Investigation into the Internal Factors for the Catalytic Oxidation of Cyclohexane by Zr(IV)-Based Metal-Organic Frameworks
Abstract
:1. Introduction
2. Experimental Section
2.1. Chemicals
2.2. Catalyst Syntheses
2.3. Characterizations
2.4. Catalytic Test
2.5. Grand Canonical Monte Carlo (GCMC) Simulations
2.6. Free-Radical Capture Methods
3. Results and Discussion
3.1. Characterization of Catalysts
3.2. Investigation of the Effect of Different Linkage Numbers
3.3. Investigation of the Effect of Solvent and Temperature
3.4. Free-Radical Capture Experiments
3.5. Catalytic Reaction Mechanism
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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Catalyst | Connected | Con. | Sel. | TON |
---|---|---|---|---|
MOF-808 | 6 | 8.30% | 98% | 39.9 |
MOF-802 | 10 | 0.53% | 83% | 3.27 |
UiO-66 | 12 | 0.36% | 76% | 2.24 |
Temperature | Con. | Sel. | TON | |
---|---|---|---|---|
A | K | |||
60 °C | 0.47% | 38.93% | 36.87% | 2.93 |
65 °C | 5.08% | 41.65% | 39.57% | 31.59 |
70 °C | 8.24% | 31.06% | 32.08% | 39.28 |
75 °C | 3.68% | 29.13% | 44.46% | 22.74 |
80 °C | 0.58% | 20.54% | 61.56% | 3.53 |
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Wang, K.; Tao, Z.-P.; Chu, J.-Q.; Wang, S.-M.; Han, Z.-B. Investigation into the Internal Factors for the Catalytic Oxidation of Cyclohexane by Zr(IV)-Based Metal-Organic Frameworks. Polymers 2024, 16, 3114. https://doi.org/10.3390/polym16223114
Wang K, Tao Z-P, Chu J-Q, Wang S-M, Han Z-B. Investigation into the Internal Factors for the Catalytic Oxidation of Cyclohexane by Zr(IV)-Based Metal-Organic Frameworks. Polymers. 2024; 16(22):3114. https://doi.org/10.3390/polym16223114
Chicago/Turabian StyleWang, Kechao, Zhi-Peng Tao, Jia-Qi Chu, Shi-Ming Wang, and Zheng-Bo Han. 2024. "Investigation into the Internal Factors for the Catalytic Oxidation of Cyclohexane by Zr(IV)-Based Metal-Organic Frameworks" Polymers 16, no. 22: 3114. https://doi.org/10.3390/polym16223114