Synthesis, Structure, and UV–Vis Characterization of Antimony(III) Phthalocyanine: [(SbPc)2(Sb2I8)(SbBr3)]2
Abstract
:1. Introduction
2. Experimental Section
2.1. General Procedure
2.2. Synthesis [(SbIIIPc)2(Sb2I8)(SbBr3)]2
2.3. X-ray Crystallography
2.4. Hirshfeld Surface Analysis
2.5. Theoretical Calculations
3. Results and Discussion
3.1. Synthesis and Initial Characterization
3.2. Structural Characterization
3.3. Hirshfeld Surface Analysis
3.4. UV–Vis Spectrosopy
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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[(SbIIIPc)2(Sb2I8)(SbBr3)]—(1) | |
---|---|
Formula | C64H32Br3I8N16Sb5 |
Molecular weight | 2888.73 |
Temperature (K) | 295(2) |
Crystal system | Triclinic |
Space group | |
a, b, c (Å) | 14.399(2), 15.344(3), 18.992(3) |
α, β, γ (°) | 95.64(2), 96.89(2), 113.93(2) |
V (Å3) | 3757.4(12) |
Z | 2 |
Dcal (gcm−3) | 2.553 |
Crystal size (mm3) | 0.250 × 0.125 × 0.080 |
μ (mm−1) | 6.707 |
Absorption correction | multi-scan |
Tmax./Tmin. | 0.4754/1.000 |
Total/Unique/Obs refls | 23,647/14,738/7721 |
Rint | 0.0271 |
R, [F2 > 2σ(F2)] 1 | 0.0476 |
wR [F2 all refls] 2 | 0.0957 |
S | 1.001 |
Δρmax, Δρmin (e·Å−3) | 2.072, −1.286 |
(SbPc)+ Cations | |||||
---|---|---|---|---|---|
Sb4–N2 | 2.191(8) | Sb4B–N2B | 2.202(7) | ||
Sb4–N4 | 2.178(8) | Sb4B–N4B | 2.181(7) | ||
Sb4–N6 | 2.190(9) | Sb4B–N6B | 2.206(8) | ||
Sb4–N8 | 2.206(8) | Sb4B–N8B | 2.146(8) | ||
N2–Sb4–N4 | 78.0(3) | N2B–Sb4B–N4B | 77.6(3) | ||
N4–Sb4–N6 | 79.4(3) | N4B–Sb4B–N6B | 77.7(3) | ||
N6–Sb4–N8 | 77.5(3) | N6B–Sb4B–N8B | 78.5(3) | ||
N2–Sb4–N8 | 77.7(3) | N2B–Sb4B–N8B | 78.4(3) | ||
Deviation of Sb from N4-plane | 0.992(1) | Deviation of Sb from N4-plane | 0.994(1) | ||
(Sb6I16Br6)4− Anion | |||||
Terminal Sb–I | |||||
Sb1–I7 | 2.7668(13) | Sb1–I8 | 2.6965(12) | Sb2–I6 | 2.7374(11) |
Bridged μ2 | |||||
Sb1–I3 | 3.2329(11) | Sb2–I3 | 2.9833(13) | Sb1–I5 | 2.8744(11) |
Sb3–I5 i | 3.4481(10) | Sb2–I4 | 2.8302(10) | Sb3–I4 | 3.31901(10) |
Bridged μ3 | |||||
Sb1–I1 | 3.1765(14) | Sb2–I1 | 3.1856(11) | Sb2i–I1 | 3.3610(10) |
Sb2–I2 | 3.0061(13) | Sb1i–I2 | 3.4281(12) | Sb3–I2 | 3.3531(11) |
Terminal Sb–Br | |||||
Sb3–Br1 | 2.6888(12) | Sb3–Br2 | 2.5659(14) | Sb3–Br3 | 2.6321(15) |
I8–Sb1–I7 | 96.78(4) | I8–Sb1–I5 | 90.48(4) | I7–Sb1–I5 | 98.42(4) |
I8–Sb1–I1 | 93.88(4) | I7–Sb1–I1 | 166.21(3) | I5–Sb1–I1 | 90.20(3) |
I8–Sb1–I3 | 91.83(3) | I7–Sb1–I3 | 85.88(4) | I5–Sb1–I3 | 174.85(3) |
I1–Sb1–I3 | 85.05(3) | I6–Sb2–I4 | 97.06(3) | I6–Sb2–I3 | 90.66(4) |
I4–Sb2–I3 | 88.68(3) | I6–Sb2–I2 | 91.49(3) | I4–Sb2–I2 | 93.83(4) |
I3–Sb2–I2 | 176.48(3) | I6–Sb2–I1 | 90.88(3) | I4–Sb2–I1 | 171.80(3) |
I3–Sb2–I1 | 89.16(3) | I2–Sb2–I1 | 88.02(3) | Br2–Sb3–Br3 | 92.11(5) |
Br2–Sb3–Br1 | 97.60(5) | Br3–Sb3–Br1 | 96.8 (5) | Sb1–I1–Sb2 | 91.46(3) |
Sb2–I3–Sb1 | 94.17(3) | ||||
Short Contacts between (SbPc)+ Units and (Sb6I16Br6)4− Anion | |||||
Sb4–I1 i | 3.5083(13) | Sb4–I2i | 3.6471(13) | Sb4–I3 | 3.6115(14) |
Sb4B–I5 | 3.6283(14) | Sb4B–I7 | 3.4969(11) | Sb4B–Br3i | 3.5941(18) |
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Kubiak, R.; Janczak, J. Synthesis, Structure, and UV–Vis Characterization of Antimony(III) Phthalocyanine: [(SbPc)2(Sb2I8)(SbBr3)]2. Molecules 2022, 27, 1839. https://doi.org/10.3390/molecules27061839
Kubiak R, Janczak J. Synthesis, Structure, and UV–Vis Characterization of Antimony(III) Phthalocyanine: [(SbPc)2(Sb2I8)(SbBr3)]2. Molecules. 2022; 27(6):1839. https://doi.org/10.3390/molecules27061839
Chicago/Turabian StyleKubiak, Ryszard, and Jan Janczak. 2022. "Synthesis, Structure, and UV–Vis Characterization of Antimony(III) Phthalocyanine: [(SbPc)2(Sb2I8)(SbBr3)]2" Molecules 27, no. 6: 1839. https://doi.org/10.3390/molecules27061839