Polymers

Editorial

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5 pages, 199 KiB

Open AccessEditorial

Assessment of the Ageing and Durability of Polymers

by Mariaenrica Frigione

Polymers 2022, 14(10), 1934; https://doi.org/10.3390/polym14101934 - 10 May 2022

Cited by 9 | Viewed by 2019

Abstract

As any other natural or industrial material, polymers can experience some kind of degradation during their service life, resulting in minor to severe changes in their properties [...] Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

Research

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16 pages, 5295 KiB

Open AccessArticle

Effect of Aging on the Mechanical Properties of Highly Transparent Fluoropolymers for the Conservation of Archaeological Sites

by Maria Paola Bracciale, Lorena Capasso, Fabrizio Sarasini, Jacopo Tirillò and Maria Laura Santarelli

Polymers 2022, 14(5), 912; https://doi.org/10.3390/polym14050912 - 24 Feb 2022

Cited by 5 | Viewed by 2517

Abstract

In recent years, fluoropolymers have found numerous applications in the architectural field because of their combination of mechanical-chemical resistance and high transparency. In the present work, commercial fluorinated polymers, such as perfluoro alkoxy (PFA) and ethylene tetrafluoroethylene copolymer (ETFE), have been evaluated for [...] Read more.

In recent years, fluoropolymers have found numerous applications in the architectural field because of their combination of mechanical-chemical resistance and high transparency. In the present work, commercial fluorinated polymers, such as perfluoro alkoxy (PFA) and ethylene tetrafluoroethylene copolymer (ETFE), have been evaluated for use as protective and transparent layers on monumental and archaeological sites (to preserve mosaics or frescoes) during the phases of restoration or maintenance outdoors. Considering this specific application, the present study was developed by evaluating the evolution of the mechanical (tensile, tear propagation resistance, and low-velocity impact tests) and chemical (FTIR and DSC analysis) properties of the films after accelerated UV aging. The results that were obtained demonstrated the high resistance capacity of the ETFE, which exhibits considerably higher elastic modulus and critical tear energy values than PFA films (1075.38 MPa and 131.70 N/mm for ETFE; 625.48 MPa and 59.06 N/mm for PFA). After aging, the samples exhibited only a slight reduction of about 5% in the elastic modulus for both polymers and 10% in the critical tear energy values for PFA. Furthermore, the differences in impact resistance after aging were limited for both polymers; however, the ETFE film showed higher peak force than the PFA films (82.95 N and 42.22 N, respectively). The results obtained demonstrated the high resistance capacity of ETFE films, making them the most suitable candidate for the considered application. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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13 pages, 5211 KiB

Open AccessArticle

High-Density Patterned Array Bonding through Void-Free Divinyl Siloxane Bis-Benzocyclobutene Bonding Process

by Nam Woon Kim, Hyeonjeong Choe, Muhammad Ali Shah, Duck-Gyu Lee and Shin Hur

Polymers 2021, 13(21), 3633; https://doi.org/10.3390/polym13213633 - 21 Oct 2021

Cited by 5 | Viewed by 3166

Abstract

Divinylsiloxane-bis-benzocyclobutene (DVS-BCB) has attracted significant attention as an intermediate bonding material, owing to its excellent properties. However, its applications are limited, due to damage to peripheral devices at high curing temperatures and unoptimized compressive pressure. Therefore, it is necessary to explore the compressive [...] Read more.

Divinylsiloxane-bis-benzocyclobutene (DVS-BCB) has attracted significant attention as an intermediate bonding material, owing to its excellent properties. However, its applications are limited, due to damage to peripheral devices at high curing temperatures and unoptimized compressive pressure. Therefore, it is necessary to explore the compressive pressure condition for DVS-BCB bonding. This study demonstrates an optimization process for void-free DVS-BCB bonding. The process for obtaining void-free DVS-BCB bonding is a vacuum condition of 0.03 Torr, compressive pressure of 0.6 N/mm², and curing temperature of 250 °C for 1 h. Herein, we define two factors affecting the DVS-BCB bonding quality through the DVS-BCB bonding mechanism. For strong DVS-BCB bonding, void-free and high-density chemical bonds are required. Therefore, we observed the DVS-BCB bonding under various compressive pressure conditions at a relatively low temperature (250 °C). The presence of voids and high-density crosslinking density was examined through near-infrared confocal laser microscopy and Fourier-transform infrared microscopy. We also evaluated the adhesion of the DVS-BCB bonding, using a universal testing machine. The results suggest that the good adhesion with no voids and high crosslinking density was obtained at the compressive pressure condition of 0.6 N/mm². We believe that the proposed process will be of great significance for applications in semiconductor and device packaging technologies. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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22 pages, 3412 KiB

