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Article

An Innovative Approach to Enhance the Durability and Sustainability of Shoe Insoles

1
School of Engineering and Technology, National Textile University, Faisalabad 37610, Pakistan
2
Department of Textile Engineering, Faculty of Technology, Marmara University, 34854 Istanbul, Türkiye
3
Department of Entrepreneurship and Management, National University of Science and Technology Politehnica Bucharest, Splaiul Independentei 313, 060042 Bucharest, Romania
4
Academy of Romanian Scientists, Ilfov 3, 050044 Bucharest, Romania
*
Authors to whom correspondence should be addressed.
Sustainability 2024, 16(21), 9195; https://doi.org/10.3390/su16219195
Submission received: 5 September 2024 / Revised: 17 October 2024 / Accepted: 17 October 2024 / Published: 23 October 2024

Abstract

:
This study presents an innovative approach to designing a shoe insole with enhanced durability, sustainability, and antibacterial properties. Needle-punched non-woven recycled polyester fabrics with three different GSMs (100, 200, and 300) were developed. The composite shoe insole was developed using non-woven fabric laminated with a polyurethane sheet to enhance durability. The fabrics were treated with an antibacterial finish with three different concentrations (5%, 10%, and 15%) and subjected to 5 and 10 washing cycles. The developed composites were evaluated against their relative hand value, abrasion resistance, tensile strength, antibacterial activity, and overall moisture management capability. Overall results reveal that the developed composite shoe insole is durable, sustainable, and presents no bacterial growth, demonstrating the insole’s hygienic effectiveness.

1. Introduction

One of the fastest-growing segments of technical textiles is medical textiles, which includes products like bio-scaffolds, bandages, dressing materials, personal protective equipment (PPE), and medicated footwear [1]. These medically formulated shoes are designed to reduce people’s discomfort with specific foot issues. Diabetes and foot ulcers are the two conditions that frequently call for these shoes [2]. It is essential to consider that the textile materials used to make insoles should be comfortable, breathable, stretchy, robust, and sustainable [3]. Sustainability is an essential aspect of product development, and through recycling, the need for raw materials and valuable natural resources is significantly reduced. Recycled polyester (rPET) is made from recycled plastic. It is an excellent way to prevent plastic from ending up in the trash [4]. Compared to fresh polyester, rPET requires much fewer resources and emits less CO2. It is a robust, flexible, and durable material manufactured from synthetic fibers, just like traditional (or virgin) polyester [5]. In addition, rPET is an excellent heat insulator, lightweight, breathable, promotes optimal ventilation, and reduces sweat accumulation [6]. The non-woven technique can enhance comfort, as non-woven insoles provide cushioning, support, and protection for the foot. For insoles, durability plays a crucial role in terms of reuse [7]. Polyurethane (PU) is exceptionally durable since it has been utilized as a special coating for heavy-duty and industrial applications. It has shock absorption properties and does not break or wear out quickly. PU is much better than most synthetic leather substitutes. It can be utilized as a lamination for insoles since it is more durable than thermoplastics [8]. The direct contact between insoles and human skin necessitates their antibacterial properties. Wearing shoes for an extended period can lead to perspiration on our feet, which can harbor bacteria and give off an unpleasant odor [9]. Antibacterial finishes can aid in solving this issue. A textile with an antimicrobial finish ideally satisfies the needs of the consumer by being effective against a variety of bacterial and fungal species while being low in toxicity, non-irritating, hypoallergenic, and preserving the natural flora of nonpathogenic microorganisms that reside on the skin of the wearer [10]. The demand for antimicrobial fabrics has grown by double digits during the last few years. For that matter, the shoe insole industry has achieved notable growth as customers become more aware of sustainable and health-conscious products [11].
Consequently, researchers have extensively focused on developing shoe insoles to address these demands and meet customer expectations. Bratchenya et al. found that bamboo fiber absorbs more moisture and is more potent than viscose, which validates its usage in eco-friendly insoles [12]. Rajan et al. claimed that the most suitable spacer textiles for balancing permeability and thermal qualities are those with moderate porosity and a thickness of around 3 mm for insoles [13]. Fatkullina et al., in their findings, demonstrate that low-temperature plasma-treated felt layers enhance water absorption and antimicrobial qualities, making them a suitable option for rehabilitation footwear [14]. Zhao et al.‘s research shows that although silicone insoles are long-lasting, their uneven surface and softness might be uncomfortable for the user [15]. Azam et al. combined natural fibers such as tencel/flax and bamboo/hemp with alginate hydrogel to create environmentally friendly shoe insoles. This composite showed improved overall moisture management capability (OMMC) and tensile strength by crosslinking via a sol-gel process. The final product reduced odor, created a dry foot environment and exhibited environmental sustainability [16]. Shuhua et al. focuses on developing antibacterial composite fibers from poly(ethylene terephthalate) (PET) by combining it with antibacterial components using a twin-screw extruder. These fibers, produced through high-speed melt-spinning, have over 90% antibacterial activity while retaining significant mechanical qualities. The findings indicate that such antibacterial PET composites might be efficiently used in footbeds to improve comfort and hygiene in shoe insoles [17].
Lum et al. found that cork was more biodegradable and used fewer resources in a comparison of the environmental effects of cork and rubber/plastic insoles; however, cork has drawbacks such as poor cushioning and water sensitivity, which need careful consideration before it is widely used [18]. In previous research focusing on insole manufacturing, techniques such as needle punching and heat bonding were used to improve fiber tangling and surface texture uniformity in non-woven materials. Spacer cloth production techniques have also been employed to enhance compression and texture. Furthermore, layering has been widely used, whereas polymer lamination has been used to promote durability and maintain structural integrity, notably minimizing distortion after washing [19].
As mentioned above, many insoles are available in the market for various purposes, specifically for their antibacterial properties, but somehow, they all lack durability, which is the feature that ought to be most important for an insole. In this research, we are developing an antibacterial shoe insole designed to meet high durability requirements through PU lamination while utilizing non-woven rPET to ensure comfort and sustainability. Additionally, the insole is treated with a Silvadur® finish to provide long-lasting antibacterial properties, making it a suitable option for everyday use. By combining these materials, we aim to develop an innovative, durable, and eco-friendly product that offers excellent performance, comfort, and hygiene.
Durable and hygienic shoe insoles are becoming more and more necessary, particularly for people with foot issues like infections and ulcers. Many insoles in the market today are not suited for prolonged usage because they either break down easily or do not offer antibacterial protection. Furthermore, there is a market for environmentally friendly insoles that still offer comfort and functionality due to the growing emphasis on sustainability. By providing a solution that blends sustainability, durability, and antibacterial qualities, this insole seeks to solve these problems and improve overall comfort and foot health. Though laminated textiles are used in many fields, there is not much work done on using this technique to increase the durability of sustainable materials in shoes. This study shows that the insole’s durability and wear resistance are significantly increased without sacrificing its sustainability by using PU lamination on RPET. The innovative approach of applying polymer lamination to create a long-lasting, environmentally friendly footbed meets the demands of the footwear industry for both performance and environmental responsibility. Innovative footwear design is vital because it directly affects the health and well-being of people, particularly those who suffer from infections and foot ulcers. Furthermore, by emphasizing sustainability in this subject, wider environmental issues are addressed while guaranteeing that the demands of those with limited resources are satisfied.

