3.1. Spring Depletion Coefficient Due to the Earthquake
The case illustrated in
Figure 2a involves two depletion coefficients. This is reflected in the final resulting discharge curve: the one representing the aquifer’s discharge as if there had been no seismic effect, and the exponential curve due to the earthquake (α
1 is the recession coefficient of the discharge curve before the seismic event, and α
2 is the depletion coefficient due to the earthquake). These two depletion coefficients have been observed in actual cases in both well levels and spring discharge hydrographs, e.g., for the 1989 Loma Prieta earthquake [
6], for the 1999 Chi-Chi earthquake [
16,
18,
19], and for the Mw8.8 Maule 2010 earthquake in Chile [
20].
Figure 3 depicts such a response, which, although it seems the most logical, does not occur in all the cases consulted.
A sketch of this hydrograph, neglecting aquifer inertias, is the composite recession curve shown in
Figure 3. In this case, in a semi-logarithmic diagram, the hydrograph would consist of two straight lines, and the expression for the depletion curve would be:
In this expression, stands for the initial discharge at the beginning of the spring or stream depletion curve before the earthquake, is the pre-earthquake depletion coefficient of the spring discharge curve, is the increase in discharge mobilized by the earthquake, and is the coefficient of its depletion curve. However, it might also occur that only an increase in discharge could be observed, but with the same depletion curve characteristic of the spring before the earthquake ().
Some springs have revealed that after the earthquake-induced discharge increase, the aquifer depletes with its initial, interseismic α value, behaving hydraulically as usual. This fact has been documented for the 1989 Mw6.9 Loma Prieta earthquake [
21] and the 1999 Chi-Chi earthquake [
18,
19,
22]. Hence, Wang and Manga [
11,
12] deduced that the increased permeability mechanism could not explain the increased spring discharge due to earthquakes, given that the depletion coefficient of a spring before and after an earthquake does not vary.
However, this does not seem to be the case, as a sensitivity analysis of the diverse variables involved in this coefficient, according to Equation (2), seems to show that significant increases in permeability involve imperceptible variations in the depletion coefficient. Thus, according to Equation (2), of the four variables influencing the depletion coefficient (, and ), we can consider and as fixed for each specific aquifer. depends on the aquifer type (unconfined, semi-confined, or confined), and its variation concerning is much smaller according to Darcy’s law. In other words, small increments of imply significant increases in . Additionally, appears multiplied by two. This analysis only seeks to envisage the influence of on , rather than performing a sensitivity analysis of . The reason is to demonstrate that a large variation in , being the factor that furthest affects the depletion coefficient, hardly varies.
For example, in the Vozmediano Spring (Spain), with an average discharge of 1100 L/s, if the permeability of the entire aquifer varies from
= 1.1 m/day to
= 1.2 m/day, the depletion coefficient would change from
to
[
22,
23,
24,
25,
26]. We would need to increase an order of magnitude (
= 2 m/day) for the coefficient to vary relatively significantly (
). We can then verify that significant changes in aquifer permeability are masked within the margins of measurement errors of spring discharge gauging. The changes in slope on the recession lines are so small that they are imperceptible at the hydrograph drawing level.
This does not imply that there cannot be a very significant increase in permeability occurring at great depths, near the rupture zone, but its influence on the average permeability of the entire aquifer will be small if the aquifer draining the spring is large (parameter in Equation (2)). However, if we restrict ourselves to faults, we do believe that vertical permeability can be substantially improved over geological timescales.
The ratio between the size of the aquifer and that of the fault ruptured by the earthquake is a relevant factor. In an aquifer with tens or hundreds of km2, the size of a crossing fault can be small. Even if the entire fault slips, it has little impact on the average permeability. However, if the fault itself embodies the aquifer and is surrounded by an impermeable ground, its permeability variation can become high. When faults constitute the aquifers, spring discharges are rather low. Large flow springs are usually related to massive aquifers entailing large recharge surface, although the faults associated with them become the outlet conduits. Mathematical models are valuable tools to quantify these responses in each case; otherwise, it is elusive beforehand.
The geological mechanisms that can increase vertical permeability would not only be those produced by the hydraulic fracture of the at-depth earthquake but also the increase in the fault slip, caused by friction failure between the contacting blocks, and the increase in the fault opening, cleaning the fault plane, among others.
3.2. Calculation of Post-Seismic Excess Discharge and the Mobilized Volume of Water Due to Earthquakes
Not all water mobilized by an earthquake can be quantified as post-seismic excess discharge, as it does not always come to the surface. This occurs when piezometric levels only rise but later return to lower levels and reach equilibrium. Therefore, the estimation of excess discharge measured in springs and streams will be a minimum of the water mobilized by earthquakes.
In the case of new springs and streams (see
Figure 2c), after the initial abrupt increase, there will be a descending branch in the hydrograph with slope
, as in the previous case, until the new spring dries up at
, after which only the piezometric level descent due to depressurization or downward flow will operate.
In case 2-D, only levels are available, and the effect operating in the piezometric level descent is the downward flow, with the manifestation of a single descending branch with slope . If tools were available to convert elevations into discharge (mathematical models, for example), discharge hydrographs could be obtained, and excess volumes due to earthquakes could be calculated.
3.2.1. Estimation of the Volume Mobilized by an Earthquake Using the Hydrograph of a Spring
The volume of water discharged by the earthquake (
) is the increase in hydrodynamic volume of the aquifer, which, from the hydrograph, can be calculated as the difference between the volume discharged by the spring after the earthquake and what it would have discharged if the earthquake had not occurred:
where
is the spring discharge at the beginning of the recession and
is the flow induced by the earthquake. A simple way to estimate this volume is
Expression (7) can be easily related to the colored region of
Figure 3, i.e.,
. The previous graph corresponds only to the case in which the spring was flowing at the time of the earthquake occurrence. The possibilities with their respective graphs (see
Figure 2) are as follows.