Open AccessArticle

An Effective Package of Antioxidants for Avoiding Premature Failure in Polypropylene Random Copolymer Plastic Pipes under Hydrostatic Pressure and High Temperature

by Enrique Blázquez-Blázquez, Joaquín Lahoz, Ernesto Pérez and María L. Cerrada

Polymers 2021, 13(16), 2825; https://doi.org/10.3390/polym13162825 - 22 Aug 2021

Cited by 6 | Viewed by 3910

Abstract

Pipes of polypropylene random (PP-R) copolymers are the best choice for hot- and cold-water networks. Validation of a severe test, accomplishing the ISO 1167 standard, is mandatory to assess their service lifetime expectancy. This work evaluates the behavior shown by three commercial pipes, [...] Read more.

Pipes of polypropylene random (PP-R) copolymers are the best choice for hot- and cold-water networks. Validation of a severe test, accomplishing the ISO 1167 standard, is mandatory to assess their service lifetime expectancy. This work evaluates the behavior shown by three commercial pipes, either the original ones (new pipes) or after being subjected to a hydrostatic pressure test at elevated temperature (aged pipes). Several features with relevance for the final performance have been examined: crystalline characteristics, phase transitions in crystalline regions, effect of high temperature and pressure on these transitions, and oxidation induction time. Moreover, the presence of inorganic fillers, and the content of different antioxidants together with their depletion, have also been analyzed. Films from the new pipes were also prepared for replication of the different environments in order to achieve a better and complete understanding of the phase transitions in the crystalline regions and of the consumption of antioxidants. Distinct environments surrounded the inner and outer parts of the pipes exposed to the failure aging test at 110 °C: hot water and warm dry air, respectively. These features play a key role in the loss of additives and in the subsequent initiation of degradation. Even if the crystalline characteristics are appropriate in the polymeric matrix, the success of a pipe lies in the homogeneous dispersion of components for avoiding damage at interfacial properties, and in a correct package of antioxidants used in its formulation. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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12 pages, 631 KiB

Open AccessArticle

New Aspects of Degradation in Silicone Rubber under UVA and UVB Irradiation: A Gas Chromatography–Mass Spectrometry Study

by Zheng Wang, Libing Qian, Xiangyang Peng, Zhen Huang, Yue Yang, Chunqing He and Pengfei Fang

Polymers 2021, 13(13), 2215; https://doi.org/10.3390/polym13132215 - 5 Jul 2021

Cited by 9 | Viewed by 3815

Abstract

In this paper, gas chromatography–mass spectrometry (GC–MS) and positron annihilation lifetime spectroscopy (PALS) were used to probe the changes of oligomers and the polydimethylsiloxane (PDMS) network in silicone rubber, after different durations of UVA/UVB irradiation. At the early stage (<300 h) of UVA/UVB [...] Read more.

In this paper, gas chromatography–mass spectrometry (GC–MS) and positron annihilation lifetime spectroscopy (PALS) were used to probe the changes of oligomers and the polydimethylsiloxane (PDMS) network in silicone rubber, after different durations of UVA/UVB irradiation. At the early stage (<300 h) of UVA/UVB irradiation, the concentration of D

_{4}

-D

_{9}

decreases. The o-Ps intensity of the extracted silicone rubber increases in the stage after UVB irradiation. These results indicate the crosslinking of oligomers into the PDMS network. After a long duration (>300 h) of UVB irradiation, D