2. Experimental

2.1. Materials

Recycled polyester (rPET) fibers were sourced from Gulf Fiber Company Pvt. Ltd. (Lahore, Pakistan) with a length of 38 mm, a linear density of 1.47 deniers, and a tenacity of 48.55 N/tex. A polyester-based PU lamination sheet with 18 g per square meter (GSM) and a breathability of 38.454 g/h·m2 was generously provided by Chawla Enterprises in Faisalabad, Pakistan. Silvadur® 930FLEX Antimicrobial finish was purchased from DuPont®.

2.2. Design of Experiment

Using the Design of Experiments (DOE) methodology, an experiment was designed to examine the effects of input factors on response variables (Table 1). Full factorial design was created by using Minitab® 18 software as shown in Table 2. A full factorial design was used for our experiment because it allows for a comprehensive evaluation of all possible combinations of factors and levels, providing valuable insights into their interactions.

2.3. Methodology

2.3.1. Development of rPET Non-Woven Fabric

Non-woven fabrics of rPET with three different GSM (100, 200, and 300) were developed using the non-woven machine (Dongwong-roll Co., Ltd., Incheon, Republic of Korea) (Figure 1). For the web formation, the fibers were manually opened and passed through a series of machines, including a coarse fiber opening machine (DW-B/0), a fine opener (DW-F/0), a reserve hopper feeder (DW-C/H), a baby carding machine (DW-C/H), and a cross lapper (DW-C/L). Further, the created web was fed into a needle punching machine (DW/NP) with a 10 mm depth for the web bonding [16]. The non-woven recycled polyester (rPET) sample has high resilience and tensile strength, making it suitable for long-lasting shoe insoles. Its non-woven construction improves delamination resistance and ensures integrity under stress. Furthermore, the optimized GSM increases stretchability and overall performance [20]. Figure S21 shows the microscopic images of non-woven rPET with and without lamination and its structural differences across treatments.

2.3.2. PU Lamination

The non-woven fabrics were laminated with PU using a lamination machine (Jiangsu Kuntai Machinery Co., Ltd., Yancheng, China). This machine has two horizontal rollers; one roller passes the non-woven fabric, while the upper second roller passes the PU sheet. Both layers were fused with reactive polyurethane (PUR) hot-melt adhesive, poured from the side pipe. PUR is well known for its outstanding adherence to a variety of substrates, resulting in high bonding strength while being flexible. It also has high resistance to moisture, chemicals, and temperature changes, making it appropriate for a variety of applications, such as textiles and footwear. In this study, the adhesive used for lamination resisted up to ten washing cycles, maintaining its durability and assuring long-lasting performance [21]. After lamination, samples were dried for 24 h under ambient conditions.

2.3.3. Silver-Based Finish Application

The methodology was adapted from the literature and modified according to the study requirement to yield a composite insole having antibacterial characteristics (Figure 2). At first, the colloidal solution of Silvadur® was diluted into three different concentrations of 5%, 10%, and 15% with distilled water at room temperature (24 °C). The finish was applied to the fabric through the pad–dry–cure method by dipping the samples in the prepared solution and ensuring a thorough soaking. Excessive solution from the samples was removed by passing them through padding rollers at a constant pressure of 2 bars. Further, samples were dried and cured at 150 °C for 3 min in a curing machine (Dongwong-roll Co., Ltd.) [22].

2.3.4. Washing

Samples were washed according to ISO 105-C03 [23]. In this method, a soap solution (5 gm soap and 2 gm anhydrous sodium carbonate per liter of water) was used at 60 °C for 30 min per cycle [24]. Samples were subjectsesd to 5 and 10 washing cycles to evaluate the fabric’s antibacterial performance and durability. This washing test aimed to ascertain how such harsh washing conditions would affect the fabric’s strength and surface texture.

2.4. Characterization

2.4.1. Relative Hand Value Test

The relative hand value (RHV) indicates a consumer’s overall response to a fabric [25]. It was evaluated using the fabric assessment system Phabrometer under the AATCC-202 standard [26]. The RHV assessment was conducted using a sample size of diameter 11 cm. This standard predicts the tactile sensations humans experience while handling the fabric. This system measures the values of the fabric’s resilience, softness, smoothness, and wrinkle recovery rate [27].

2.4.2. Moisture Management Test

The OMMC index measures the fabric’s overall capacity to control liquid moisture transport [28]. This study used the AATCC TM 195 standard [29] to determine the OMMC. In this standard, a sample (diameter 11 cm) was placed in the apparatus horizontally between the upper and lower sensors to analyze the liquid transport characteristics of the fabric. These sensors are composed of concentric rings of pins. A solution was dropped on the upper surface of the sample without any pressure applied [30].
AATCC TM 195; Liquid Moisture Management Properties of Textile Fabrics.

