Since huge amounts of CH
4 are bound in natural gas hydrates occurring at active and passive continental margins and in permafrost regions, the production of natural gas from hydrate-bearing sediments has become of more and more interest. Three different methods to destabilize hydrates and release the CH
4 gas are discussed in principle: thermal stimulation, depressurization and chemical stimulation. This study focusses on the thermal stimulation using a counter-current heat-exchange reactor for the
in situ combustion of CH
4. The principle of
in situ combustion as a method for thermal stimulation of hydrate bearing sediments has been introduced and discussed earlier [1,2]. In this study we present the first results of several tests performed in a pilot plant scale using a counter-current heat-exchange reactor. The heat of the flameless, catalytic oxidation of CH
4 was used for the decomposition of hydrates in sand within a LArge Reservoir Simulator (LARS). Different catalysts were tested, varying from diverse elements of the platinum group to a universal metal catalyst. The results show differences regarding the conversion rate of CH
4 to CO
2. The promising results of the latest reactor test, for which LARS was filled with sand and ca. 80% of the pore space was saturated with CH
4 hydrate, are also presented in this study. The data analysis showed that about 15% of the CH
4 gas released from hydrates would have to be used for the successful dissociation of all hydrates in the sediment using thermal stimulation via
in situ combustion.
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