The sensing characteristics of a yttria-stabilized zirconia (YSZ)-based sensor utilizing a NiO sensing-electrode (SE) towards toluene (C
7H
8) and interfering gases (C
3H
6, H
2, CO, NO
2 and C
2H
5OH) were evaluated with a view to selective C
7H
8 monitoring in indoor atmospheres. The fabricated YSZ-based sensor showed preferential responses toward 480 ppb C
2H
5OH, rather than the target 50 ppb C
7H
8 at an operational temperature of 450 °C under humid conditions (RH ⋍ 32%). To overcome this limitation, the catalytic activity of Cr
2O
3, SnO
2, Fe
2O
3 and NiO powders were evaluated for their selective ethanol oxidation ability. Among these oxides, SnO
2 was found to selectively oxidize C
2H
5OH, thus improving C
7H
8 selectivity. An inline pre-catalytic cell loaded with SnO
2 powder was installed upstream of the YSZ-based sensor utilizing NiO-SE, which enabled the following excellent abilities by selectively catalyzing common interfering gases; sensitive ppb level detection of C
7H
8 lower than the established Japanese Guideline value; low interferences from 50 ppb C
3H
6, 500 ppb H
2, 100 ppb CO, 40 ppb NO
2, as well as 480 ppb C
2H
5OH. These operational characteristics are all indicative that the developed sensor may be suitable for real-time C
7H
8 concentration monitoring in indoor environments.
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