2.4.3. Antibacterial Test

The antibacterial activity of treated fabric was conducted through qualitative and quantitative methods. A qualitative method was employed by using S. aureus as a gram-positive bacteria according to the AATCC147 standard [31]. In this procedure, bacterial culture was scattered randomly on the surface of the agar plate. The test was performed using a sample size of 1 × 1 inch. The bacteria under the fabric were monitored by placing the fabric samples (2.5 cm × 2.5 cm) on the agar plate and incubating at 37 °C. The absence of bacterial growth on samples evidenced the antibacterial activity of the fabric [32].
The quantitative method accurately assesses the percentage of bacterial growth inhibition according to the AATCC100 standard [33]. In this standard, a fabric sample (4 cm × 4 cm) is used with 100 mL of bacterial culture solution containing 1 × 105 CFU/mL. The samples were then incubated at 37 °C for 24 h. Following incubation, the bacteria were removed from the fabric by vigorously shaking the samples in 100 mL of neutralizing solution for 1 min using a vortex mixer. The bacterial count was subsequently accessed through serial dilution and plating on nutrient agar. Two contact time assays were performed: the zero contact time assay, where bacteria was eluted right after inoculation, and the 24 h contact time assay, which elutes bacteria after 24 h of exposure. The antibacterial effectiveness was calculated using the formula
B a c t e r i a l   r e d u c t i o n % = ( B A ) B × 100
In Equation (1), B represents the bacterial colonies at 0 contact time and A signifies the count after 24 h [34].

2.4.4. Tensile Strength

The tensile strength of fabric samples was determined according to the ISO 13934-1 standard [35]. This method is also known as the grab test, which determines the maximum force a fabric can withstand [36]. The test was performed using samples with dimensions of 17 inches in length and 2.5 inches in width. The fabric sample was gripped from the upper and lower edges by jaws of a certain size and extended continuously until it ruptured. The point where the sample was ruptured with maximum force was recorded and measured in force per unit area [32].

2.4.5. Abrasion

Martindale abrasion tester was used to perform an abrasion test on the fabric samples according to the ISO 12947-2 standard (50,000 cycles for the laminated side and 20,000 cycles for the non-woven side) [37]. A circular fabric sample (10 cm × 10 cm) was mounted in a specimen holder. The fabric sample was rubbed against an abrasive medium while the specimen holder was rotating around its axis, perpendicular to the specimen’s plane, until a hole appeared or the material thinned to an unacceptable level [38].

3. Results and Discussion

3.1. Relative Hand Value

RHV quantitatively measures the tactile quality of the fabric. Resilience refers to the fabric’s resistance to deformation. It has been reported that fabric thickness, density, and structural integrity are the main factors that affect fabric resilience [39]. Higher GSM has more density, which provides better structural support and elasticity [40]. In this study, sample YZ (300 GSM) exhibited the highest value, while sample B (100 GSM) had the lowest value of resilience, as shown in Figure 3A, which supports the statement. However, antibacterial finish and washing mainly affect the fabric’s surface rather than altering core physical properties, leaving resilience unaffected [41]. Softness is related to the pliability of fabric. GSM affects the softness; heavier fabrics generally feel less soft due to their compact structure. Fabrics with lower GSM have fewer fibers per unit area, making them less dense and softer [42]. Sample B (100 GSM) has the highest softness, while sample Z (300 GSM) showed the lowest softness value, as shown in Figure 3B. Antibacterial finish and washing did not affect the softness for the same reasons identified regarding resilience.
Smoothness is related to fabric surface texture. According to the literature, GSM and washing affect the smoothness of the fabric [43]. However, in this study, the smoothness results fail to match the statement as shown in Figure 3C. Despite variations in GSM, finish, and washing, the consistent smoothness observed throughout the samples can be explained by the stability of the needle punching technique. This technique develops a robust and entangled fiber network that maintains a consistent surface texture for fabric [44]. Another attribute is the polymer lamination on the opposite side, which supports non-woven fabric and makes it less susceptible to changes from washing. This combination keeps the non-woven surface smooth and minimizes the impact of other factors [45]. The ability of a fabric to resist the formation of a crease or wrinkle when slightly squeezed is termed crease resistance. Polymer lamination has a significant effect on the wrinkle recovery rate due to its elastic nature. It recovers lower GSM faster than higher GSM samples because of its less dense structure and thickness, allowing the lamination to exert a more uniform and effective restorative force across the fabric sample, leading to quicker wrinkle recovery [46]. Sample U (100 GSM) showed the highest wrinkle recovery rate, and sample I (300 GSM) had the lowest, as shown in Figure 3D. As previously stated, the antibacterial finish and the washing process affect surface qualities rather than the fabric’s structure, explaining their lack of effect on wrinkle recovery [47].
After analyzing the graphs of RHV (resilience, softness, smoothness, and wrinkle recovery rate), a clear correlation between softness and wrinkle recovery rate can be observed. This indicates that fabric with higher softness tends to have a better wrinkle recovery rate, as reported in previous studies [48]. Softness and wrinkle recovery in the insole are correlated, as both increase when GSM is decreased. Softness is improved by reduced density and fewer fibers per unit area, and wrinkle recovery is improved by polymer lamination, which supports the non-woven side in recovering from wrinkles faster. The RHV results showed that among all samples tested, sample YZ stands out. This sample had 300 GSM, showing its durability and resilience with a 15% finish. Figures S1–S16 show the data and interaction plots that demonstrate the effects of GSM, finish concentration, and washing cycles on the RHV. The results allow for a statistical analysis of how each factor influences the tactile quality and durability of the samples. The sample also underwent ten washes, indicating that it maintains its properties well after repeated use, which is critical for a product like a shoe insole that experiences significant wear and tear.

