Spectroscopic Studies of Lanthanide(III) Complexes with L-Malic Acid in Binary Systems
Abstract
:1. Introduction
2. Results and Discussion
2.1. Equilibrium Study
2.2. Luminescence Spectroscopy
2.3. IR Spectroscopy
2.4. CD Spectroscopy
3. Materials and Methods
3.1. Materials
3.2. Equilibrium Study
3.3. UV-Vis and Luminescence Spectroscopy
3.4. Infrared Spectroscopy (FT-IR)
3.5. CD Spectroscopy
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Species | logβ | logKe | Reaction |
---|---|---|---|
Mal | |||
H2L | 7.92(1) * | 3.22 | HL− + H+ ⇋ H2L |
HL | 4.70(1) * | 4.70 | L2− + H+ ⇋ HL− |
La(III)-Mal | |||
LaHMal | 9.52(5) | 4.82 | La3+ + HMal La(HMal) |
LaMal | 5.54(3) | 5.54 | La3+ + Mal LaMal |
La(Mal)(OH) | −3.35(6) | 4.88 | LaMal + H2O La(Mal)(OH)2− + H+ |
Nd(III)-Mal | |||
Nd(HMal)(Mal) | 13.19(6) | 8.49 | Nd 3+ + HMal− + Mal2− Nd(HMal)(Mal) |
Nd(Mal)2 | 9.24(6) | 9.24 | Nd 3+ + 2Mal2− Nd(Mal)2− |
Nd(Mal)(OH) ** | −3.03(7) | 10.74 | Nd3+ + Mal2−+ H2O Nd(Mal)(OH) + H+ |
Nd(Mal)2(OH) | 1.31(2) | 5.84 | Nd(Mal)2− + H2O Nd(Mal)2(OH)2− + H+ |
Gd(III)-Mal | |||
Gd(HMal)(Mal) | 12.61(3) | 7.91 | Gd3+ + HMal− + Mal2− Gd(HMal)(Mal) |
Gd(Mal)2 | 7.57(5) | 7.57 | Gd 3+ + 2Mal2− Gd(Mal)2− |
Gd(Mal)(OH) | −3.26(5) | 10.51 | Gd3+ + Mal2−+ H2O Gd(Mal)(OH) + H+ |
Gd(Mal)(OH)2 ** | −11.83(4) | 5.20 | Gd(Mal)(OH) + H2O Gd(Mal)(OH)2− + H+ |
Gd(Mal)2(OH) *** | 0.67(6) | 6.87 | Gd(Mal)2− + H2O Gd(Mal)2(OH)2− + H+ |
Gd(Mal)2(OH)2 *** | −7.78(4) | 5.32 | Gd(Mal)(OH) + H2O Gd(Mal)(OH)2− + H+ |
Tb(III)-Mal | |||
Tb(HMal)(Mal) | 12.81(3) | 8.11 | Tb3+ + HMal− + Mal2− Tb(HMal)(Mal) |
Tb(Mal)2 | 6.80(4) | 6.80 | Tb3+ + 2Mal2− Tb(Mal)2− |
Tb(Mal)(OH) ** | −3.46(4) | 10.31 | Tb3+ + Mal2−+ H2O Tb(Mal)(OH) + H+ |
Tb(Mal)2(OH) | −0.06(1) | 6.91 | Tb(Mal)2− + H2O Tb(Mal)2(OH)2− + H+ |
Tb(Mal)2(OH)2 *** | −8.98(9) | 4.85 | Tb(Mal)2(OH)2− + H2O Tb(Mal)2(OH)23− + H+ |
Ho(III)-Mal | |||
Ho(HMal)(Mal) | 12.56(2) | 7.86 | Ho3+ + HMal− + Mal2− Ho(HMal)(Mal) |
Ho(Mal)2 | 6.86(6) | 6.86 | Ho3+ + 2Mal2− Ho(Mal)2− |
Ho(Mal)(OH) ** | −3.00(3) | 10.77 | Ho3+ + Mal2−+ H2O Ho(Mal)(OH) + H+ |
Ho(Mal)(OH)2 ** | −11.50(4) | 5.27 | Ho(Mal)(OH) + H2O Ho(Mal)(OH)2− + H+ |
Ho(Mal)2(OH) *** | −0.36(3) | 6.55 | Ho(Mal)2− + H2O Ho(Mal)2(OH)2− + H+ |
Lu(III)-Mal | |||
Lu(HMal)(Mal) | 12.70(2) | 8.00 | Lu3+ + HMal− + Mal2− Lu(HMal)(Mal) |
Lu(Mal)2 | 8.55(2) | 8.55 | Lu3+ + 2Mal2− Lu(Mal)2− |
Lu(Mal)(OH) | −2.32(3) | 11.45 | Lu3+ + Mal2−+ H2O Lu(Mal)(OH) + H+ |
Lu(Mal)2(OH) | 1.74(4) | 6.96 | Lu(Mal)2− + H2O Lu(Mal)2(OH)2− + H+ |
La(III)/Mal | Nd(III)/Mal | Gd(III)/Mal | Tb(III)/Mal | Ho(III)/Mal | Lu(III)/Mal |
---|---|---|---|---|---|
