Latest Developments in Photocatalytic Nanomaterials and Processes. Second Edition

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: closed (30 June 2023) | Viewed by 2282

Special Issue Editors


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Guest Editor
Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Budapest, Hungary
Interests: materials science; nanotechnology; analytical chemistry; photocatalysis; gas sensing; nanofluids; atomic layer deposition; nanocomposites
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Guest Editor
1. Institute of Physical Metallurgy, Metal Forming and Nanotechnology, University of Miskolc, C/2-5 Building 209, H-3515 Miskolc-Egyetemvaros, Hungary
2. Department of Applied and Environmental Chemistry, University of Szeged, Szeged, Hungary
Interests: heterogeneous catalysis; photocatalytic materials; carbon nanotubes; nanocomposite materials; immobilization of biologically active units
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Photocatalysis, which uses solar energy as renewable resource, is one of the most promising technologies for the elimination of toxic compounds from water, due to the advantages of high activity, photochemical stability and cost-efficiency. I  addition to aqueous applications, it can also significantly increase indoor air quality, addressing the so-called “sick building syndrome” and contribute to eliminating pollutants like VOCs both indoors and outdoors. Alongside oxidation, the photocatalytic reduction of harmful molecules (e.g., NOx) is an emerging field.

Photocatalytic synthesis is also a major field of green chemistry. It ranges from the artificial photosynthesis of converting CO2 and H2O into organic raw molecules to performing photocatalytic synthetic versions of more sophisticated organic processes, as examples.

There are many exciting resent materials and processes appearing in the photocatalytic research, including photonic bandgap structures, all-organic photocatalysts, etc.

Other hot topics in the filed include the use of computational chemistry and the application of extreme laser infrastructure to understand photon absorption, excitation and dissipation processes and the occurring photochemical reactions.

A great challenge in photocatalytic materials research is to increase their selectivity, robustness, electron–hole lifetime, and achieve a more optimal use of the solar spectrum.

Although there are already some practical, real-life applications, the major breakthrough of the everyday use of photocatalysis is still awaited. To achieve this, new laboratory and scaled-up setups and processes are needed, with robust catalysts and reactors.

Recently, a very successful Special Issue in the field was edited by us in Nanomaterials, titled Latest Developments in Photocatalytic Materials and Processes (https://www.mdpi.com/journal/nanomaterials/special_issues/Photocatalytic_Materials_Processes) .

The present Special Issue is the continuation of the previous one, and aims to collect further studies and results about the latest developments in the field of photocatalysis.

Dr. Imre Miklós Szilágyi
Dr. Klára Hernádi
Guest Editors

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Keywords

  • photocatalysis
  • decontamination
  • synthesis
  • nanotechnology
  • nanocomposites
  • visible
  • UV

Published Papers (1 paper)

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Research

14 pages, 4640 KiB  
Article
Synthesis of TiO2/Al2O3 Double-Layer Inverse Opal by Thermal and Plasma-Assisted Atomic Layer Deposition for Photocatalytic Applications
by Hamsasew Hankebo Lemago, Feras Shugaa Addin, Dániel Atilla Kárajz, Tamás Igricz, Bence Parditka, Zoltán Erdélyi, Dóra Hessz and Imre Miklós Szilágyi
Nanomaterials 2023, 13(8), 1314; https://doi.org/10.3390/nano13081314 - 08 Apr 2023
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Abstract
In comparison to conventional nano-infiltration approaches, the atomic layer deposition (ALD) technology exhibits greater potential in the fabrication of inverse opals (IOs) for photocatalysts. In this study, TiO2 IO and ultra-thin films of Al2O3 on IO were successfully deposited [...] Read more.
In comparison to conventional nano-infiltration approaches, the atomic layer deposition (ALD) technology exhibits greater potential in the fabrication of inverse opals (IOs) for photocatalysts. In this study, TiO2 IO and ultra-thin films of Al2O3 on IO were successfully deposited using thermal or plasma-assisted ALD and vertical layer deposition from a polystyrene (PS) opal template. SEM/EDX, XRD, Raman, TG/DTG/DTA-MS, PL spectroscopy, and UV Vis spectroscopy were used for the characterization of the nanocomposites. The results showed that the highly ordered opal crystal microstructure had a face-centered cubic (FCC) orientation. The proposed annealing temperature efficiently removed the template, leaving the anatase phase IO, which provided a small contraction in the spheres. In comparison to TiO2/Al2O3 plasma ALD, TiO2/Al2O3 thermal ALD has a better interfacial charge interaction of photoexcited electron–hole pairs in the valence band hole to restrain recombination, resulting in a broad spectrum with a peak in the green region. This was demonstrated by PL. Strong absorption bands were also found in the UV regions, including increased absorption due to slow photons and a narrow optical band gap in the visible region. The results from the photocatalytic activity of the samples show decolorization rates of 35.4%, 24.7%, and 14.8%, for TiO2, TiO2/Al2O3 thermal, and TiO2/Al2O3 plasma IO ALD samples, respectively. Our results showed that ultra-thin amorphous ALD-grown Al2O3 layers have considerable photocatalytic activity. The Al2O3 thin film grown by thermal ALD has a more ordered structure compared to the one prepared by plasma ALD, which explains its higher photocatalytic activity. The declined photocatalytic activity of the combined layers was observed due to the reduced electron tunneling effect resulting from the thinness of Al2O3. Full article
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