3.2. Moisture Management

Moisture management is the ability of the fabric to absorb and wick away moisture. To determine the OMMC value in the AATCC TM 195 standard, the liquid is dropped on the surface without any pressure while analyzing its movement using specific metrics, such as absorption rate, wetting time, and spreading speed [49]. In this study, the standard resulted in a zero OMMC value for rPET non-woven samples, which means the fabric does not absorb any moisture in these testing circumstances due to the fabric’s surface tension and the hydrophobic nature of rPET. However, the sample absorbs moisture when slight pressure is applied, as shown in the Supplementary Video S1; the external force overcomes the surface tension, allowing the water to penetrate the fabric. The non-woven rPET fabric resists moisture under standard conditions but can absorb water when applying mechanical pressure, forcing the liquid into the inter-fiber spaces, as noted in previous studies [50]. This explains why the fabric absorbs water well under pressure while showing zero moisture management in the standard OMMC test. The standard test method may indicate a lack of moisture management as it does not fully capture the dynamic conditions experienced during real-life use, while practically all the samples can absorb sweat when foot pressure is applied to the insole.

3.3. Antibacterial Test

The non-woven rPET samples were pretreated with Silvadur® antibacterial finish to evaluate their antibacterial activity using a qualitative method (AATCC147) and a quantitative method (AATCC100). In Silvadur®, the active ingredient is silver ions (Ag+), which are known to prevent bacterial growth by affecting cellular processes. It also contains a polymeric carrier system, which acts as a stabilizing medium and regulates the release of silver ions. This method ensures the ions are delivered gradually, resulting in persistent antibacterial action.

3.3.1. Qualitative Antibacterial Test

In this method, a subset of 5 samples was selected from 27 samples to examine the antibacterial activity. Samples were selected based on the lowest and highest concentration (5–15%) of finish. This approach allows for a clear comparison of the extremes, providing insights into the effectiveness of the antibacterial treatment across different washing cycles (0, 5, and 10). The non-woven side of the samples faced the agar plate to note the bacterial growth under the samples [51]. According to the test results, no visible bacterial growth was observed under any samples, as shown in Figure 4 and Table 3. Hence, the samples treated with Silvadur® finish inhibited the growth of S. aureus bacteria, thus showing antibacterial efficacy. In this study, a qualitative test was conducted with a single bacterial strain (S. aureus) to demonstrate the antibacterial efficacy of our samples, as extensive research has already shown the efficacy of the same antibacterial finish (Silvadur) against a broad range of microorganisms, including gram-negative bacteria (Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa) and fungi [10].
The antibacterial test results showed no zone inhibition around the sample, demonstrating the zero inhibition zone, as shown in Table 3 This is due to the non-leaching nature of the antibacterial finish, which prevents it from spreading into the surrounding medium, consistent with existing knowledge [52].

3.3.2. Quantitative Antibacterial Test

The quantitative antibacterial assessment used 5 selected samples from a total of 27 samples in DOE, the same as in the qualitative method. An extra control sample was included for comparison (Figure 5). The results showed a considerable reduction in bacterial growth across all samples. The control sample C1 exhibited less than 10 ± 1% bacterial reduction due to the absence of an antibacterial finish, while sample I (15% finish, 0 wash) achieved a remarkable reduction of 91.25 ± 1.01%. Similarly, sample G (5% finish and 0 wash) also showed high efficacy with a reduction of 92.75 ± 1.24%, while sample YZ (15% finish, 10 washes) exhibited 85.03 ± 1% reduction, samples P (5% finish, 5 washes) and Y (5% finish, 10 washes) showed reductions of 82.3 ± 1.56% and 80.2 ± 1.50% respectively. This slight decrease in the efficiency of samples YZ, P, and Y can be attributed to the washing cycles, which most likely influenced the finish concentration, reducing antibacterial characteristics and resulting in slightly lower bacterial reduction percentages.

3.4. Tensile Strength Evaluation

Tensile strength refers to the fabric’s ability to bear the maximum force during stretching until it breaks. Sample I, with 300 GSM, 15% finish, and 0 washes, shows the highest, while Sample A, with 100 GSM, 5% finish, and 0 washings, shows the lowest tensile strength value, as shown in Figure 6. The data analysis demonstrates that an increase in GSM with an increase in finish concentration leads to a corresponding rise in tensile strength [40]. Higher GSM fabrics are more compact and have a denser structure, while the Silvadur® finish enhances fiber bonding, increasing the material’s strength, as mentioned in the literature [10]. Conversely, washing has minimal effect on tensile strength, indicating that fabric retains its durability and strength even after multiple washing cycles [53]. The elongation data in the graph shows a balance of flexibility and tensile strength among the samples. They display materials capable of significant stretching before breaking, which is important for applications that need elasticity and durability. Figures S17–S20 exhibit data and interaction plots demonstrating the impacts of GSM, finish concentration, and washing cycles on tensile strength and provide the statistical significance of these parameters on the tensile performance and durability of the samples.
To determine the effect of lamination on tensile strength, a comparative analysis was conducted using a non-woven rPET sample without lamination as a control (C2). The control sample, with 100 GSM, had a tensile strength of 65N and an elongation of 85%. In contrast, sample A had the lowest tensile strength of the laminated samples, as mentioned above, with a tensile strength of 75N and an elongation of 56%. The lower elongation in the laminated sample is due to the restriction of the fiber movement imposed by the lamination process, but it increases its tensile strength by providing more structural support [54].

3.5. Abrasion Resistance

Abrasion resistance is a fabric’s capacity to withstand wear and tear from rubbing or friction. This test was performed on 6 samples of non-woven rPET selected from the 27 samples, using the Martindale method. The test was conducted on both non-woven and laminated sides of the samples. For each side, six samples were taken from the same fabric samples (B, U, W, N, I, and Z). Each sample varied in GSM (100, 200, and 300) and was treated with three different finish concentrations (5%, 10%, and 15%). Four samples were subjected to 5 and 10 washing cycles, while two were unwashed. Results showed that the non-woven side of the samples withstood up to 20,000 cycles without showing significant damage, as shown in Figure 7A. The only noticeable effect was the displacement of surface fibers. The primary contributing factors were the rPET fibers’ durability and wear resistance, as well as the fact that the non-woven structure evenly distributes the stress across the fabric, reducing localized damage, despite variations in GSM and finish concentration [55]. Additionally, the polymer lamination prevents the fibers from being easily displaced. The test was continued from the other (laminated) side of the samples to measure durability under extended wear conditions. This side of the samples lasted up to 50,000 cycles without damage, as shown in Figure 7B. This result highlights the outstanding durability of PU lamination while showing its capacity to sustain significant mechanical stress, supporting results reported in the literature [56]. Hence, the durable polyester fibers, non-woven structure, and PU lamination contributed significantly to the fabric’s integrity throughout the abrasion resistance testing.