pH = 3.0 Δε (nm) 0.44 (213) 0.67 (195) | pH = 3.3 Δε (nm) −0.71 (215) −0.85 (208) 1.77 (191) | pH = 4.4 Δε (nm) −2.56 (207) | pH = 4.6 Δε (nm) −2.43 (208) 4.11 (186) | pH = 4.3 Δε (nm) −2.97 (210) −3.00 (206) −3.78 (189) | pH = 3.3 Δε (nm) −2.05 (210) |
pH = 6.3 Δε (nm) −1.57 (211) 1.78 (192) | pH = 6.0 Δε (nm) −1.94 (212) | pH = 6.5 Δε (nm) −2.31 (207) | pH = 6.2 Δε (nm) −3.13 (207) | pH = 5.1 Δε (nm) −3.09 (210) | |
pH = 8.2 Δε (nm) −0.75 (220) −0.79 (212) 0.78 (196) | pH = 7.7 Δε (nm) −1.73 (207) 0.61 (191) | pH = 7.8 Δε (nm) −1.23 (214) −1.69 (204) −1.26 (196) | pH = 7.7 Δε (nm) −1.10 (218) −2.33 (205) | pH = 7.5 Δε (nm) −2.45 (207) −2.41 (201) | |
pH = 8.9 Δε (nm) 0.32 (213) 0.88 (198) | pH = 9.5 Δε (nm) −0.19 (223) 0.44 (213) 0.86 (203) 1.14 (194) | pH = 9.2 Δε (nm) −0.45 (223) 0.52 (194) | pH = 10.2 Δε (nm) 0.67 (211) 0.89 (194) | pH = 9.3 Δε (nm) −0.54 (215) −0.93 (207) −1.08 (197) |
La(III)/Mal | Nd(III)/Mal | Gd(III)/Mal | Tb(III)/Mal | Ho(III)/Mal | Lu(III)/Mal |
---|---|---|---|---|---|
pH = 2.5 Δε (nm) 1.13 (214) 1.22 (200) 1.44 (192) | pH = 3.5 Δε (nm) −1.36 (213) 1.81 (193) | pH = 3.7 Δε (nm) −1.44 (209) 3.51 (186) | pH = 4.2 Δε (nm) −2.86 (211) | pH = 4.4 Δε (nm) −3.04 (208) | pH = 3.7 Δε (nm) −2.38 (208) 3.72 (187) |
pH = 6.3 Δε (nm) −1.27 (212) | pH = 6. 0 Δε (nm) −2.27 (210) 2.12 (195) | pH = 5.8 Δε (nm) −2.41 (212) 4.68 (193) | pH = 6.2 Δε (nm) −2.98 (210) | pH = 6.3 Δε (nm) −2.90 (208) | pH = 5.6 Δε (nm) −3.38 (211) |
pH = 7.9 Δε (nm) −0.72 (216) −1.98 (205) −1.75 (200) | pH = 8.0 Δε (nm) −3.15 (196) | pH = 8.0 Δε (nm) −1.38 (215) −2.17 (206) −2.06 (197) | pH = 8.5 Δε (nm) −0.21 (217) −1.16 (200) | ||
pH = 9.2 Δε (nm) 2.33 (205) 2.53 (195) | pH = 9.0 Δε (nm) −0.44 (222) 0.25 (203) 0.84 (195) | pH = 9.8 Δε (nm) 1.85 (208) 1.53 (197) | pH = 10.3 Δε (nm) 0.88 (211) 1.30 (203) 0.69 (193) |
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Zabiszak, M.; Frymark, J.; Grajewski, J.; Jastrzab, R. Spectroscopic Studies of Lanthanide(III) Complexes with L-Malic Acid in Binary Systems. Int. J. Mol. Sci. 2024, 25, 9210. https://doi.org/10.3390/ijms25179210
Zabiszak M, Frymark J, Grajewski J, Jastrzab R. Spectroscopic Studies of Lanthanide(III) Complexes with L-Malic Acid in Binary Systems. International Journal of Molecular Sciences. 2024; 25(17):9210. https://doi.org/10.3390/ijms25179210
Chicago/Turabian StyleZabiszak, Michał, Justyna Frymark, Jakub Grajewski, and Renata Jastrzab. 2024. "Spectroscopic Studies of Lanthanide(III) Complexes with L-Malic Acid in Binary Systems" International Journal of Molecular Sciences 25, no. 17: 9210. https://doi.org/10.3390/ijms25179210