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Biomass-Derived Materials: Synthesis and Applications

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: 30 November 2024 | Viewed by 3115

Special Issue Editor


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Guest Editor
Institut UTINAM - UMR CNRS 6213, Université de Franche-Comté, 16 route de Gray, 25030 Besançon, France
Interests: heterocyclic chemistry; green chemistry; material science

Special Issue Information

Dear Colleagues,

In the 1990s, Anastas and Warner introduced the twelve principles of green chemistry as a set of guidelines to make chemical processes more sustainable. One of these principles is the use of renewable feedstocks, such as biomass, as a source of chemicals and materials. Biomass-derived materials can be raw materials extracted from biomass (such as biopolymers for example), materials obtained by means of the chemical modification of these raw materials and materials obtained from biomass-derived synthons (small molecules such as furan-derivatives for example) through synthesis. They find applications in many fields, such as medicine (e.g., drug delivery systems), consumer goods (e.g., packaging films), materials for water treatment (e.g., adsorbents for pollutants) or as catalysts, just to name a few. Owing to the vast molecular diversity of biomass-derived materials and molecules, there is no doubt that these renewable chemicals will be increasingly significant in the future of chemical and industrial processes. This Special Issue of the International Journal of Material Science will focus on such new biomass-derived materials, and we are seeking contributions underlying the recent findings in this field.

Dr. Jérôme Husson
Guest Editor

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Keywords

  • biomass
  • biomass-derived synthons
  • renewable chemicals
  • biopolymers
  • materials for water treatment
  • catalysts

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Published Papers (3 papers)

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Research

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19 pages, 2491 KiB  
Article
Exploring the Potential of Fungal Biomass for Bisphenol A Removal in Aquatic Environments
by Kamila Wlizło, Marek Siwulski, Beata Kowalska-Krochmal and Adrian Wiater
Int. J. Mol. Sci. 2024, 25(21), 11388; https://doi.org/10.3390/ijms252111388 - 23 Oct 2024
Viewed by 321
Abstract
Bisphenol A is a plastic component, which shows endocrine activity that is detrimental to humans and aquatic ecosystems. The elimination of BPA from the environment is one of the solutions for BPA contaminant management. Adsorption is a cost-effective, easy-to-use method generating low harmful [...] Read more.
Bisphenol A is a plastic component, which shows endocrine activity that is detrimental to humans and aquatic ecosystems. The elimination of BPA from the environment is one of the solutions for BPA contaminant management. Adsorption is a cost-effective, easy-to-use method generating low harmful byproducts; nevertheless, contaminant sorbent treatment is a challenge that still needs to be addressed. Fungal fruiting bodies biomass is rarely studied sorbent but is promising due to its high polysaccharide content and availability. Our preliminary studies showed BPA sorption (100 mg/L) by 50 cultivated and wild fungi. The cultivated species: Clitocybe maxima (82%), Pholiota nameko (77%), and Pleurotus columbinus (74%), and wild fungi Cantharellus cibarius (75%) and Lactarius deliciosus (72%) were the most efficient. The biomass was able to sorb BPA over a broad range of temperature and pH levels, with an optimum at 20 °C and pH 7. Although saturation of sorbents was rapid, the regeneration process using ethanol was effective and allowed to recover up to 75% of sorbents’ initial efficiency. A single use of 1 g of sorbent would allow the treatment of 8.86 to 10.1 m3 of wastewater effluent, 16.5 to 18.7 m3 of surface water, and 411 to 469 m3 of drinking water, assuming the concentrations of BPA reported in the literature. Full article
(This article belongs to the Special Issue Biomass-Derived Materials: Synthesis and Applications)
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26 pages, 7034 KiB  
Article
Bactericidal Chitosan Derivatives and Their Superabsorbent Blends with ĸ-Carrageenan
by Kamila Lewicka, Anna Smola-Dmochowska, Natalia Śmigiel-Gac, Bożena Kaczmarczyk, Henryk Janeczek, Renata Barczyńska-Felusiak, Izabela Szymanek, Piotr Rychter and Piotr Dobrzyński
Int. J. Mol. Sci. 2024, 25(8), 4534; https://doi.org/10.3390/ijms25084534 - 20 Apr 2024
Cited by 1 | Viewed by 1586
Abstract
The aim of this work is research dedicated to the search for new bactericidal systems for use in cosmetic formulations, dermocosmetics, or the production of wound dressings. Over the last two decades, chitosan, due to its special biological activity, has become a highly [...] Read more.
The aim of this work is research dedicated to the search for new bactericidal systems for use in cosmetic formulations, dermocosmetics, or the production of wound dressings. Over the last two decades, chitosan, due to its special biological activity, has become a highly indispensable biopolymer with very wide application possibilities. Reports in the literature on the antibacterial effects of chitosan are very diverse, but our research has shown that they can be successfully improved through chemical modification. Therefore, in this study, results on the synthesis of new chitosan-based Schiff bases, dCsSB-SFD and dCsSB-PCA, are obtained using two aldehydes: sodium 4-formylbenzene-1,3-disulfonate (SFD) and 2-pyridine carboxaldehyde (PCA), respectively. Chitosan derivatives synthesized in this way demonstrate stronger antimicrobial activity. Carrying out the procedure of grafting chitosan with a caproyl chain allowed obtaining compatible blends of chitosan derivatives with κ-carrageenan, which are stable hydrogels with a high swelling coefficient. Furthermore, the covalently bounded poly(ε-caprolactone) (PCL) chain improved the solubility of obtained polymers in organic solvents. In this respect, the Schiff base-containing polymers obtained in this study, with special hydrogel and antimicrobial properties, are very promising materials for potential use as a controlled-release formulation of both hydrophilic and hydrophobic drugs in cosmetic products for skin health. Full article
(This article belongs to the Special Issue Biomass-Derived Materials: Synthesis and Applications)
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Review

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25 pages, 10051 KiB  
Review
Functional Materials from Biomass-Derived Terpyridines: State of the Art and Few Possible Perspectives
by Jérôme Husson
Int. J. Mol. Sci. 2024, 25(16), 9126; https://doi.org/10.3390/ijms25169126 - 22 Aug 2024
Viewed by 623
Abstract
This review focuses on functional materials that contain terpyridine (terpy) units, which can be synthesized from biomass-derived platform chemicals. The latter are obtained by the chemical conversion of raw biopolymers such as cellulose (e.g., 2-furaldehyde) or lignin (e.g., syringaldehyde). These biomass-derived platform chemicals [...] Read more.
This review focuses on functional materials that contain terpyridine (terpy) units, which can be synthesized from biomass-derived platform chemicals. The latter are obtained by the chemical conversion of raw biopolymers such as cellulose (e.g., 2-furaldehyde) or lignin (e.g., syringaldehyde). These biomass-derived platform chemicals serve as starting reagents for the preparation of many different terpyridine derivatives using various synthetic strategies (e.g., Kröhnke reaction, cross-coupling reactions). Chemical transformations of these terpyridines provide a broad range of different ligands with various functionalities to be used for the modification or construction of various materials. Either inorganic materials (such as oxides) or organic ones (such as polymers) can be combined with terpyridines to provide functional materials. Different strategies are presented for grafting terpy to materials, such as covalent grafting through a carboxylic acid or silanization. Furthermore, terpy can be used directly for the elaboration of functional materials via complexation with metals. The so-obtained functional materials find various applications, such as photovoltaic devices, heterogeneous catalysts, metal–organic frameworks (MOF), and metallopolymers. Finally, some possible developments are presented. Full article
(This article belongs to the Special Issue Biomass-Derived Materials: Synthesis and Applications)
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