4. Conclusions

This study investigated the potential of utilizing non-woven rPET with polymer (PU) lamination to develop a shoe insole. The material was characterized based on its durability, sustainability, and comfort, with the addition of a Silvadur® finish to impart antibacterial properties. The findings demonstrate that when a fabric’s GSM increases, its resilience, smoothness, and tensile strength increase. Despite showing zero OMMC value under standard conditions, the insole adequately absorbs moisture under slight pressure, revealing its potential for moisture management in real-life situations. The abrasion resistance test determined that the non-woven side of the insole resisted up to 20,000 cycles, while the laminated side lasted up to 50,000 cycles, demonstrating the material’s durability. Furthermore, the antibacterial test confirmed no bacterial growth with zero zone inhibition, reinforcing the insole’s functional properties. The implications of these findings show that the insole meets the durability standards for footwear.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/su16219195/s1. Video S1: Moisture management capacity experimental video. Figure S1: Impact of GSM on resilience. Figure S2: Impact of finish concentration on resilience. Figure S3: Impact of washing on resilience. Figure S4: Interaction plot for resilience. Figure S5: Impact of GSM on softness. Figure S6: Impact of finish concentration on softness. Figure S7: Impact of washing on softness. Figure S8: Interaction plot for softness. Figure S9: Impact of GSM on smoothness. Figure S10: Impact of GSM on smoothness. Figure S11: Impact of washing on smoothness. Figure S12: Interaction plot for smoothness. Figure S13: Impact of GSM on wrinkle recovery. Figure S14: Impact of finish concentration on wrinkle recovery. Figure S15: Impact of washing on wrinkle recovery. Figure S16: Interaction plot for wrinkle recovery. Figure S17: Impact of GSM on tensile strength. Figure S18: Impact of washing on tensile strength. Figure S19: Impact of finish concentration on tensile strength. Figure S20: Interaction plot for wrinkle recovery. Figure S21: The microscopic images of the nonwoven samples.

Author Contributions

Conceptualization, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Methodology, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Software, Z.N., I.Z., S.R.B., M.U. and M.A.N.; Validation, Z.N., I.Z., S.R.B., M.U. and M.A.N.; Formal analysis, Z.N., I.Z., S.R.B., M.U. and M.A.N.; Investigation, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Resources, Z.N., I.Z., S.R.B., M.U. and M.A.N.; Data curation, Z.N., I.Z., S.R.B., M.U. and M.A.N.; Writing – original draft, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Writing – review & editing, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Visualization, Z.N., I.Z., S.R.B., M.U., A.I. and M.A.N.; Supervision, M.U. and M.A.N.; Project administration, M.A.N.; Funding acquisition, A.I. and M.A.N. All authors have read and agreed to the published version of the manuscript.

