Quantitative Description of Isomorphism in the Series of Simple Compounds
Abstract
:1. Introduction
Theory
2. Results
3. Discussion
4. Materials and Methods
- The apatite group: apatites derived from the hydroxyapatite 3Ca3(PO4)2*Ca(OH)2, with cationic substitutions of Mg, Cd, Pb, Sr and Ba16.
- The calcite group: magnesite MgCO3, calcite CaCO3, siderite FeCO3, spherocobaltite CoCO3, gaspeite NiCO3, smithsonite ZnCO3, otavite CdCO3 and nitratine NaNO3. Rhodocrosite MnCO3 was rejected, probably due to the variable valence state of Mn and the different environments of ions.
- The aragonite group: aragonite CaCO3, strontianite SrCO3, witherite BaCO3, and cerussite PbCO3.
- The celestine group: anhydrite CaSO4, SrSO4, barite BaSO4, and anglesite PbSO4.
- Zn Tutton’s Me2[Zn(H2O)6](SO4)2 salt with substitutions with NH4+, K, Rb, and Cs.
- Cu Tutton’s Me2[Cu(H2O)6](SO4)2 salt with Me: NH4+, K, Rb, and Cs.
- K Tutton’s K2[Me(H2O)6](SO4)2 with Me: Zn, Co, Cu, and Ru.
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Appendix A
Appendix B
References
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Kuczumow, A.; Gorzelak, M.; Kosiński, J.; Lasota, A.; Szabelska, A.; Blicharski, T.; Gągała, J.; Wawrzyniak, J.; Jarzębski, M.; Jabłoński, M. Quantitative Description of Isomorphism in the Series of Simple Compounds. Int. J. Mol. Sci. 2023, 24, 11324. https://doi.org/10.3390/ijms241411324
Kuczumow A, Gorzelak M, Kosiński J, Lasota A, Szabelska A, Blicharski T, Gągała J, Wawrzyniak J, Jarzębski M, Jabłoński M. Quantitative Description of Isomorphism in the Series of Simple Compounds. International Journal of Molecular Sciences. 2023; 24(14):11324. https://doi.org/10.3390/ijms241411324
Chicago/Turabian StyleKuczumow, Andrzej, Mieczysław Gorzelak, Jakub Kosiński, Agnieszka Lasota, Anna Szabelska, Tomasz Blicharski, Jacek Gągała, Jolanta Wawrzyniak, Maciej Jarzębski, and Mirosław Jabłoński. 2023. "Quantitative Description of Isomorphism in the Series of Simple Compounds" International Journal of Molecular Sciences 24, no. 14: 11324. https://doi.org/10.3390/ijms241411324