Oleogels and Organogels: A Promising Tool for New Functionalities

A special issue of Gels (ISSN 2310-2861).

Deadline for manuscript submissions: closed (28 February 2021) | Viewed by 7634

Special Issue Editors


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Guest Editor
International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal
Interests: food science; packaging; biopolymers; oleogels; controlled delivery systems
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Food Materials Science Research Group, Department of Food and Nutrition, Helsinki Institute of Sustainability Science (HELSUS), Helsinki, Finland
Interests: oleogel; aerogel; emulsion; high-energy emulsification; low-energy emulsification; hemicelluloses
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Guest Editor
National Institute of Technology Rourkela, Rourkela 769008, India
Interests: oleogels; hydrogels; bigels; emulgels; controlled delivery systems
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Special Issue Information

Dear Colleagues,

Organogels and Oleogels are semi-solid materials which contain a large fraction of organic solvents and liquid oil entrapped in a network of structuring molecules. Oleogels have been used for structuring edible oils, e.g., sunflower oil, wheat germ oil. These formulations are regarded as a particular class of organogels. Organogels are used for the gelification of organic solvents. These formulations appear as gels and solid-like structures that, according to the field of application, can be used to produce creams and mimic fats having a low amount of trans and saturated fatty acids. In the last decade, there has been an increasing interest in these structures, not only from a scientific point of view, i.e., studying new molecules and methodologies for the gelification, but also from a technological point of view, where researchers and companies have envisioned these structures as a way to overcome certain challenges and/or create new and innovative products. One of the exciting applications of oleogels is the delivery of functional molecules, where the incorporation of oil-soluble functional compounds can be explored. These can be performed not only at macroscale but also at micro- and nanoscale, resulting in different release behaviors and also different applications. Functionality can also be achieved by the replacement of saturated fats by unsaturated ones rich in omega-3 and omega-6 fatty acids.

This Special Issue will provide the possibility to researchers around the world to present and discuss the most recent works on the development, production, characterization, and applications of oleogels and organogels. It will be focused on oleogels and organogels to deliver functional molecules in food, cosmetic, and pharmaceutical applications. It should discuss the gelification mechanism of oleogels and organogels and the incorporation of functional compounds, but also their use for fat replacement.

Dr. Miguel Cerqueira
Dr. Fabio Valoppi
Prof. Dr. Kunal Pal
Guest Editors

Manuscript Submission Information

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Published Papers (2 papers)

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18 pages, 8125 KiB  
Article
Modulation and Characterization of Wax-Based Olive Oil Organogels in View of Their Application in the Food Industry
by Pedro M. Silva, Artur J. Martins, Luiz H. Fasolin and António A. Vicente
Gels 2021, 7(1), 12; https://doi.org/10.3390/gels7010012 - 28 Jan 2021
Cited by 15 | Viewed by 3305
Abstract
Olive oil has recognized health benefits but lacks structural resilience to act in a similar fashion as do the typically used triglycerides (TAGs) when applied in food manufacturing. Therefore, olive oil structuring is critical to widening its use as a healthier alternative in [...] Read more.
Olive oil has recognized health benefits but lacks structural resilience to act in a similar fashion as do the typically used triglycerides (TAGs) when applied in food manufacturing. Therefore, olive oil structuring is critical to widening its use as a healthier alternative in spreadable products. Foreseeing the development of an application for the food industry, three types of natural waxes were used as organogelators, generating olive oil organogels with distinct properties. Retail-simulated storage conditions were used to mimic real-life industrial and commercial use. Organogel systems were evaluated according to their oxidation stability and textural and rheological properties. Textural and rheological parameters increased in response to increasing gelator concentration, while oxidation values (below 1.5 meq O2·kg−1) remained within legal limits. Organogels displayed similar textural properties to those of commercially available spreadable products, while displaying a low critical gelation concentration. In short, it was shown that tailoring the physicochemical properties of organogels towards specific applications is possible. The produced organogels showed similar properties to the ones of commercially available spreadable products, revealing favourable oxidative profiles. Therefore, an industrial application can be easily foreseen, building on the natural characteristics of olive oil as a healthier alternative to current spreadable products. Full article
(This article belongs to the Special Issue Oleogels and Organogels: A Promising Tool for New Functionalities)
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26 pages, 9837 KiB  
Article
Graphene Oxide Increases Corneal Permeation of Ciprofloxacin Hydrochloride from Oleogels: A Study with Cocoa Butter-Based Oleogels
by Dilshad Qureshi, Barbiee Choudhary, Biswaranjan Mohanty, Preetam Sarkar, Arfat Anis, Miguel A. Cerqueira, Indranil Banerjee, Samarendra Maji and Kunal Pal
Gels 2020, 6(4), 43; https://doi.org/10.3390/gels6040043 - 23 Nov 2020
Cited by 5 | Viewed by 3398
Abstract
In this work, oleogels of cocoa butter (CB), rice bran oil (RBO), and graphene oxide (GO) were prepared. The prepared oleogels were subjected to various characterization techniques such as bright-field microscopy, X-ray diffraction (XRD), crystallization kinetics, differential scanning calorimetry (DSC), and mechanical studies. [...] Read more.
In this work, oleogels of cocoa butter (CB), rice bran oil (RBO), and graphene oxide (GO) were prepared. The prepared oleogels were subjected to various characterization techniques such as bright-field microscopy, X-ray diffraction (XRD), crystallization kinetics, differential scanning calorimetry (DSC), and mechanical studies. The influence of increasing GO content on the in vitro drug release and ex vivo corneal permeation of the model drug (ciprofloxacin HCl—CPH) from the oleogels was also investigated. Bright-field micrographs showed that increment in GO content reduced the size of the globular particles of CB. XRD analysis revealed that CB was crystallized in its β’ and β polymorphic forms in the oleogels, which was in agreement with thermal studies. The mechanical characterization demonstrated that the presence of GO improved the elastic nature and stress-bearing properties of the oleogels. Moreover, GO altered the crystallization kinetics of CB in the oleogels in a composition-dependent manner. The in vitro release of CPH from the oleogels occurred through either Fickian diffusion or fat network relaxation or a combination thereof. Furthermore, the inclusion of GO enhanced the ex vivo permeation of CPH molecules across the caprine cornea. Hence, we concluded that the prepared oleogels could be explored as potential delivery systems for ophthalmic applications. Full article
(This article belongs to the Special Issue Oleogels and Organogels: A Promising Tool for New Functionalities)
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