Funding

The schematics were made using the paid versions of CS6 Illustrator® and Biorender® (biorender.com). The authors acknowledge the funding from the Higher Education Commission of Pakistan under grant no. TTSF-195 for completing this research study.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Data are contained within the article and Supplementary Materials.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Morris, H.; Murray, R. Medical textiles. Text. Prog. 2020, 52, 1–127. [Google Scholar] [CrossRef]
  2. Ulbrecht, J.S.; Cavanagh, P.R.; Caputo, G.M. Foot Problems in Diabetes: An Overview. Clin. Infect. Dis. 2004, 39 (Suppl. S2), S73–S82. [Google Scholar] [CrossRef] [PubMed]
  3. Yick, K.L.; Tse, C.Y. Textiles and other materials for orthopaedic footwear insoles. In Handbook of Footwear Design and Manufacture; Woodhead Publishing: Sawston, UK, 2013. [Google Scholar] [CrossRef]
  4. Sun, D.; McCullough, H. An Investigation into the Performance Viability of Recycled Polyester from Recycled Polyethylene Terephthalate (R-PET). J. Text. Sci. Fash. Technol. 2019, 2, 1–8. [Google Scholar] [CrossRef]
  5. Kumar, P.S.; Suganya, S. Test Methods and Identification of Recycled Polyester. In Recycled Polyester; Springer: Singapore, 2020. [Google Scholar] [CrossRef]
  6. Hegyi, A.; Vermeșan, H.; Lăzărescu, A.-V.; Petcu, C.; Bulacu, C. Thermal Insulation Mattresses Based on Textile Waste and Recycled Plastic Waste Fibres, Integrating Natural Fibres of Vegetable or Animal Origin. Materials 2022, 15, 1348. [Google Scholar] [CrossRef]
  7. Van Rensburg, M.L.; Nkomo, S.L.; Mkhize, N.M. Life cycle and End-of-Life management options in the footwear industry: A review. Waste Manag. Res. 2020, 38, 599–613. [Google Scholar] [CrossRef]
  8. Healy, A.; Dunning, D.; Chockalingam, N. Effect of insole material on plantar pressure. Footwear Sci. 2011, 3, S69–S70. [Google Scholar] [CrossRef]
  9. Gnanasundaram, S.; Ranganathan, M.; Das, B.N.; Mandal, A.B. Surface modified and medicated polyurethane materials capable of controlling microorganisms causing foot skin infection in athletes. Colloids Surf. B Biointerfaces 2013, 102, 139–145. [Google Scholar] [CrossRef]
  10. Morais, D.S.; Guedes, R.M.; Lopes, M.A. Antimicrobial approaches for textiles: From research to market. Materials 2016, 9, 498. [Google Scholar] [CrossRef]
  11. Tania, I.S.; Ali, M.; Arafat, M.T. Processing techniques of antimicrobial textiles. In Antimicrobial Textiles from Natural Resources; Woodhead Publishing: Sawston, UK, 2021; pp. 189–215. [Google Scholar] [CrossRef]
  12. Bratchenya, L.A.; Tolochkova, O.N.; Lebedeva, M.V. Creation of nonwoven shoe materials with improved hygienic properties. Fibre Chem. 2012, 43, 369–371. [Google Scholar] [CrossRef]
  13. Rajan, T.P.; Souza, L.D.; Ramakrishnan, G.; Zakriya, G.M. Comfort properties of functional warp-knitted polyester spacer fabrics for shoe insole applications. J. Ind. Text. 2014, 45, 1239–1251. [Google Scholar] [CrossRef]
  14. Fatkullina, R.R.; Yarullin, R.M.; Abutalipova, L.N.; Khadysov, B.A. Effect of Low-Temperature Plasma Treatment on The Properties of a Complex Wool-Containing Material. J. Phys. Conf. Ser. 2022, 2379, 012002. [Google Scholar] [CrossRef]
  15. Wang, Y.; Guo, H.; Yuan, T.; Ma, L.; Liu, N.; Sun, P. Friction-induced noise of vehicle wiper-windshield system: A review. Results Eng. 2023, 20, 101557. [Google Scholar] [CrossRef]
  16. Azam, F.; Ali, H.; Ahmad, F.; Rasheed, A.; Ahmad, S.; Ali, M.U.; Nawab, Y. A Fibrous Nonwoven Hydrogel Composite for Shoe Insole with Enhanced Mechanical and Comfort Properties. J. Polym. Environ. 2023, 32, 399–410. [Google Scholar] [CrossRef]
  17. Wang, S.; Hou, W.; Wei, L.; Dai, J.; Jia, H.; Liu, X.; Xu, B. Structure and properties of composite antibacterial PET fibers. J. Appl. Polym. Sci. 2009, 112, 1927–1932. [Google Scholar] [CrossRef]
  18. Smith, L.; Ali, M.; Agrissais, M.; Mulligan, S.; Koh, L.; Martin, N. A comparative life cycle assessment of dental restorative materials. Dent. Mater. 2022, 39, 13–24. [Google Scholar] [CrossRef]
  19. Messaoud, M.; Vaesken, A.; Aneja, A.; Schacher, L.; Adolphe, D.C.; Schaffhauser, J.-B.; Strehle, P. Physical and mechanical characterizations of recyclable insole product based on new 3D textile structure developed by the use of a patented vertical-lapping process. J. Ind. Text. 2013, 44, 497–512. [Google Scholar] [CrossRef]
  20. Sadeghi, B.; Marfavi, Y.; AliAkbari, R.; Kowsari, E.; Ajdari, F.B.; Ramakrishna, S. Recent Studies on Recycled PET Fibers: Production and Applications: A Review. Mater. Circ. Econ. 2021, 3, 4. [Google Scholar] [CrossRef]
  21. Cognard, P. Adhesives and Sealants: General Knowledge, Application of Techniques, New Curing Techniques. 2006. Available online: https://books.google.com.pk/books?hl=en&lr=&id=4UjQAEmjghUC&oi=fnd&pg=PP1&dq=21.%09P.+Cognard,+Adhesives+and+Sealants:+General+Knowledge,+Application+of+techniques,+new+curing+techniques.+2006.+&ots=O0HdE_8NhE&sig=cWFq68VhISizjqsvHZgaGTxEG5s&redir_esc=y#v=onepage&q=21.%09P.%20Cognard%2C%20Adhesives%20and%20Sealants%3A%20General%20Knowledge%2C%20Application%20of%20techniques%2C%20new%20curing%20techniques.%202006.&f=false (accessed on 16 October 2024).
  22. Afroz, S.; Azady, M.A.R.; Akter, Y.; Al Ragib, A.; Hasan, Z.; Rahaman, M.S.; Islam, J.M. Self-cleaning textiles: Structure, fabrication and applications. In Fundamentals of Natural Fibres and Textiles; Woodhead Publishing: Sawston, UK, 2021; pp. 557–597. [Google Scholar] [CrossRef]
  23. ISO 105-C03; Colour Fastness to Washing. International Organization for Standardization: Geneva, Switzerland, 1989.
  24. Hribernik, S.; Pivec, T.; Kurečič, M.; Kolar, M.; Stana-Kleinschek, K. Optimization of the sol-gel–assisted procedure for binding of silver onto modal fibres. In Proceedings of the 7th central European Conference 2012 Fibre-Grade Polymers, Portorose, Slovenia, 15–17 September 2012. [Google Scholar]
  25. Dabolina, I.; Abu-Rous, M.; Lapkovska, E. A Fast Training Method of a Fabric Hand-Feel Panel under Industry Conditions, and Its Conformity with Other Human and Instrumental Approaches. Appl. Sci. 2022, 12, 12344. [Google Scholar] [CrossRef]
