Transformation of Cu2O into Metallic Copper within Matrix of Carboxylic Cation Exchangers: Synthesis and Thermogravimetric Studies of Novel Composite Materials
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of CCEs with Metallic Copper Particles
2.3. X-ray Powder Diffraction Analysis
2.4. Attenuated Total Reflectance–Fourier Transform Infrared Spectroscopy (ATR-FTIR)
2.5. Scanning Electron Microscopy Analysis (SEM)
2.6. Thermogravimetric Analysis
3. Results and Discussion
3.1. Metallic Copper Deposition within G/H, M/H to Obtain G/H#Cu, M/H#Cu
3.2. Attempt to Obtain G/Na#Cu, M/Na#Cu
3.3. Thermogravimetric Studies, G/H vs. G/H#Cu, M/H vs. M/H#Cu
3.4. Thermal Analysis as a Useful Method for Evaluating CuO-, Cu2O-, Cu0-Doped Carboxylic Cation Exchangers
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Code | Cu, mg/g | Water, % * |
---|---|---|
G/Cu | 228.9 | 10.22 |
M/Cu | 217.9 | 9.37 |
G/Na#Cu2O | 199.2 | 15.96 |
M/Na#Cu2O | 180.3 | 21.35 |
Sample Code | Water Mass Loss, wt% | Peak Temperature of Polymer Decomposition, °C | End Temperature, °C | Residual Mass at 900 °C, wt% |
---|---|---|---|---|
(a) Decomposition in air | ||||
G/H | 6.04 | 284.7, 426.9, 524.2 | 552.1 | 0.00 |
G/H#Cu | 5.96 | 266.3, 344.2, 458.4 | 484.6 | 26.28 |
M/H | 4.05 | 238.1, 416.3, 487.4 | 503.6 | 0.00 |
M/H#Cu | 7.91 | 230.6, 312.4, 407.0 | 487.0 | 22.80 |
(b) Decomposition in N2 | ||||
G/H | 5.89 | 284.1, 440.9 | 458.8 | 12.17 |
G/H#Cu | 5.99 | 258.3, 413.9 | 439.3 | 39.35 |
M/H | 4.84 | 239.9, 429.2 | 441.0 | 6.10 |
M/H#Cu | 7.53 | 231.6, 303.5, 417.7 | 439.1 | 26.23 |
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Kociołek-Balawejder, E.; Winiarska, K.; Winiarski, J.; Mucha, I. Transformation of Cu2O into Metallic Copper within Matrix of Carboxylic Cation Exchangers: Synthesis and Thermogravimetric Studies of Novel Composite Materials. Materials 2024, 17, 3893. https://doi.org/10.3390/ma17163893
Kociołek-Balawejder E, Winiarska K, Winiarski J, Mucha I. Transformation of Cu2O into Metallic Copper within Matrix of Carboxylic Cation Exchangers: Synthesis and Thermogravimetric Studies of Novel Composite Materials. Materials. 2024; 17(16):3893. https://doi.org/10.3390/ma17163893
Chicago/Turabian StyleKociołek-Balawejder, Elżbieta, Katarzyna Winiarska, Juliusz Winiarski, and Igor Mucha. 2024. "Transformation of Cu2O into Metallic Copper within Matrix of Carboxylic Cation Exchangers: Synthesis and Thermogravimetric Studies of Novel Composite Materials" Materials 17, no. 16: 3893. https://doi.org/10.3390/ma17163893