An Inorganic–Organic Hybrid Framework Composed of Polyoxotungstate and Long-Chained Bolaamphiphile
Abstract
:1. Introduction
2. Results
2.1. Syntheses of C12N2-H2W12 Hybrid Crystal
2.2. Crystal Strucure of C12N2-H2W12 Hybrid Crystals
2.3. Conductive Property of C12N2-H2W12 Hybrid Crystal
3. Discussion
4. Materials and Methods
4.1. General Procedures and Instrumental Methods
4.2. Syntheses
4.2.1. Route 1
4.2.2. Route 2
4.2.3. Route 3
4.3. Crystal Structure Determination
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Compound | C12N2-H2W12 |
---|---|
Chemical formula | C36H92N6W12O44 |
Formula weight | 3519.35 |
Crystal system | trigonal |
Space group | P3 (No. 147) |
a (Å) | 18.3644 (4) |
b (Å) | 18.3644 (4) |
c (Å) | 12.7069 (3) |
α (°) | 90.000 |
β (°) | 90.000 |
γ (°) | 120.000 |
V (Å3) | 3711.28 (17) |
Z | 2 |
ρcalcd (g cm−3) | 3.149 |
T (K) | 296 (2) |
Wavelength (Å) | 0.71075 |
μ (mm−1) | 18.604 |
No. of reflections measured | 60,648 |
No. of independent reflections | 5667 |
Rint | 0.0619 |
No. of parameters | 301 |
R1 (I > 2σ(I)) | 0.0227 |
wR2 (all data) | 0.0501 |
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Ikuma, H.; Aoki, S.; Kawahara, K.; Ono, S.; Iwamatsu, H.; Kobayashi, J.; Kiyota, Y.; Okamura, Y.; Higuchi, M.; Ito, T. An Inorganic–Organic Hybrid Framework Composed of Polyoxotungstate and Long-Chained Bolaamphiphile. Int. J. Mol. Sci. 2023, 24, 2824. https://doi.org/10.3390/ijms24032824
Ikuma H, Aoki S, Kawahara K, Ono S, Iwamatsu H, Kobayashi J, Kiyota Y, Okamura Y, Higuchi M, Ito T. An Inorganic–Organic Hybrid Framework Composed of Polyoxotungstate and Long-Chained Bolaamphiphile. International Journal of Molecular Sciences. 2023; 24(3):2824. https://doi.org/10.3390/ijms24032824
Chicago/Turabian StyleIkuma, Haruka, Shunsuke Aoki, Kai Kawahara, Seiji Ono, Hironori Iwamatsu, Jun Kobayashi, Yoshiki Kiyota, Yosuke Okamura, Masashi Higuchi, and Takeru Ito. 2023. "An Inorganic–Organic Hybrid Framework Composed of Polyoxotungstate and Long-Chained Bolaamphiphile" International Journal of Molecular Sciences 24, no. 3: 2824. https://doi.org/10.3390/ijms24032824