Recent Advances in Metal–Organic Framework (MOF)-Based Composites for Organic Effluent Remediation
Abstract
:1. Introduction
2. Synthesis Methods of MOF-Based Materials
2.1. Conventional Methods for the Synthesis of MOFs
2.2. Advanced Methods for the Synthesis of MOFs
2.2.1. Electrochemical Synthesis
2.2.2. Microwave-Assisted Synthesis
3. Functional Regulations of MOF-Based Materials
3.1. Structural Regulation
3.1.1. Aerogels and Hydrogels
3.1.2. Nanostructured Membranes
3.2. Functional Regulation
3.2.1. Composites of 0D Materials with MOF-Based Materials
3.2.2. Composites of 1D Materials with MOF-Based Materials
3.2.3. Composites of 2D Materials with MOF-Based Materials
4. Application of MOF-Based Materials for Treating Organic Effluents
4.1. Removal of Organic Dyes
4.2. Removal of Agricultural Pollutants
4.3. Removal of Oil Contaminants
5. Conclusions and Outlooks
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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MOF-Based Material | Pollutants Removed | Preparation Method | Advantages | Ref. |
---|---|---|---|---|
SM-3 | Iodine and dyes | Solvothermal method | High selectivity | [99] |
MIL-101 (Cr), MIL-101(Fe) | Methyl orange dye | Infiltration method | Excellent adsorption capacity, simple one-step infiltration, excellent adsorption properties and simple operation | [100] |
ZIF-L, UiO-66-NH2 | Dye | Spray deposition and post-stabilization | High water permeance and excellent dye rejection | [108] |
CoSx composite membrane ZIF-67-derived CoSx | Dye Desalination of dyes | Solvothermal method In situ sulfurization | Outstanding permeance and excellent rejection | [109] |
xOy=Ag2O and ZnO | MB and MO azo dyes | Sol–gel method | Definite durability | [110] |
iMOF-14C | Antibiotics and pesticides | Solvothermal method | High selectivity and low detection limit | [128] |
Cu-BTC@ CA | Dimethoate pesticide | In situ synthesis | High adsorbability, large adsorption capacity and good recoverability | [123] |
MOF-525 and MOF-545 | Sulfamethoxazole | Solvothermal method | Great adsorption capacity and good reusability | [124] |
V2O5@Ch/Cu-TMA | Levofloxacin drug and Cr(Vl) | Solvothermal method | High efficiency | [125] |
NH2-UiO-101-Zr@Ox-cotton | Dye | Non-aqueous method | Large adsorption capacity and good recyclability | [131] |
M-ZIF-8@ZIF-67 | Fipronil and its metabolites | Solvothermal method | High adsorption capacity | [132] |
PVDF membranes | Oil | Delayed phase inversion | Good stability and excellent recyclability | [140] |
PLA/ZIF-8 | Dye wastewater | Solvothermal method | Increased oil wettability and significantly improved mechanical property | [141] |
HKUST-1 MOFs | Oil | Solvothermal method | High separation efficiency and good repeatability | [143] |
MOF-5/PDA/SSM | Oil | Solvothermal method | Outstanding separation efficiency, excellent recyclability and high water flux | [144] |
Cu(BDC)MOF | Oil | Solvothermal method | Excellent stability, exhibited good compressibility and reusability | [145] |
SH-UiO-66 | Heavy and light oils | Solvothermal method | High water resistance, high oil absorption capacity and good reversibility | [147] |
Ti3C2-Mxene | Oil | Solvothermal method | High hydrophobicity, abundant porosity and sufficient mechanical strength | [149] |
NH2-MIL-125 (Ti) | Pesticide | Solvothermal method | High removal rate | [149] |
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Tang, S.; Wang, Y.; He, P.; Wang, Y.; Wei, G. Recent Advances in Metal–Organic Framework (MOF)-Based Composites for Organic Effluent Remediation. Materials 2024, 17, 2660. https://doi.org/10.3390/ma17112660
Tang S, Wang Y, He P, Wang Y, Wei G. Recent Advances in Metal–Organic Framework (MOF)-Based Composites for Organic Effluent Remediation. Materials. 2024; 17(11):2660. https://doi.org/10.3390/ma17112660
Chicago/Turabian StyleTang, Shuxian, Yuxuan Wang, Peng He, Yan Wang, and Gang Wei. 2024. "Recent Advances in Metal–Organic Framework (MOF)-Based Composites for Organic Effluent Remediation" Materials 17, no. 11: 2660. https://doi.org/10.3390/ma17112660