A Highly Sensitive Chitosan-Based SERS Sensor for the Trace Detection of a Model Cationic Dye
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the CS-SAMSA
2.1.1. Viscosity Average Molecular Weight
2.1.2. FT-IR Spectroscopy
2.1.3. 13C CP/MAS Solid-State NMR Spectra
2.1.4. Raman Spectroscopy
2.1.5. NIR Spectroscopy
2.1.6. Thermogravimetric Analysis (TGA)
2.2. Characterization of the Ag@CS-SAMSA
2.2.1. X-ray Photoelectron Spectroscopy (XPS)
2.2.2. FT-IR Spectroscopy
2.2.3. TEM
2.2.4. Raman Spectroscopy
2.2.5. Two-Dimensional Raman Spectral Mapping
2.2.6. UV-Vis Spectra of the Ag NPs on the Substrate
2.3. SERS Performance Studies and Raman Imaging
2.4. Calibration Curve and Determination of LOD and LOQ
2.5. Dye Adsorption
2.6. Enhancement Factor (EF)
2.7. Orientation of the Probe Molecules
2.8. Distance Dependence of SERS Signals
2.9. Effect of Ag NP Concentration
2.10. Regeneration, Reproducibility, and Storage Stability of the Substrate
3. Materials and Methods
3.1. Materials
3.2. Methods
3.2.1. Synthetic Methods
3.2.2. Characterization Methods
3.2.3. Adsorption Studies, Isotherm, and Modelling
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Vafakish, B.; Wilson, L.D. A Highly Sensitive Chitosan-Based SERS Sensor for the Trace Detection of a Model Cationic Dye. Int. J. Mol. Sci. 2024, 25, 9327. https://doi.org/10.3390/ijms25179327
Vafakish B, Wilson LD. A Highly Sensitive Chitosan-Based SERS Sensor for the Trace Detection of a Model Cationic Dye. International Journal of Molecular Sciences. 2024; 25(17):9327. https://doi.org/10.3390/ijms25179327
Chicago/Turabian StyleVafakish, Bahareh, and Lee D. Wilson. 2024. "A Highly Sensitive Chitosan-Based SERS Sensor for the Trace Detection of a Model Cationic Dye" International Journal of Molecular Sciences 25, no. 17: 9327. https://doi.org/10.3390/ijms25179327