  26. AATCC-202; Relative Hand Value of Textiles: Instrumental. American Association of Textile Chemists and Colorists: Research Triangle Park, NC, USA, 2012.
  27. Yim; Ka, Y. Correlation between Fabric Specifications and Fabric Hand Characteristics for Warp Knitted Fabrics. Master’s Thesis, Hong Kong Polytechnic University, Hong Kong, China, 2016.
  28. McQueen, R.; Batcheller, J.; Mah, T.; Hooper, P. Development of a protocol to assess fabric suitability for testing liquid moisture transport properties. J. Text. Inst. 2013, 104, 900–905. [Google Scholar] [CrossRef]
  29. AATCC TM 195; Liquid Moisture Management Properties of Textile Fabrics. American Association of Textile Chemists and Colorists: Research Triangle Park, NC, USA, 2009.
  30. Öner, E.; Atasağun, H.G.; Okur, A.; Beden, A.R.; Durur, G. Evaluation of moisture management properties on knitted fabrics. J. Text. Inst. 2013, 104, 699–707. [Google Scholar] [CrossRef]
  31. AATCC147; Antibacterial Activity of Textile Materials: Parallel Streak. American Association of Textile Chemists and Colorists: Research Triangle Park, NC, USA, 1976.
  32. Yıldırım, F.F.; Avinc, O.; Yavas, A.; Sevgisunar, G. Sustainable Antifungal and Antibacterial Textiles Using Natural Resources. In Sustainability in the Textile and Apparel Industries; Springer: Cham, Switzerland, 2020. [Google Scholar] [CrossRef]
  33. AATCC 100; Antibacterial Finishes on Textile Materials: Assessment. American Association of Textile Chemists and Colorists: Research Triangle Park, NC, USA, 1961.
  34. Aksit, A.; Camlibel, N.O.; Zeren, E.T.; Kutlu, B. Development of antibacterial fabrics by treatment with Ag-doped TiO2 nanoparticles. J. Text. Inst. 2017, 108, 2046–2056. [Google Scholar] [CrossRef]
  35. ISO13934-1; Textiles—Tensile Properties of Fabrics—Part 1: Determination of Maximum Force and Elongation at Maximum Force Using the Strip Method. International Organization for Standardization: Geneva, Switzerland, 2013.
  36. von Maubeuge, K.P.; Ehrenberg, H. Comparison of peel bond and shear tensile test methods for needlepunched geosynthetic clay liners. Geotext. Geomembr. 2000, 18, 203–214. [Google Scholar] [CrossRef]
  37. ISO12947; Determination of the abrasion resistance of fabrics by the Martindale method. International Organization for Standardization: Geneva, Switzerland, 1998.
  38. Kara, S.; Yesilpinar, S.; Aksit, A. Permeability properties and abrasion resistance of coated polypropylene fabrics. Fibres Text 2018, 25, 40–47. [Google Scholar]
  39. Wang, W.Y.; Yim, H.H.L.; Kan, C.W.; Chanuntawaree, S.; Chonsakorn, S.; Udon, S.; Peangsai, M.; Mongkholrattanasit, R. A study of relative hand value of quick dry inner wear. Key Eng. Mater. 2020, 831, 171–176. [Google Scholar] [CrossRef]
  40. Qutaba, S.; Azhari, A.; Asmelash, M.; Haider, M.; Lusi, N. Development of fiber metal laminate composite with different glass fiber GSM. Mater. Today Proc. 2023, 1. [Google Scholar] [CrossRef]
  41. Li, J.; He, J.; Huang, Y. Role of alginate in antibacterial finishing of textiles. Int. J. Biol. Macromol. 2017, 94, 466–473. [Google Scholar] [CrossRef]
  42. Patil, S.; Mahapatra, A.; Gotmare, V.D.; Patil, P.G.; Bharimalla, A.K.; Arputharaj, A. Effect of different mercerization techniques on tactile comfort of cotton fabric. Indian J. Fibre Text. Res. 2019, 44, 217–222. [Google Scholar]
  43. Hasan, Z.; Asif, A.K.M.A.H.; Razzaque, A.; Hasan, R.; Sur, S.; Faruque, O. An Experimental Investigation of Different Washing Processes on Various Properties of Stretch Denim Fabric. J. Mater. Sci. Chem. Eng. 2021, 9, 1–15. [Google Scholar] [CrossRef]
  44. Venkataraman, D.; Shabani, E.; Park, J.H. Advancement of Nonwoven Fabrics in Personal Protective Equipment. Materials 2023, 16, 3964. [Google Scholar] [CrossRef]
  45. Vick, C.B.; Okkonen, E.A. Strength and durability of one-part polyurethane adhesive bonds to wood. For. Prod. J. 1998, 48, 71–76. [Google Scholar]
  46. Deǧirmenci, Z.; Çelik, N. The effects of selected improving methods on wrinkle resistance of warp knitted and laminated car seat cover fabrics. J. Ind. Text. 2013, 44, 245–256. [Google Scholar] [CrossRef]
  47. Zelova, K.; Glombikova, V. The effect of cyclic wrinkling on the durability of waterproof breathable functional outdoor materials for sportswear. J. Text. Inst. 2024, 1–14. [Google Scholar] [CrossRef]
  48. Soni, S.; Babel, R.; Saxena, S.; Arputharaj, A.; Raja, A.; Srivastava, M. Enhancing Cotton Fabric Softness and Wrinkle Resistance through Optimized Formulation of Nano ZnO and Benzalkonium Chloride-Enriched Rinse-Cycle Softener. Ecol. Environ. Conserv. 2024, 30, S431–S438. [Google Scholar] [CrossRef]
  49. Uyanık, S. A Comparative Study on Moisture Management Properties of Cotton/Elastane Plain Knit Fabrics Having Different Elastane Ratio. Fibers Polym. 2022, 23, 2316–2329. [Google Scholar] [CrossRef]
  50. Dalhat, M. Improving hydrophobicity of asphalt surfaces using pulverized recycled polyethylene terephthalate: Towards efficient roofing/waterproofing. Mater. Today Commun. 2024, 39, 109166. [Google Scholar] [CrossRef]
  51. Pinho, E.; Magalhães, L.; Henriques, M.; Oliveira, R. Antimicrobial activity assessment of textiles: Standard methods comparison. Ann. Microbiol. 2010, 61, 493–498. [Google Scholar] [CrossRef]
  52. Sivaramakrishnan, C.N. Antimicrobial finishes. Colourage 2007, 54, 3–4. [Google Scholar]
  53. Luo, Y.; Wang, C.; Wang, L.; Ding, X.; Wu, X. Effect of a novel press washing mode on appearance and mechanical properties of silk garments: Comparison with hand washing and front-loading machine washing. J. Text. Inst. 2022, 114, 959–973. [Google Scholar] [CrossRef]
  54. Xu, T.; Goldthorpe, I.A. Mitigating the Impact of Thermoplastic Polyurethane Films on the Performance of Electronic Textiles. In Proceedings of the 2022 IEEE International Flexible Electronics Technology Conference (IFETC), Qingdao, China, 21–24 August 2022; pp. 1–2. [Google Scholar]
