ZIF-67/SA@PVDF Ultrafiltration Membrane with Simultaneous Adsorption and Catalytic Oxidation for Dyes
Abstract
:1. Introduction
2. Experimental Work
2.1. Materials
2.2. Preparation of ZIF-67
2.3. Preparation of PVDF, ZIF-67@PVDF and (Z)SAx@PVDF Membranes
2.4. Characterizations
2.5. Evaluation of Adsorption Performance
2.6. Evaluation of Self-Cleaning Performance
3. Result and Discussion
3.1. Characterizations
3.2. Static Adsorption Performance
3.3. The Permeability and Dynamic Removal Ability of MB
3.4. Membrane Self-Cleaning Performance
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Appendix A
References
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Membranes | SA | PVDF | ZIF-67 | DMAC |
---|---|---|---|---|
(wt%) | (wt%) | (wt%) | (wt%) | |
PVDF | 0 | 8 | 0 | 92 |
ZIF-67@PVDF | 0 | 8 | 1 | 91 |
SA1@PVDF | 1 | 8 | 0 | 91 |
SA2@PVDF | 2 | 8 | 0 | 90 |
SA3@PVDF | 3 | 8 | 0 | 89 |
ZSA3@PVDF | 3 | 8 | 1 | 88 |
Material | Specific Surface Area | Average Pore Diameter |
---|---|---|
(m2/g) | (nm) | |
SA | 887.39 | 3.66 |
ZIF-67 | 1363.94 | 2.61 |
Membranes | Ra (nm) | Rq (nm) |
---|---|---|
PVDF | 15.7 | 21.7 |
ZIF-67@PVDF | 47 | 64 |
SA1@PVDF | 52.8 | 67.4 |
SA2@PVDF | 65.8 | 82.3 |
SA3@PVDF | 94.3 | 83.6 |
ZSA3@PVDF | 112 | 139 |
Membranes | Pseudo-First-Order | Pseudo-Second-Order | ||||
---|---|---|---|---|---|---|
k1 (min−1) | R12 | qe (mg g−1) | k2 (min−1) | R22 | qe (mg g−1) | |
PVDF | 0.0413 | 0.9827 | 4.77 | 0.0104 | 0.9974 | 5.22 |
ZIF-67@PVDF | 0.0333 | 0.9900 | 9.05 | 0.0044 | 0.9993 | 9.96 |
SA1@PVDF | 0.0268 | 0.9906 | 9.84 | 0.0030 | 0.9972 | 10.98 |
SA2@PVDF | 0.0267 | 0.9952 | 12.48 | 0.0024 | 0.9971 | 13.90 |
SA3@PVDF | 0.0356 | 0.9848 | 15.21 | 0.0029 | 0.9960 | 16.60 |
ZSA3@PVDF | 0.0419 | 0.9908 | 17.14 | 0.0028 | 0.9971 | 18.68 |
Membranes | Adsorption Capacity for Different Dyes | ||
---|---|---|---|
AO7 | RhB | MB | |
PVDF | 2.505 | 17.11 | 5.22 |
ZSA3@PVDF | 11.875 | 21.165 | 18.68 |
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Zhu, K.; Mohammed, S.; Tang, H.; Xie, Z.; Fang, S.; Liu, S. ZIF-67/SA@PVDF Ultrafiltration Membrane with Simultaneous Adsorption and Catalytic Oxidation for Dyes. Sustainability 2023, 15, 2879. https://doi.org/10.3390/su15042879
Zhu K, Mohammed S, Tang H, Xie Z, Fang S, Liu S. ZIF-67/SA@PVDF Ultrafiltration Membrane with Simultaneous Adsorption and Catalytic Oxidation for Dyes. Sustainability. 2023; 15(4):2879. https://doi.org/10.3390/su15042879
Chicago/Turabian StyleZhu, Kaixuan, Shabin Mohammed, Hai Tang, Zongli Xie, Sisheng Fang, and Shasha Liu. 2023. "ZIF-67/SA@PVDF Ultrafiltration Membrane with Simultaneous Adsorption and Catalytic Oxidation for Dyes" Sustainability 15, no. 4: 2879. https://doi.org/10.3390/su15042879