Hybrid Macrocyclic Polymers: Self-Assembly Containing Cucurbit[m]uril-pillar[n]arene
Abstract
:1. Introduction
2. The Competition and Cooperation between CB[m] and Pillar[n]arene as the Host
3. The Preparation of Mechanically Interlocked Molecules Containing CB[m] and Pillar[n]arene
4. The Preparation of Supramolecular Polymer containing CB[m] and pillar[n]arene
5. Overview and Outlook
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
CB[m] | Cucurbit[m]uril |
Ka | Associate constants |
LCST | Lower critical solution temperature |
MIM | Mechanically interlocked molecules |
Tcloud | Clouding point |
References
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CB[m] | Pillar[n]arene | Relationship | Guests | Ref |
---|---|---|---|---|
CB[7] | Pillar[5]arene P2 | Competition of hosts (Ka of P2⸧G2 ~103 M−1) vs. (Ka of CB[7]⸧G2 ~105 M−1) | G2 | [79] |
CB[10] | Pillar[5]arene P4 | Forming hybrid macrocyclic system CB[10]•P4 presenting integrated Ka towards G4 and G6 as ~106 and ~105 M−1 | G4-G6 | [84] |
CB[m] | Pillar[n]arene | Self-Assembly | Guests as Building Blocks | Ref |
---|---|---|---|---|
CB[6] | Pillar[5]arene P5 | n]Rotaxane CP1-CP4 | G7-G11 | [89] |
CB[6] | Pillar[6]arene P6 | [n]Rotaxane CP5-CP7 | G8, G9 and G12 | [90] |
CB[8] | Pillar[6]arene P7 | Supramolecular polymer P7⸧G13⊂CB[8] | G13 | [93] |
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Liu, Z.; Li, Z.; Li, B.; Zhou, L.; Zhang, H.; Han, J. Hybrid Macrocyclic Polymers: Self-Assembly Containing Cucurbit[m]uril-pillar[n]arene. Polymers 2022, 14, 1777. https://doi.org/10.3390/polym14091777
Liu Z, Li Z, Li B, Zhou L, Zhang H, Han J. Hybrid Macrocyclic Polymers: Self-Assembly Containing Cucurbit[m]uril-pillar[n]arene. Polymers. 2022; 14(9):1777. https://doi.org/10.3390/polym14091777
Chicago/Turabian StyleLiu, Zhaona, Zhizheng Li, Bing Li, Le Zhou, Huacheng Zhang, and Jie Han. 2022. "Hybrid Macrocyclic Polymers: Self-Assembly Containing Cucurbit[m]uril-pillar[n]arene" Polymers 14, no. 9: 1777. https://doi.org/10.3390/polym14091777