_{4}

was generated and the lifetime of

τ_{3}

also increased, indicating the rupture of the Si-O bond in the PDMS network. These two aging processes were termed the post curing process and the chain session process. The new finding was that UVA could only induce the post curing process; UVB causes the rupture of the chemical bond in silicone rubber. Photons of UVB could break the C-H bond, and then trigger the backbiting decomposition of PDMS, breaking the Si-O bond, while the photons of UVA cannot. The fact that D

_{4}

was generated after UVB irradiation can be used to evaluate the UVB stability of silicone rubber in the future. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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21 pages, 5303 KiB

Open AccessArticle

Influence of Gamma Irradiation on Electric Cables Models: Study of Additive Effects by Mid-Infrared Spectroscopy

by Astrid Maléchaux, Juliette Colombani, Sandrine Amat, Sylvain R. A. Marque and Nathalie Dupuy

Polymers 2021, 13(9), 1451; https://doi.org/10.3390/polym13091451 - 30 Apr 2021

Cited by 10 | Viewed by 3223

Abstract

Cables, especially their insulation and jacket materials made of polymers, are vulnerable to ageing degradation during normal operation. However, they must remain functional for the entire life of a nuclear power plant, or even in the event of an accident for cables with [...] Read more.

Cables, especially their insulation and jacket materials made of polymers, are vulnerable to ageing degradation during normal operation. However, they must remain functional for the entire life of a nuclear power plant, or even in the event of an accident for cables with a safety requirement. This study focuses on models of crosslinked polyethylene (XLPE)-based insulation of cables and deals with the structure modification and the behavior of XLPE for nuclear applications due to the effect of additives. Various additives are added to the polymer formulation to evaluate their impact on ageing. The samples are irradiated at room temperature by several gamma doses, up to 374 kGy, with two dose rates (40 Gy/h and 300 Gy/h) and compared with a non-irradiated sample used as reference. To understand the impact of gamma irradiation on the materials, the principal component analysis (PCA) method is applied on spectra recorded through attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy. The results highlight the effects of ageing depending on the dose rate and on the formulation of the materials, with the identification of different degradation products. A curve resolution study compares the effects of different additives on polymer oxidation and shows that the low dose rate leads to a higher degradation than the high dose rate. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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18 pages, 5706 KiB

Open AccessArticle

Reliability Prediction of Acrylonitrile O-Ring for Nuclear Power Applications Based on Shore Hardness Measurements

by Alvaro Rodríguez-Prieto, Ernesto Primera, Mariaenrica Frigione and Ana María Camacho

Polymers 2021, 13(6), 943; https://doi.org/10.3390/polym13060943 - 19 Mar 2021

Cited by 7 | Viewed by 2824

Abstract

The degradation of polymeric components is of considerable interest to the nuclear industry and its regulatory bodies. The objective of this work was the development of a methodology to determine the useful life—based on the storage temperature—of acrylonitrile O-rings used as mechanical sealing [...] Read more.

The degradation of polymeric components is of considerable interest to the nuclear industry and its regulatory bodies. The objective of this work was the development of a methodology to determine the useful life—based on the storage temperature—of acrylonitrile O-rings used as mechanical sealing elements to prevent leakages in nuclear equipment. To this aim, a reliability-based approach that allows prediction of the use-suitability of different storage scenarios (that involve different storage times and temperatures) considering the further required in-service performance, is presented. Thus, experimental measurements of Shore A hardness have been correlated with storage variables (temperature and storage time). The storage (and its associated hardening) was proved to have a direct effect on in-service durability, reducing this by up to 60.40%. Based on this model, the in-service performance was predicted; after the first three years of operation the increase in probability of failure (POF) was practically insignificant. Nevertheless, from this point on, and especially, from 5 years of operation, the POF increased from 10% to 20% at approximately 6 years (for new and stored). From the study, it was verified that for any of the analysis scenarios, the limit established criterion was above that of the storage time premise considered in usual nuclear industry practices. The novelty of this work is that from a non-destructive test, like a Shore A hardness measurement, the useful life and reliability of O-rings can be estimated and be, accordingly, a decision tool that allows for improvement in the management of maintenance of safety-related equipment. Finally, it was proved that the storage strategies of our nuclear power plants are successful, perfectly meeting the expectations of suitability and functionality of the components when they are installed after storage. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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13 pages, 6339 KiB

