Advanced Inorganic Nanomaterials for Energy Conversion and Catalysis Applications

A special issue of Inorganics (ISSN 2304-6740). This special issue belongs to the section "Inorganic Materials".

Deadline for manuscript submissions: 28 February 2025 | Viewed by 2493

Special Issue Editors


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Guest Editor
College of Science, Health, Engineering and Education, Murdoch University, 90 South Street, Murdoch, WA 6150, Australia
Interests: crystalline; electrodes; cobalt; electrochemical deposition technique; electronic characterization; electrical properties
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Guest Editor
Department of Advanced Applied Materials Engineering, Kun Shan University, Tainan 71070, Taiwan
Interests: electrochemical catalyst; rechargeable battery; ceramic material

Special Issue Information

Dear Colleagues,

Until today, inorganic nanomaterials for energy conversion and catalysis have become increasingly significant in academic research and industrial applications compared to before, such as in air purification, wastewater treatment, bacterial disinfection, and medical science. This is primarily due to unique properties such as their nanoporosity, optical absorption, intense crystalline phases, high specific surface areas, nanomorphology, and high oxidation. Hence, they play a vital role in the successful design of composite catalysts with enhanced efficiency and selectivity and a steady catalytic activity.

This Special Issue aims to track the most recent advances in inorganic nanomaterials in energy conversion and catalysis applications by hosting a mix of original research articles and comprehensive reviews.

Dr. Guan-Ting Pan
Prof. Dr. Chao-Ming Huang
Guest Editors

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Keywords

  • catalysis
  • composites
  • nanoparticles
  • band gap
  • electron transfer
  • characterization
  • electrochemistry
  • catalysis applications

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Published Papers (2 papers)

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Research

15 pages, 5450 KiB  
Article
Synthesis of Sulfonic Acid-Functionalized g-C3N4/BiOI Bifunctional Heterojunction for Enhanced Photocatalytic Removal of Tartrazine and PEC Oxygen Evolution Reaction
by Sridharan Balu, Harikrishnan Venkatesvaran, Chien-Chih Wang, Joon Ching Juan and Thomas Chung-Kuang Yang
Inorganics 2024, 12(9), 243; https://doi.org/10.3390/inorganics12090243 - 5 Sep 2024
Viewed by 612
Abstract
A Z-scheme heterojunction photo(electro)catalyst was fabricated by coupling sulfonic acid-modified graphitic carbon nitride (SA-g-CN) with bismuth oxyiodide (BiOI). The SA-g-CN component was prepared via wet-impregnation, while BiOI was synthesized through a hydrothermal method. Comprehensive characterization elucidated the structural and morphological properties of the [...] Read more.
A Z-scheme heterojunction photo(electro)catalyst was fabricated by coupling sulfonic acid-modified graphitic carbon nitride (SA-g-CN) with bismuth oxyiodide (BiOI). The SA-g-CN component was prepared via wet-impregnation, while BiOI was synthesized through a hydrothermal method. Comprehensive characterization elucidated the structural and morphological properties of the resulting composite. The SA-g-CN/BiOI exhibited exceptional performance in both photocatalytic degradation of tartrazine (TTZ) and photoelectrochemical oxygen evolution reaction (OER). Notably, 98.26% TTZ removal was achieved within 60 min of irradiation, while an OER onset potential of 0.94 V (vs. Ag/AgCl) and a high photocurrent density of 6.04 mA were recorded under AM 1.5G illumination. Band energy calculations based on Mott–Schottky measurements confirmed the formation of a Z-scheme heterojunction, which facilitated efficient charge separation and transfer, thereby enhancing catalytic activity. These findings establish the SA-g-CN/BiOI composite as a promising candidate for sustainable energy generation and environmental remediation applications. Full article
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24 pages, 7873 KiB  
Article
CuFe2O4 Nanofiber Incorporated with a Three-Dimensional Graphene Sheet Composite Electrode for Supercapacitor and Electrochemical Sensor Application
by Sivaramakrishnan Vinothini, Arjunan Karthi Keyan, Subramanian Sakthinathan, Te-Wei Chiu and Naratip Vittayakorn
Inorganics 2024, 12(6), 164; https://doi.org/10.3390/inorganics12060164 - 12 Jun 2024
Cited by 1 | Viewed by 1008
Abstract
The demand for regenerative energy and electric automotive applications has grown in recent decades. Supercapacitors have multiple applications in consumer alternative electronic products due to their excellent energy density, rapid charge/discharge time, and safety. CuFe2O4-incorporated three-dimensional graphene sheet (3DGS) [...] Read more.
The demand for regenerative energy and electric automotive applications has grown in recent decades. Supercapacitors have multiple applications in consumer alternative electronic products due to their excellent energy density, rapid charge/discharge time, and safety. CuFe2O4-incorporated three-dimensional graphene sheet (3DGS) nanocomposites were studied by different characterization studies such as X-ray diffraction, transmission electron microscopy, and scanning electron microscopy. The electrochemical studies were based on cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS) measurements. As prepared, 3DGS/CuFe2O4 nanocomposites exhibited an excellent surface area, high energy storage with appreciable durability, and excellent electrocatalysis properties. A supercapacitor with 3DGS/CuFe2O4-coated nickel foam (NF) electrodes exhibited an excellent specific capacitance of 488.98 Fg−1, a higher current density, as well as a higher power density. After charge–discharge cycles in a 2.0 M KOH aqueous electrolyte solution, the 3DGS/CuFe2O4/NF electrodes exhibited an outstanding cyclic stability of roughly 95% at 10 Ag−1, indicating that the prepared nanocomposites could have the potential for energy storage applications. Moreover, the 3DGS/CuFe2O4 electrode exhibited an excellent electrochemical detection of chloramphenicol with a detection limit of 0.5 µM, linear range of 5–400 µM, and electrode sensitivity of 3.7478 µA µM−1 cm−2. Full article
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

