Carbamazepine and Diclofenac Removal Double Treatment: Oxidation and Adsorption
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents
2.2. Analytical Method
2.3. Adsorption Tests
2.4. Oxidation Tests
2.5. Combined Tests
3. Results and Discussion
3.1. Activated Carbon
3.2. Carbamazepine and Diclofenac Adsorption Tests
3.3. Carbamazepine and Diclofenac Oxidation Tests
3.4. Combined Tests for Carbamazepine and Diclofenac PAC/O3 and O3/PAC
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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CEC | Molecule Size (nm) | Molar Mass (g mol−1) | Solubility in Water (mg L−1) | Log Kow | pKa |
---|---|---|---|---|---|
CBZ | 0.84 | 236.27 | 18.00 (25 °C) | 2.3 | 13.9 |
DCF | 0.93 | 296.10 | 2.37 (25 °C) | 4.51 | 4.15 |
CEC (mg L−1) | Freundlich | Langmuir | ||||
---|---|---|---|---|---|---|
KF (L g−1) | n | R2 | qe (mg g−1) | b (L mg−1) | R2 | |
DCF 0.7 | 192.24 | 4.42 | 0.998 | 89.08 | 827.02 | 0.817 |
DCF 1.8 | 167.13 | 4.06 | 0.990 | 144.32 | 56.09 | 0.811 |
CBZ 0.7 | 68.70 | 11.17 | 0.990 | 57.41 | 1254.14 | 0.846 |
CBZ 1.8 | 80.42 | 4.39 | 0.990 | 99.93 | 4.34 | 0.957 |
CEC (mg L−1) | Pseudo-First-Order Model | Pseudo-Second-Order Model | |||||
---|---|---|---|---|---|---|---|
qe (mg g−1) | k1 10−3 (min−1) | R2 | qe (mg g−1) | h (mg g−1 min−1) | k2 10−4 (g mg−1 min−1) | R2 | |
DCF 0.7 | 20.590 | 23.19 | 0.870 | 52.550 | 5.978 | 21.60 | 1.000 |
DCF 1.8 | 51.261 | 5.374 | 0.735 | 115.864 | 5.419 | 4.04 | 1.000 |
CBZ 0.7 | 29.615 | 2.118 | 0.932 | 47.162 | 0.588 | 2.64 | 0.997 |
CBZ 1.8 | 40.398 | 1.243 | 0.765 | 83.411 | 1.464 | 2.10 | 0.996 |
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Aldeguer Esquerdo, A.; Varo Galvañ, P.J.; Sentana Gadea, I.; Prats Rico, D. Carbamazepine and Diclofenac Removal Double Treatment: Oxidation and Adsorption. Int. J. Environ. Res. Public Health 2021, 18, 7163. https://doi.org/10.3390/ijerph18137163
Aldeguer Esquerdo A, Varo Galvañ PJ, Sentana Gadea I, Prats Rico D. Carbamazepine and Diclofenac Removal Double Treatment: Oxidation and Adsorption. International Journal of Environmental Research and Public Health. 2021; 18(13):7163. https://doi.org/10.3390/ijerph18137163
Chicago/Turabian StyleAldeguer Esquerdo, Alejandro, Pedro José Varo Galvañ, Irene Sentana Gadea, and Daniel Prats Rico. 2021. "Carbamazepine and Diclofenac Removal Double Treatment: Oxidation and Adsorption" International Journal of Environmental Research and Public Health 18, no. 13: 7163. https://doi.org/10.3390/ijerph18137163