Rapid and Local Self-Healing Ability of Polyurethane Nanocomposites Using Photothermal Polydopamine-Coated Graphene Oxide Triggered by Near-Infrared Laser
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of PDA–rGO
2.3. Preparation of PDA–rGO/PU Nanocomposites
2.4. Characterization
3. Results and Discussion
3.1. Synthesis and Characterization of PDA–rGO
3.2. Preparation and Characterization of PDA–rGO/PU Nanocomposites
3.3. Photothermal and Self-Healing Properties of the PDA–rGO/PU Nanocomposites
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Sample Codes | Tg (°C) | Tm (°C) | Breaking Stress (MPa) | Elongation at Break (%) | Young’s Modulus (MPa) | Toughness (J/m2) |
---|---|---|---|---|---|---|
PU | −2.1 | 44.6 | 18.1 ± 0.65 | 582.4 ± 41.2 | 8.44 ± 0.86 | 5672.3 ± 129.1 |
1 wt% GO/PU | 1.3 | 46.7 | 16.4 ± 0.87 | 433.8 ± 15.7 | 10.06 ± 2.17 | 3983.4 ± 99.8 |
0.1 wt% PDA–rGO/PU | −1.6 | 45.1 | 17.7 ± 0.28 | 555.7 ± 25.6 | 6.84 ± 0.29 | 5357.5± 107.3 |
0.5 wt% PDA–rGO/PU | −0.8 | 45.8 | 18.6 ± 0.86 | 511.7 ± 17.3 | 6.9 ± 1.67 | 4979.3 ± 101.6 |
1 wt% PDA–rGO/PU | −0.1 | 46.0 | 18.9 ± 0.24 | 500.0 ± 30.4 | 8.3 ± 1.17 | 5000.9 ± 113.9 |
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Ha, Y.-M.; Kim, Y.N.; Jung, Y.C. Rapid and Local Self-Healing Ability of Polyurethane Nanocomposites Using Photothermal Polydopamine-Coated Graphene Oxide Triggered by Near-Infrared Laser. Polymers 2021, 13, 1274. https://doi.org/10.3390/polym13081274
Ha Y-M, Kim YN, Jung YC. Rapid and Local Self-Healing Ability of Polyurethane Nanocomposites Using Photothermal Polydopamine-Coated Graphene Oxide Triggered by Near-Infrared Laser. Polymers. 2021; 13(8):1274. https://doi.org/10.3390/polym13081274
Chicago/Turabian StyleHa, Yu-Mi, Young Nam Kim, and Yong Chae Jung. 2021. "Rapid and Local Self-Healing Ability of Polyurethane Nanocomposites Using Photothermal Polydopamine-Coated Graphene Oxide Triggered by Near-Infrared Laser" Polymers 13, no. 8: 1274. https://doi.org/10.3390/polym13081274