Open AccessArticle

Mathematical Modeling of Outdoor Natural Weathering of Polycarbonate: Regional Characteristics of Degradation Behaviors

by Takato Ishida and Ryoma Kitagaki

Polymers 2021, 13(5), 820; https://doi.org/10.3390/polym13050820 - 7 Mar 2021

Cited by 6 | Viewed by 2974

Abstract

Many natural exposure sites have been developed to ensure the reliability of materials intended for outdoor use. However, the effects of local climate on aging have not been completely understood. This study aimed to elucidate the regional characteristics of natural aging. Non-stabilized and [...] Read more.

Many natural exposure sites have been developed to ensure the reliability of materials intended for outdoor use. However, the effects of local climate on aging have not been completely understood. This study aimed to elucidate the regional characteristics of natural aging. Non-stabilized and stabilized polycarbonates were monitored in terms of their appearance (yellowing and loss of gloss) during natural weathering at five exposure sites (Tokyo, Kagoshima, Okinawa, Florida, and Arizona) in conjunction with climate fluctuation for up to 24 months. Three approaches were employed to characterize the natural aging behaviors: (i) modeling the rate function of degradation, (ii) evaluating the contribution ratio of individual degradational factors, and (iii) estimating the “synchronicity” by cross-correlation analysis with the climate dataset. The aging rates were the highest in Arizona and lowest in Kagoshima among the five exposure sites. First, prediction curves were constructed from the degradation rate function (variables: UV irradiation, temperature, and humidity), and these curves were found to agree well with the measured aging behaviors. Second, the exposure data in Arizona demonstrated strong temperature dependence, while those in Okinawa and Florida had stronger dependence on UV irradiation compared to other sites. Lastly, the synchronicity between UV irradiation and temperature was the highest in Arizona and lowest in Kagoshima, which can explain the significantly faster deterioration in Arizona and the slow deterioration in Kagoshima. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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16 pages, 10435 KiB

Open AccessArticle

Synthesis of Carvedilol–Organotin Complexes and Their Effects on Reducing Photodegradation of Poly(Vinyl Chloride)

by Omar G. Mousa, Gamal A. El‐Hiti, Mohammed A. Baashen, Muna Bufaroosha, Ahmed Ahmed, Ahmed A. Ahmed, Dina S. Ahmed and Emad Yousif

Polymers 2021, 13(4), 500; https://doi.org/10.3390/polym13040500 - 6 Feb 2021

Cited by 19 | Viewed by 3245

Abstract

Poly(vinyl chloride) (PVC) undergoes photodegradation induced by ultraviolet (UV) irradiation; therefore, for outdoor applications, its photostability should be enhanced through the use of additives. Several carvedilol tin complexes were synthesized, characterized and mixed with PVC to produce thin films. These films were irradiated [...] Read more.

Poly(vinyl chloride) (PVC) undergoes photodegradation induced by ultraviolet (UV) irradiation; therefore, for outdoor applications, its photostability should be enhanced through the use of additives. Several carvedilol tin complexes were synthesized, characterized and mixed with PVC to produce thin films. These films were irradiated at 25 °C with a UV light (λ = 313 nm) for up to 300 h. The reduction in weight and changes in chemical structure and surface morphology of the PVC films were monitored. The films containing synthesized complexes showed less undesirable changes than the pure PVC film. Organotin with a high content of aromatics was particularly efficient in inhibiting photodegradation of PVC. The carvedilol tin complexes both absorbed UV light and scavenged radicals, hydrochloride, and peroxides and, therefore, photostabilized PVC. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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20 pages, 15978 KiB

Open AccessArticle

The Impact of the Acidic Environment on the Mechanical Properties of Epoxy Compounds in Different Conditions

by Anna Rudawska

Polymers 2020, 12(12), 2957; https://doi.org/10.3390/polym12122957 - 10 Dec 2020

Cited by 15 | Viewed by 2438

Abstract

The aim of this work was to determine the impact of the acidic environment on the mechanical properties of two epoxy compounds in different conditions. The samples were made from the epoxy compounds composed of the epoxy resin (based on Bisphenol A), triethylenetetramine [...] Read more.

