Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay
Abstract
:1. Introduction
2. Results and Discussion
2.1. Receptor Design and Synthesis
2.2. Binding Studies in Organic Solvents
2.3. Crystallization and Single-Crystal X-ray Diffraction
2.4. Studies in the Aqueous Environment
2.5. Extraction Studies
2.6. Transport Experiments
2.7. Fluorescent Studies
3. Materials and Methods
3.1. Materials and Reagents
3.2. UV–Vis Experiments
3.3. 1H NMR Experiments
3.4. Liquid–Liquid Extraction (LLE)
3.5. Synthetic Details
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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TBA+ | B1 | B1 + 1 equiv. K+ | KK+/TBA+ |
---|---|---|---|
Cl− | 1.60 × 105 | 3.40 × 105 | 2.1 |
Br− | 0.95 × 104 | 2.15 × 104 | 2.3 |
NO2− | 4.61 × 104 | 6.96 × 104 | 1.5 |
NO3− | 1.72 × 104 | 2.51 × 104 | 1.5 |
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Zaleskaya-Hernik, M.; Dobrzycki, Ł.; Romański, J. Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay. Int. J. Mol. Sci. 2023, 24, 8536. https://doi.org/10.3390/ijms24108536
Zaleskaya-Hernik M, Dobrzycki Ł, Romański J. Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay. International Journal of Molecular Sciences. 2023; 24(10):8536. https://doi.org/10.3390/ijms24108536
Chicago/Turabian StyleZaleskaya-Hernik, Marta, Łukasz Dobrzycki, and Jan Romański. 2023. "Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay" International Journal of Molecular Sciences 24, no. 10: 8536. https://doi.org/10.3390/ijms24108536