Title: HARNESSING CONDUCTING POLYMER INORGANIC HYBRID NANO COMPOSITES FOR EMPOWERING SUSTAINABILITY
Author: S
Highlights: Conducting polymer inorganic nanocomposites offer a sustainable alternative to traditional synthetic materials, providing eco-friendly bioactive materials with enhanced opto electronic and photophysical properties. Conducting polymer mixed metal oxide/metal oxide composites are opening up possibilities for the applications promoting sustainability.

Title: Efficient catalyst for hydrogen evolution reaction of water electrolysis
Authors: Zhichao Gao,Haiyan Xiang
Affiliation: College of Materials and Advanced Manufacturing, Hunan University of Technology, 412007, Zhuzhou
Abstract: With the escalating consumption of conventional energy, there is an urgent need for a novel form of clean energy to replace it. Hydrogen energy possesses the advantages of high energy density and pollution-free combustion, making it a pivotal direction for new energy development. As research on water electrolysis for hydrogen production deepens, it has been observed that the efficiency and effectiveness of hydrogen evolution are sub-optimal. This paper discusses the composition, structure, catalytic properties, and electrochemical characteristics of various noble metal catalysts and non-noble metal catalysts while addressing the challenges and future directions in developing highly efficient catalysts for electrolytic water hydrogen evolution.

Title: Synthesis and characterization of a homogeneous copper electrocatalyst for proton reduction in aqueous acid medium
Authors: Ram Chandra Maji
Affiliation: Department of Chemistry, Bankura University, Bankura-722155, West Bengal, India
Abstract: One novel copper (II) complex [Cu(HL)](ClO4) (1) has been synthesized, employing N and O donor ligand, namely H2L. The CV experiments were carried out to examine the catalytic proton reduction ability of complex 1 in phosphate buffer solutions (PBS) at three distinct pH: 2.5, 4.6 and 7. At pH 2.5 and 4.6, complex 1 shows catalytically proton reduction peaks with a sharp increase of current height at -1.04 and -0.95 V, corresponding to an onset overpotential of 892 mV and 678 mV, respectively. The controlled potential electrolysis experiments of complex 1 in 0.1 M PBS at pH 2.5 were conducted using a glassy carbon working electrode for 130 minutes. During the bulk electrolysis process at -1.5 V, 95 C of charges were passed, which corresponding to a turnover number (TON) of 3710 mol H2 (molcat)-1cm-2 and a turnover frequency (TOF) of 1720 mol H2 (molcat)-1h-1cm-2. The electrochemical experiments unequivocally demonstrate the high catalytic activity of complex 1 for generating dihydrogen via proton reduction in aqueous acidic media. The hydrogen-generation rate constant (kobs) of complex 1 is calculated to be 1.93 × 103 s-1 at pH 2.5 further underscores the remarkable efficiency of this complex 1 in facilitating hydrogen evolution reactions.

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