The aim of this work was to determine the impact of the acidic environment on the mechanical properties of two epoxy compounds in different conditions. The samples were made from the epoxy compounds composed of the epoxy resin (based on Bisphenol A), triethylenetetramine curing agent (unmodified compound), and calcium carbonate (CaCO₃) (modified compound). The epoxy compound samples were seasoned for the following period of time (i.e., one week, one month, and three months). The environment was tap water and the acidic environment had three different concentrations of acetic acid (3%, 6%, and 9%). Strength tests of the epoxy compound samples were carried out in accordance with the ISO 604 standard. In the case of the modified composition, it is noted that the samples immersed in tap water were characterized by a higher strength than in acidic environments. A similar tendency was observed for unmodified compositions, although the differences were smaller than for the modified compositions. It was also noticed that the increase in the pH of the acidic solution in many analyzed cases contributed to the decrease in mechanical properties, although the immersion time in the acidic solution is important. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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16 pages, 4732 KiB

Open AccessArticle

Tin Complexes Containing an Atenolol Moiety as Photostabilizers for Poly(Vinyl Chloride)

by Baneen Salam, Gamal A. El-Hiti, Muna Bufaroosha, Dina S. Ahmed, Ahmed Ahmed, Mohammad Hayal Alotaibi and Emad Yousif

Polymers 2020, 12(12), 2923; https://doi.org/10.3390/polym12122923 - 6 Dec 2020

Cited by 12 | Viewed by 2863

Abstract

The lifetime of poly(vinyl chloride) (PVC) can be increased through the addition of additives to provide protection against irradiation. Therefore, several new tin complexes containing atenolol moieties were synthesized and their photostabilizing effect on PVC was investigated. Reacting atenolol with a number of [...] Read more.

The lifetime of poly(vinyl chloride) (PVC) can be increased through the addition of additives to provide protection against irradiation. Therefore, several new tin complexes containing atenolol moieties were synthesized and their photostabilizing effect on PVC was investigated. Reacting atenolol with a number of tin reagents in boiling methanol provided high yields of tin complexes. PVC was then mixed with the tin complexes at a low concentration, producing polymeric thins films. The films were irradiated with ultraviolet light and the resulting damage was assessed using different analytical and surface morphology techniques. Infrared spectroscopy and weight loss determination indicated that the films incorporating tin complexes incurred less damage and less surface changes compared to the blank film. In particular, the triphenyltin complex was very effective in enhancing the photostability of PVC, and this is due to its high aromaticity (three phenyl rings) compared to other complexes. Such an additive acts as a hydrogen chloride scavenger, radical absorber, and hydroperoxide decomposer. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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19 pages, 7474 KiB

Open AccessArticle

Moving toward Smart Cities: Evaluation of the Self-Cleaning Properties of Si-Based Consolidants Containing Nanocrystalline TiO₂ Activated by Either UV-A or UV-B Radiation

by José Santiago Pozo-Antonio, Daniel Noya-Pintos and Patricia Sanmartín

Polymers 2020, 12(11), 2577; https://doi.org/10.3390/polym12112577 - 2 Nov 2020

Cited by 4 | Viewed by 2126

Abstract

This study evaluated the self-cleaning ability and durability of Si-based consolidants (an ethyl silicate consolidant and a consolidant based on nanosized silica) spiked with nanocrystalline TiO₂ activated by either UV-A radiation (spectral region between 340 and 400 nm, and main peak at [...] Read more.

