cl10] | [Ag(C6H6)2[12-CB11H11F]] [Ag(C6H6)2][6,8-CB9H8F2] | [Ag(C6H6)[12-CB11H11Br]] [MoCp(CO)3(CB11H11Br)] [Ir(PPh3)2H2(1-CB11H6Cl6)] [Cp*Ir{9,10-S2C2(B10H10)}] [Cp*Ir(R3P){9,10-S2C2(B10H10)}] [Cp*Co{9,12-S2C2B10H10}] [Cp*Rh{9,12-S2C2B10H10}] [cis-Rh(Ph2PCH2CH2S-{9-1,7-C2B10H11})2]Cl [cis-Pt(Ph2PCH2CH2S-{1-CB11H11})2] [cis-Pt(Ph2PCH2CH2S-{9-closo-1,7-C2B10H11})Cl2] [cis-Pt(Ph2PCH2CH2S-{9-closo-1,7-C2B10H11})2](BF4)2 [Au2(Ph3P)2S{9,12-S2C2B10H10] [Cu-S-9-closo-1,7-C2B10H11]4 [PdCl2(Ph2PCH2PPh2CN)9B10C2H11] [Re(CO)3L2Br] (L = 3-CN-1,2-B10C2H10] {[(POCOP)Pd][HCB11Cl10OTf]} | [MoCp(CO)3IAg(CB11H11Br)]2 |
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Matveev, E.Y.; Avdeeva, V.V.; Zhizhin, K.Y.; Malinina, E.A.; Kuznetsov, N.T. Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal). Inorganics 2022, 10, 238. https://doi.org/10.3390/inorganics10120238
Matveev EY, Avdeeva VV, Zhizhin KY, Malinina EA, Kuznetsov NT. Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal). Inorganics. 2022; 10(12):238. https://doi.org/10.3390/inorganics10120238
Chicago/Turabian StyleMatveev, Evgenii Yu., Varvara V. Avdeeva, Konstantin Yu. Zhizhin, Elena A. Malinina, and Nikolay T. Kuznetsov. 2022. "Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)" Inorganics 10, no. 12: 238. https://doi.org/10.3390/inorganics10120238