Insight into the Effect of Counterions on the Chromatic Properties of Cr-Doped Rutile TiO2-Based Pigments
Abstract
:1. Introduction
2. Experimental Procedure
2.1. Materials
2.2. Synthesis of Ti0.9−xCr0.1MxO2 Pigment
2.3. Characterization Techniques
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Oxides | SiO2 | Al2O3 | CaO | BaO | MgO | Na2O | K2O | ZnO | ZrO2 | Fe2O3 |
---|---|---|---|---|---|---|---|---|---|---|
Content/% | 65.70 | 13.00 | 5.84 | 4.00 | 0.86 | 3.52 | 0.79 | 0.51 | 5.50 | 0.20 |
Dopant Elements | Cr | Cr/Sb | Cr/Nb | Cr/W | Cr/Mo |
---|---|---|---|---|---|
Eg/eV | 1.83 | 2.28 | 2.21 | 2.03 | 1.36 |
λi/nm | 677 | 543 | 561 | 610 | 911 |
Doped Elements | Conditions | L* | a* | b* | ΔE* |
---|---|---|---|---|---|
10% Cr | Untreated | 41.06 | 12.00 | 17.54 | - |
5% HCl | 39.85 | 12.12 | 16.88 | 1.38 | |
5% H2SO4 | 40.25 | 12.64 | 17.85 | 1.08 | |
5% NaOH | 39.70 | 12.60 | 19.44 | 2.41 | |
10% Cr + 10% Sb | Untreated | 62.75 | 25.15 | 46.64 | - |
5% HCl | 61.53 | 25.69 | 46.36 | 1.36 | |
5% H2SO4 | 61.82 | 25.69 | 46.02 | 1.24 | |
5% NaOH | 61.55 | 25.26 | 46.23 | 1.27 | |
10% Cr + 10% Nb | Untreated | 52.13 | 26.14 | 41.44 | - |
5% HCl | 52.95 | 27.46 | 41.06 | 1.59 | |
5% H2SO4 | 52.20 | 27.98 | 41.18 | 1.86 | |
5% NaOH | 52.67 | 28.04 | 41.52 | 1.98 | |
10% Cr + 10% W | Untreated | 36.44 | 21.68 | 13.69 | - |
5% HCl | 38.21 | 22.19 | 14.54 | 2.44 | |
5% H2SO4 | 38.65 | 21.84 | 13.96 | 2.23 | |
5% NaOH | 36.78 | 23.03 | 14.21 | 1.49 | |
10% Cr + 10% Mo | Untreated | 29.17 | 3.60 | −1.81 | - |
5% HCl | 28.11 | 2.79 | −1.78 | 1.33 | |
5% H2SO4 | 28.63 | 2.74 | −1.96 | 1.03 | |
5% NaOH | 28.98 | 2.76 | −2.61 | 1.18 |
Doped Elements | L* | a* | b* | C* |
---|---|---|---|---|
10% Cr | 41.63 | 12.82 | 27.02 | 29.91 |
10% Cr + 10% Sb | 54.28 | 21.96 | 49.46 | 54.12 |
10% Cr + 10% Nb | 43.93 | 23.31 | 43.33 | 49.20 |
10% Cr + 10% W | 37.15 | 16.38 | 14.21 | 21.68 |
10% Cr + 10% Mo | 29.99 | 4.11 | 6.50 | 7.69 |
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Zhou, X.; Zhang, X.; Zou, C.; Chen, R.; Cheng, L.; Han, B.; Liu, H. Insight into the Effect of Counterions on the Chromatic Properties of Cr-Doped Rutile TiO2-Based Pigments. Materials 2022, 15, 2049. https://doi.org/10.3390/ma15062049
Zhou X, Zhang X, Zou C, Chen R, Cheng L, Han B, Liu H. Insight into the Effect of Counterions on the Chromatic Properties of Cr-Doped Rutile TiO2-Based Pigments. Materials. 2022; 15(6):2049. https://doi.org/10.3390/ma15062049
Chicago/Turabian StyleZhou, Xiaojian, Xiaozhen Zhang, Chunhai Zou, Renhua Chen, Lanlan Cheng, Botao Han, and Huafeng Liu. 2022. "Insight into the Effect of Counterions on the Chromatic Properties of Cr-Doped Rutile TiO2-Based Pigments" Materials 15, no. 6: 2049. https://doi.org/10.3390/ma15062049