This study evaluated the self-cleaning ability and durability of Si-based consolidants (an ethyl silicate consolidant and a consolidant based on nanosized silica) spiked with nanocrystalline TiO₂ activated by either UV-A radiation (spectral region between 340 and 400 nm, and main peak at 365 nm) or UV-B radiation (spectral region between 270 and 420 nm, and main peak at 310 nm). Granite samples were coated with consolidant, to which nanocrystalline TiO₂ was added at different concentrations (0.5, 1, and 3%, by wt.). Diesel soot was then applied to the coated surfaces, and the samples were exposed to UV-A or UV-B radiation for 1650 h. The surface color changes, relative to the color of untreated granite, were determined every 330 h by color spectrophotometry. Slight color changes indicated a recovery of the reference color due to the degradation of the soot. The final surfaces of both the untreated and treated surfaces were compared by stereomicroscopy and scanning electron microscopy. The main findings were that: (1) In general, the consolidant containing nanosized silica induced the most intense photocatalytic activity. In the more compact xerogel coating formed by the nanosized silica, more TiO₂ nanoparticles were available to interact with the radiation. (2) For all consolidant mixtures, soot degradation remained constant or decreased over time, except with ethyl silicate with 0.5 wt % TiO₂ (no self-cleaning capacity). (3) Soot degradation increased with the concentration of TiO₂. (4) The UV-B radiation was the most effective in terms of soot degradation, except for the surface coated with the ethyl silicate and 3% wt. TiO₂. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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Review

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18 pages, 1579 KiB

Open AccessReview

Can Accelerated Aging Procedures Predict the Long Term Behavior of Polymers Exposed to Different Environments?

by Mariaenrica Frigione and Alvaro Rodríguez-Prieto

Polymers 2021, 13(16), 2688; https://doi.org/10.3390/polym13162688 - 12 Aug 2021

Cited by 52 | Viewed by 7521

Abstract

During their useful life, polymers are subject to degradation processes due to exposure to specific environmental conditions over long times. These processes generally lead to changes, almost always irreversible, of properties and performances of polymers, changes which would be useful to be able [...] Read more.

During their useful life, polymers are subject to degradation processes due to exposure to specific environmental conditions over long times. These processes generally lead to changes, almost always irreversible, of properties and performances of polymers, changes which would be useful to be able to predict in advance. To meet this need, numerous investigations have been focused on the possibility to predict the long-term performance of polymers, if exposed to specific environments, by the so called “accelerated aging” tests. In such procedures, the long-term behavior of polymeric materials is typically predicted by subjecting them to cycles of radiations, temperatures, vapor condensation, and other external agents, at levels well above those found in true conditions in order to accelerate the degradation of polymers: this can produce effects that substantially deviate from those observable under natural exposure. Even following the standard codes, different environmental parameters are often used in the diverse studies, making it difficult to compare different investigations. The correlation of results from accelerated procedures with data collected after natural exposure is still a debated matter. Furthermore, since the environmental conditions are a function of the season and the geographical position, and are also characteristic of the type of exposure area, the environmental parameters to be used in accelerated aging tests should also consider these variables. These and other issues concerning accelerated aging tests applied to polymers are analyzed in the present work. However, bearing in mind the limitations of these practices, they can find useful applications for rating the durability of polymeric materials. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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24 pages, 6563 KiB

Open AccessReview

Durability of Externally Bonded Fiber-Reinforced Polymer Composites in Concrete Structures: A Critical Review

by Jovan Tatar and Sandra Milev

Polymers 2021, 13(5), 765; https://doi.org/10.3390/polym13050765 - 28 Feb 2021

Cited by 42 | Viewed by 6321

Abstract

Externally bonded fiber-reinforced polymer composites have been in use in civil infrastructure for decades, but their long-term performance is still difficult to predict due to many knowledge gaps in the understanding of degradation mechanisms. This paper summarizes critical durability issues associated with the [...] Read more.

Externally bonded fiber-reinforced polymer composites have been in use in civil infrastructure for decades, but their long-term performance is still difficult to predict due to many knowledge gaps in the understanding of degradation mechanisms. This paper summarizes critical durability issues associated with the application of fiber-reinforced polymer (FRP) composites for rehabilitation of concrete structures. A variety of factors that affect the longevity of FRP composites are discussed: installation, quality control, material selection, and environmental conditions. Critical review of design approaches currently used in various international design guidelines is presented to identify potential opportunities for refinement of design guidance with respect to durability. Interdisciplinary approaches that combine materials science and structural engineering are recognized as having potential to develop composites with improved durability. Full article

(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)

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