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Coordination Polymer: Design and Synthesis

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: closed (31 October 2023) | Viewed by 1182

Special Issue Editor


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Guest Editor
Department of Chemistry, Ludwig-Maximilians-University Munich, Butenandtstr. 9, 81377 München, Germany
Interests: metallocene chemistry; coordination polymers; crystal structure determination
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Supramolecular chemistry is currently one of the most intensively studied sub-discipline of chemistry. Within the realm of coordination chemistry, the same is true for the field of “Coordination Polymers”. A quick look into SciFindern at the beginning of 2023 reveals over 12000 entries for the concept “coordination polymer”, including over 800 review articles, nine books and 1300 patents, describing in all nearly 55000 substances. Although the “climax” of research papers was reached 10 years ago with over 1000 papers in 2013, the last years show continuously ca. 700 annual publications. This continuous interest is mainly due to the large variety of applications, ranging from organic synthesis over (bio-) medicinal and environmental chemisty to material science including nanomaterials, sensors and photocatalysis.

In most cases, the formation of coordination polymers is within the domain of solid state chemistry. Therefore, the synthesis of such compounds does not just require an appropriate choice of metals and ligands, but also the right choice of crystallization conditions—shortly “Crystal Engineering”. This present “Special Issue” has the focus on the design and synthesis of coordination polymers, and not so much on the actual applications (although, of course, the “design” implies a certain purpose of the synthesized compounds). Therefore, we invite all synthetic chemists interested in this field of coordination chemistry to contribute either a review of their own results or very recent developments in their research on this subject.

Prof. Dr. Karlheinz Sünkel
Guest Editor

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Published Papers (1 paper)

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Review

22 pages, 6172 KiB  
Review
Reticular Chemistry for Optical Sensing of Anions
by Aasif Helal, Mohd Yusuf Khan, Abuzar Khan, Muhammad Usman and Md. Hasan Zahir
Int. J. Mol. Sci. 2023, 24(17), 13045; https://doi.org/10.3390/ijms241713045 - 22 Aug 2023
Viewed by 888
Abstract
In the last few decades, reticular chemistry has grown significantly as a field of porous crystalline molecular materials. Scientists have attempted to create the ideal platform for analyzing distinct anions based on optical sensing techniques (chromogenic and fluorogenic) by assembling different metal-containing units [...] Read more.
In the last few decades, reticular chemistry has grown significantly as a field of porous crystalline molecular materials. Scientists have attempted to create the ideal platform for analyzing distinct anions based on optical sensing techniques (chromogenic and fluorogenic) by assembling different metal-containing units with suitable organic linking molecules and different organic molecules to produce crystalline porous materials. This study presents novel platforms for anion recognition based on reticular chemistry with high selectivity, sensitivity, electronic tunability, structural recognition, strong emission, and thermal and chemical stability. The key materials for reticular chemistry, Metal-Organic Frameworks (MOFs), Zeolitic Imidazolate Frameworks (ZIFs), and Covalent-Organic Frameworks (COFs), and the pre- and post-synthetic modification of the linkers and the metal oxide clusters for the selective detection of the anions, have been discussed. The mechanisms involved in sensing are also discussed. Full article
(This article belongs to the Special Issue Coordination Polymer: Design and Synthesis)
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