Solketal Production via Solvent-Free Acetalization of Glycerol over Triphosphonic-Lanthanide Coordination Polymers
Abstract
:1. Introduction
2. Results and Discussion
2.1. Catalysts Synthesis and Characterization
2.2. Reaction of Glycerol with Acetone
2.3. Catalyst Stability
3. Materials and Methods
3.1. Reagents
3.2. General Instrumentation
3.3. Catalyst Synthesis
3.4. Catalytic Tests
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Entry | Catalyst | Gly/Acet | Temp. (°C) | Conv. (%) | Selectivity (%) | |
---|---|---|---|---|---|---|
1,3-Dioxolane | 1,3-Dioxane | |||||
1 | UAV-63 | 1/10 | 40 | 22 | 70 | 30 |
2 | UAV-63 | 1/10 | 55 | 84 | 96 | 4 |
3 | UAV-63 | 1/4 | 55 | 64 | 96 | 4 |
4 | UAV-20 | 1/10 | 40 | 8 | 72 | 28 |
5 | UAV-20 | 1/10 | 55 | 56 | 90 | 10 |
6 | UAV-20 | 1/4 | 55 | 44 | 93 | 7 |
Entry | Catalyst | T | Gly/Ace | Cat/Gly | t | Conv. | Selectivity (%) | Ref. | |
---|---|---|---|---|---|---|---|---|---|
(Solvent) | (°C) | (%, w/w) | (h) | (%) | | | |||
1 | UAV-63 | 55 | 1:10 | 5 | 6 | 84 | 96 | 4 | This work |
2 | UAV-20 | 55 | 1:10 | 5 | 6 | 56 | 82 | 18 | This work |
3 | UiO-66(Zr) MOF | RT | 1:4 | 10 | 1 | 2 | 73 | 27 | [21] |
4 | UiO-66(Ce) MOF | RT | 1:4 | 10 | 1 | 70 | 90 | 10 | [21] |
5 | UiO-66(Hf) MOF | RT | 1:4 | 10 | 1 | 95 | 97 | 3 | [21] |
6 | MIL-100(V) (CH3CN) | 70 | 1:4.7 | 20 | 1.25 | 85.4 | 97.7 | 2.3 | [22] |
7 | MIL-100(V) (CH3CN) | 25 | 1:4.1 | 2.5 | 1.5 | 83 | 98 | n.m. | [22] |
9 | MIL-47(V) (CH3CN) | 70 | 1:4.7 | 20 | 1.25 | 75.9 | 97.5 | 2.5 | [22] |
10 | MIL-47(V) (CH3CN) | 25 | 1:4.1 | 2.5 | 1.5 | 73 | 87 | n.m. | [22] |
11 | MIL-53(Al:V) (25:75) (CH3CN) | 70 | 1:4.7 | 20 | 1.25 | 57.7 | 95.1 | 4.9 | [22] |
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Santos-Vieira, I.C.M.S.; Mendes, R.F.; Almeida Paz, F.A.; Rocha, J.; Simões, M.M.Q. Solketal Production via Solvent-Free Acetalization of Glycerol over Triphosphonic-Lanthanide Coordination Polymers. Catalysts 2021, 11, 598. https://doi.org/10.3390/catal11050598
Santos-Vieira ICMS, Mendes RF, Almeida Paz FA, Rocha J, Simões MMQ. Solketal Production via Solvent-Free Acetalization of Glycerol over Triphosphonic-Lanthanide Coordination Polymers. Catalysts. 2021; 11(5):598. https://doi.org/10.3390/catal11050598
Chicago/Turabian StyleSantos-Vieira, Isabel C.M.S., Ricardo F. Mendes, Filipe A. Almeida Paz, João Rocha, and Mário M. Q. Simões. 2021. "Solketal Production via Solvent-Free Acetalization of Glycerol over Triphosphonic-Lanthanide Coordination Polymers" Catalysts 11, no. 5: 598. https://doi.org/10.3390/catal11050598