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Metal Oxides in Energy Technologies

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Nanotechnology and Applied Nanosciences".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 6011

Special Issue Editors


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Guest Editor
Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy
Interests: photovoltaics; metal oxides; perovskites; thin film processing

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Guest Editor
Center for Materials Research (LaMa), Justus Liebig University, 35390 Giessen, Germany
Interests: functional materials for energy conversion and optoelectronics; 2D materials

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Guest Editor
Optical and Vibrational Spectroscopy Lab, Department of Engineering for Innovation Medicine, University of Verona, Ca' Vignal 2, Strada Le Grazie 15, 37134 Verona, Italy
Interests: nanostructured materials; rare-earth ions; luminescent materials; optical films and coatings; materials for energy applications; solar cells; lighting
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Special Issue Information

Dear Colleagues,

Metal oxides (MOs) are cutting-edge materials in next-generation energy devices. Due to their chemical stability, physical and electronic versatile properties, ease of processability, MO applications span from photovoltaics to energy concentrators/accumulators and photocatalytic systems for the production of solar fuels. The interest in these materials emerged when the effective chemical doping of insulating oxides was made possible, leading to the realization of the key materials for (opto)electronics named transparent conducting oxides (TCOs). This fundamental step forward has allowed the integration of MO into the semiconductor manufacturing industry, with multiple uses in diodes, PN junctions, LEDs, and solar cells. In particular, last-generation ultra-cheap solar cells have gained great advantages from the use of TCO as electrodes, due to their favorable energetic alignment for both electron and hole collection, leading to power-to-conversion efficiencies similar to established silicon-based technologies. MOs band engineering can further be exploited for promoting highly sustainable photocatalytic processes like water splitting or CO2 reduction, which will allow the future transition of our society to a fully circular economy.

Additionally, metal-doped oxides can also play an important role in energy applications. Among them, rare-earth dopants are widely used for their optical properties in lasers, lighting and solar cells. Rare-earth ions have been used in phosphors for efficient and high-quality lighting devices, as well as in spectral conversion coatings to improve the matching of the solar incoming radiation with the solar cell’s absorption, increasing the overall photon-to-current conversion efficiency.

Within a similar scenario, we are convinced that MOs represent fundamental components of research in energy technologies and, therefore, this Special Issue will collect recent, outstanding contributions in different topics, including (but not limited to) MOs application in photovoltaics (with both established and novel concepts), solar-to-thermal conversion, photocatalysis, thermoelectrics, energy storage and lighting. In particular, manuscripts focusing on MO-based nanostructured semiconductors, binary and n-ary systems, perovskite-based structures, 2D, 1D, and 0D materials, heterojunctions, chemical and physical doping protocols, advanced optical, electrical properties, and morphological characterization techniques will be considered.

Original papers, communications, and topical/extended reviews are welcome to this Special Issue.

Dr. Francesco Lamberti
Dr. Teresa Gatti
Dr. Francesco Enrichi
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Applied Sciences is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Metal oxides
  • rare-earth doped oxides
  • semiconductors
  • chemical doping
  • transparent conductive oxides
  • energy applications

Published Papers (2 papers)

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Research

26 pages, 5177 KiB  
Article
Enhancing the Spectroelectrochemical Performance of WO3 Films by Use of Structure-Directing Agents during Film Growth
by Thi Hai Quyen Nguyen, Florian Eberheim, Sophie Göbel, Pascal Cop, Marius Eckert, Tim P. Schneider, Lukas Gümbel, Bernd M. Smarsly and Derck Schlettwein
Appl. Sci. 2022, 12(5), 2327; https://doi.org/10.3390/app12052327 - 23 Feb 2022
Cited by 5 | Viewed by 2172
Abstract
Thin, porous films of WO3 were fabricated by solution-based synthesis via spin-coating using polyethylene glycol (PEG), a block copolymer (PIB50-b-PEO45), or a combination of PEG and PIB50-b-PEO45 as structure-directing agents. The [...] Read more.
Thin, porous films of WO3 were fabricated by solution-based synthesis via spin-coating using polyethylene glycol (PEG), a block copolymer (PIB50-b-PEO45), or a combination of PEG and PIB50-b-PEO45 as structure-directing agents. The influence of the polymers on the composition and porosity of WO3 was investigated by microwave plasma atomic emission spectroscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy, X-ray diffraction, and gas sorption analysis. The electrochromic performance of the WO3 thin films was characterized with LiClO4 in propylene carbonate as electrolyte. To analyze the intercalation of the Li+ ions, time-of-flight secondary ion mass spectrometry, and X-ray photoelectron spectroscopy were performed on films in a pristine or reduced state. The use of PEG led to networks of micropores allowing fast reversible electrochromic switching with a high modulation of the optical transmittance and a high coloration efficiency. The use of PIB50-b-PEO45 provided isolated spherical mesopores leading to an electrochromic performance similar to compact WO3, only. Optimum characteristics were obtained in films which had been prepared in the presence of both, PEG and PIB50-b-PEO45, since WO3 films with mesopores were obtained that were interconnected by a microporous network and showed a clear progress in electrochromic switching beyond compact or microporous WO3. Full article
(This article belongs to the Special Issue Metal Oxides in Energy Technologies)
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13 pages, 2182 KiB  
Article
Work Function Tuning in Hydrothermally Synthesized Vanadium-Doped MoO3 and Co3O4 Mesostructures for Energy Conversion Devices
by Pietro Dalle Feste, Matteo Crisci, Federico Barbon, Francesca Tajoli, Marco Salerno, Filippo Drago, Mirko Prato, Silvia Gross, Teresa Gatti and Francesco Lamberti
Appl. Sci. 2021, 11(5), 2016; https://doi.org/10.3390/app11052016 - 25 Feb 2021
Cited by 11 | Viewed by 2970
Abstract
The wide interest in developing green energy technologies stimulates the scientific community to seek, for devices, new substitute material platforms with a low environmental impact, ease of production and processing and long-term stability. The synthesis of metal oxide (MO) semiconductors fulfils these requirements [...] Read more.
The wide interest in developing green energy technologies stimulates the scientific community to seek, for devices, new substitute material platforms with a low environmental impact, ease of production and processing and long-term stability. The synthesis of metal oxide (MO) semiconductors fulfils these requirements and efforts are addressed towards optimizing their functional properties through the improvement of charge mobility or energy level alignment. Two MOs have rising perspectives for application in light harvesting devices, mainly for the role of charge selective layers but also as light absorbers, namely MoO3 (an electron blocking layer) and Co3O4 (a small band gap semiconductor). The need to achieve better charge transport has prompted us to explore strategies for the doping of MoO3 and Co3O4 with vanadium (V) ions that, when combined with oxygen in V2O5, produce a high work function MO. We report on subcritical hydrothermal synthesis of V-doped mesostructures of MoO3 and of Co3O4, in which a tight control of the doping is exerted by tuning the relative amounts of reactants. We accomplished a full analytical characterization of these V-doped MOs that unambiguously demonstrates the incorporation of the vanadium ions in the host material, as well as the effects on the optical properties and work function. We foresee a promising future use of these materials as charge selective materials in energy devices based on multilayer structures. Full article
(This article belongs to the Special Issue Metal Oxides in Energy Technologies)
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