The Coordination Chemistry of Imidomethanedithiolate Di-anions: A Structural Comparison with Their Dithiocarbamate Analogs
Abstract
:1. Introduction
2. General Aspects of Dithiocarbimate Ligands
3. Crystal Structures: Analysis of CSD Data
3.1. Coordination Chemistry of Dithiocarbimate Di-Anions
3.1.1. Cr Group
3.1.2. Mn Group
3.1.3. Fe Group
3.1.4. Co Group
3.1.5. Ni Group
3.1.6. Cu Group
3.1.7. Actinides
3.1.8. Main Group Elements
3.2. Comparison between Dithiocarbimate and Dithiocarbamate Structures
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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No. | Formulation | M–S (Å) | CSD Refcode | Ref. |
---|---|---|---|---|
10 | [AsPh]2{Ni[S2C=N(CN)]2} | 2.19 and 2.19 | PASCNN | [21] |
11 | [NBu4]2{Ni[S2C=N(C6H4CN-4)]2} | 2.20 and 2.20 | NILTOR | [33] |
12 a | (dppe)Ni[S2C=N(CN)] | 2.20 and 2.21 | PEZTIA | [34] |
2.22 and 2.22 | ||||
13 | [Ph4P]2{Pd[S2C=N(CN)]2} | 2.31 and 3.33 | BENKEL | [19] |
2.32 and 2.32 | ||||
14 | [NBu4]2{Pd[S2C=N(C6H4NH2-4)]2} | 2.31 and 3.33 | ZUNFOD | [23] |
15 | (Me3P)2Pd[S2C=N(Ph)] | 2.31 and 2.34 | EJUGAS | [35] |
16 | (Et3P)2Pd[S2C=N(CH2Ph)] | 2.31 and 2.33 | CICKII | [22] |
17 | (Me2PhP)2Pt[S2C=N(Ph)] | 2.32 and 2.33 | EJUGEW | [35] |
18 | (Ph3P)2Pd[S2C=N(C(=O)OEt)] | 2.32 and 2.34 | PECTPD | [36] |
19 | (Ph3P)2Pd[S2C=N(2-py)] | 2.32 and 2.33 | QAHQUN | [37] |
20 | (Et3P)2Pt[S2C=N(CH2Ph)] | 2.33 and 2.34 | CICKEE | [22] |
21 | (Me2PhP)2Pt[S2C=N(Ph)] | 2.34 and 2.34 | EGULUO | [38] |
22 | (Me2PhP)2Pt[S2C=N(CN)] | 2.35 and 2.36 | BENKIP | [19] |
23 | (Ph3P)2Pt[S2C=N(Me)] | 2.32 and 2.34 | SOQYEC | [39] |
24 a,b | (Et2P(CH2)2PEt2)Pd[S2C=N(CH(Me)Ph)] | 2.32 and 2.34 | NOQZEA | [40] |
2.33 and 2.33 | ||||
25 a,c | (Et2P(CH2)2PEt2)Pd[S2C=N(CH(Me)Ph)] | 2.32 and 2.33 | NOQZIE | [40] |
2.33 and 2.33 | ||||
26 | (Ph2P(CH2)3PPh2)Pt[S2C=N(Ph)].CH2Cl2, H2O | 2.34 and 2.34 | EGUMAV | [38] |
27 | (dppf)Pt[S2C=N(CN)] | 2.34 and 2.35 | BENKOV | [19] |
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Heard, P.J.; Tan, Y.S.; Yeo, C.I.; Tiekink, E.R.T. The Coordination Chemistry of Imidomethanedithiolate Di-anions: A Structural Comparison with Their Dithiocarbamate Analogs. Inorganics 2021, 9, 71. https://doi.org/10.3390/inorganics9090071
Heard PJ, Tan YS, Yeo CI, Tiekink ERT. The Coordination Chemistry of Imidomethanedithiolate Di-anions: A Structural Comparison with Their Dithiocarbamate Analogs. Inorganics. 2021; 9(9):71. https://doi.org/10.3390/inorganics9090071
Chicago/Turabian StyleHeard, Peter J., Yee Seng Tan, Chien Ing Yeo, and Edward R. T. Tiekink. 2021. "The Coordination Chemistry of Imidomethanedithiolate Di-anions: A Structural Comparison with Their Dithiocarbamate Analogs" Inorganics 9, no. 9: 71. https://doi.org/10.3390/inorganics9090071