  55. Chen, N.; Silberstein, M.N. A micromechanics-based damage model for non-woven fiber networks. Int. J. Solids Struct. 2018, 160, 18–31. [Google Scholar] [CrossRef]
  56. Bin Ying, W.; Yu, Z.; Kim, D.H.; Lee, K.J.; Hu, H.; Liu, Y.; Kong, Z.; Wang, K.; Shang, J.; Zhang, R.; et al. Waterproof, Highly Tough, and Fast Self-Healing Polyurethane for Durable Electronic Skin. ACS Appl. Mater. Interfaces 2020, 12, 11072–11083. [Google Scholar] [CrossRef]
Figure 1. Development of sustainable shoe insole, starting with rPET fibers, made into a non-woven web, PU lamination for durability, and treated with a silver-based antibacterial finish to make the final insole.
Figure 1. Development of sustainable shoe insole, starting with rPET fibers, made into a non-woven web, PU lamination for durability, and treated with a silver-based antibacterial finish to make the final insole.
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Figure 2. Schematic representation of laminated non-woven insole. It illustrates the placement and dual-layered structure of the insole. The insole design combines sustainability, durability, and antibacterial protection for optimal foot hygiene and comfort.
Figure 2. Schematic representation of laminated non-woven insole. It illustrates the placement and dual-layered structure of the insole. The insole design combines sustainability, durability, and antibacterial protection for optimal foot hygiene and comfort.
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Figure 3. The RHV analysis of 27 samples, in which (A) illustrates the resilience, (B) shows the softness, (C) depicts smoothness, and (D) demonstrates the wrinkle recovery rate.
Figure 3. The RHV analysis of 27 samples, in which (A) illustrates the resilience, (B) shows the softness, (C) depicts smoothness, and (D) demonstrates the wrinkle recovery rate.
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Figure 4. The antibacterial efficacy of fabric samples with a GSM of 300. Samples with varying finish concentrations and washing cycles were placed on an agar plate, with no underneath bacterial growth visible across any of the samples.
Figure 4. The antibacterial efficacy of fabric samples with a GSM of 300. Samples with varying finish concentrations and washing cycles were placed on an agar plate, with no underneath bacterial growth visible across any of the samples.
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Figure 5. Antibacterial reduction percentages across the selected samples with various finish concentrations and washing cycles (n = 3).
Figure 5. Antibacterial reduction percentages across the selected samples with various finish concentrations and washing cycles (n = 3).
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Figure 6. This figure depicts the mechanical performance of the samples under tensile stress, demonstrating a variation in tensile strength with different GSM, while elongation remains relatively consistent across all samples.
Figure 6. This figure depicts the mechanical performance of the samples under tensile stress, demonstrating a variation in tensile strength with different GSM, while elongation remains relatively consistent across all samples.
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Figure 7. This figure illustrates the abrasion resistance on both sides of the insole, where (A) displays the recycled polyester non-woven side with no visible damage after 20,000 abrasion cycles, while (B) shows the polymer laminated side, which remains undamaged after 50,000 abrasion cycles.
Figure 7. This figure illustrates the abrasion resistance on both sides of the insole, where (A) displays the recycled polyester non-woven side with no visible damage after 20,000 abrasion cycles, while (B) shows the polymer laminated side, which remains undamaged after 50,000 abrasion cycles.
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Table 1. Factors and their respective levels.
Table 1. Factors and their respective levels.
FactorsLevels
GSM of Non-woven Fabric100200300
Finish Concentration
(% on the weight of fabric)
51015
Washing0510
Table 2. Design of experiment.
Table 2. Design of experiment.
Run OrderSamplesGSMAntibacterial FinishWashing
1F20015%0 cycles
2G3005%5 cycles
3R30015%5 cycles
4Y3005%10 cycles
5X20015%10 cycles
6B10010%0 cycles
7E20010%0 cycles
8S1005%10 cycles
9K10010%5 cycles
10C10015%0 cycles
11YZ30015%10 cycles
12L10015%5 cycles
13W20010%10 cycles
14U10015%10 cycles
15G3005%0 cycles
16Z30010%10 cycles
17H30010%0 cycles
18I30015%0 cycles
19T10010%10 cycles
20D2005%0 cycles
21V2005%10 cycles
22N20010%5 cycles
23J1005%5 cycles
24O20015%5 cycles
25Q30010%5 cycles
26M2005%5 cycles
27A1005%0 cycles
Table 3. Antibacterial efficacy of non-woven samples treated with Silvadur® finish.
Table 3. Antibacterial efficacy of non-woven samples treated with Silvadur® finish.
SamplesAntibacterial FinishWashing CyclesBacterial Growth in the Sample Contact AreaClear Zone Inhibition
(mm)
P5%5No0.00
Y5%10No0.00
YZ15%10No0.00
G5%0No0.00
I15%0No0.00
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Naseem, Z.; Zainab, I.; Batool, S.R.; Uzun, M.; Ioanid, A.; Nazeer, M.A. An Innovative Approach to Enhance the Durability and Sustainability of Shoe Insoles. Sustainability 2024, 16, 9195. https://doi.org/10.3390/su16219195

AMA Style

Naseem Z, Zainab I, Batool SR, Uzun M, Ioanid A, Nazeer MA. An Innovative Approach to Enhance the Durability and Sustainability of Shoe Insoles. Sustainability. 2024; 16(21):9195. https://doi.org/10.3390/su16219195

Chicago/Turabian Style

Naseem, Zohra, Iqra Zainab, Syeda Rubab Batool, Muhammet Uzun, Alexandra Ioanid, and Muhammad Anwaar Nazeer. 2024. "An Innovative Approach to Enhance the Durability and Sustainability of Shoe Insoles" Sustainability 16, no. 21: 9195. https://doi.org/10.3390/su16219195

APA Style

Naseem, Z., Zainab, I., Batool, S. R., Uzun, M., Ioanid, A., & Nazeer, M. A. (2024). An Innovative Approach to Enhance the Durability and Sustainability of Shoe Insoles. Sustainability, 16(21), 9195. https://doi.org/10.3390/su16219195

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