3.2.2. Analysis of Spring Hydrographs
Regardless of other methods for calculating recharge using piezometric variations or mathematical models, we will focus here on those that utilize the spring hydrograph. We will consider recharge as the excess discharge draining through a spring due to an earthquake. These methods are based on the analysis of hydrograph peaks: the surges that occur as a result of upward flow due to an earthquake and their subsequent decline when the seismic activity has ceased. In addition to the method proposed by Wang and Manga [
12,
13], we present below, as an example, the recession curve shifting method. Other similar methods can be found in Sanz Pérez [
23,
24,
25,
27]. The goal is not to exhaust the topic but to adapt and apply hydrogeological theory to earthquake scenarios to demonstrate the possibilities of these estimations.
3.2.3. The Recession Curve Shifting Method
This method is based on raising the recession curve of the discharge ensuing from recharge induced by an earthquake from below. It includes the possibility of analyzing the inflow injections from various events, such as aftershocks, although the first event causes the most significant surge in the spring. If α is the depletion coefficient, which has been determined beforehand, it assumes that at the so-called “critical time” () from the end of the recharge, the spring acquires its base flow.
For each hydrograph peak, with semi-logarithmic representation (see
Figure 1), estimate on the graph the descent curve of the peak until it becomes parallel to the recession line or, in other words, with slope α, at the “critical time.” At this moment, measure the flows
from the recession line of the peak and
from the previous recession.
Formulations by Glover [
28] and Rorabaught [
29], automated later by Rutledge and Daniel [
30], show that the total potential groundwater recharge at a critical time after the flow peak is approximately equal to half the recharged water volume into the system. Therefore, for peaks 1 and 2 in
Figure 4, the following recharges
and
would be obtained:
3.2.4. Rainfall–Runoff Mathematical Models
For the mathematical description of recharge and discharge transfer in the simulation of spring hydrographs and well levels, mainly aggregated models (uni- and multicellular models) have been employed, some of which are also called black-box models. A variety of authors have explained some of such models, e.g., [
23,
30,
31,
32].
A simple and effective model is the single-cell model, which considers the aquifer as a linear reservoir in which the volume of stored water above the outlet level relates to the discharge through a depletion coefficient, as expressed in Equation (4). Otherwise, multicellular models are suitable when the spring has several depletion coefficients.
In the encompassed multicellular models, for example, modeling is expressed exclusively under drained flow conditions, volumes, and recharges in each decomposition cell. Therefore, knowledge of piezometric level series is not required, as they do not intervene in the calculation. The quantification of evapotranspiration is not required, nor is the aquifer geometry and conditions at the borders; only the total surface of the aquifer and the precipitation and natural flow gauge series of the spring are necessary.
Both unicellular and multicellular models can be used to analyze the effect of pumping or recharge induced by an earthquake. These models are more suitable than finite difference or finite element ones for heterogeneous media. The reason is that these latter models require knowing the parameters of the aquifer distributed over its spatial domain, which is very difficult. On the contrary, all these aggregate or black-box models explained below build exclusively on the analysis of the spring hydrograph. These aggregate models suggest that the interpretation of attributing the slopes these pluricellular models may not be as complete, but they can simulate the hydrograph very well. Another question is whether we can draw direct geological conclusions. For example, different depletion coefficients with different slopes are not exclusively due to differences in hydraulic conductivity.
Some other valuable models, such as SIMERO [
23,
25,
27] or CREC [
29,
31], are very appropriate for the research at hand. These models consider the aquifer as divided into three deposits distributed in series and representing three successive water stages, from precipitation to its outlet to the spring. In the first, a conventional hydraulic balance is operated, from which the water comes out to the unsaturated zone (second deposit) and saturated (third deposit), where the flow undergoes a delay and phase shift. SIMERO can assume a linear and invariant system, by specifying such condition in the last two layers, and therefore, the circulation of water is expressed by a convolution integral. In the CREC model, the deposit representing the unsaturated zone is responsible for the nonlinear drainage of the aquifer and the transfer of flow to the saturated zone, and in the latter, linear drainage occurs. From these models, flows, pressures, and volumes can be obtained.
3.2.5. Application to the Case of Seismic Alteration of a Spring
These precipitation–runoff models could simulate not only flow variations but also pressure variations, i.e., piezometric level variations. For this, a reasonable assumption is made, such as that recharge comes from bottom to top, passing directly to the saturated zone. In this way, the flow does not undergo the reduction in balance in the soil, such as rain-infiltrated water, nor the delay and phase shift of the following deposits of mathematical models. It is as if we recharged the aquifer by injecting water through a well into the saturated zone.
As an example, we present the simulation of an earthquake affecting the Fuentetoba Spring (Soria, Spain) [
32,
33,
34,
35]. This spring drains a karstic aquifer naturally, without exploitation wells, and the recharge comes only from rainfall. It has an average flow of 200 L/s, but a very variable regime, so that it has peaks of up to 7000 L/s, although it can also dry up. Its hydrograph has been simulated using the CREC model for 20 years, so it is very well calibrated. The first simulation of an earthquake involved injecting a recharge directly into the saturated zone during a rainless period and a dry spring, albeit with the water table at the natural drain outlet level of the spring. It could be assimilated somehow to the appearance of new springs due to the effect of an earthquake. The recharged flow was practically instantaneous (31 July 2011), and with a very large amount (100 mm spread throughout the aquifer). As shown in
Figure 5, the reaction was immediate, with a vertical ascending branch in the hydrograph, and a spring-depletion-coefficient dependent recession that lasted more than a month, until it dried up again.
In the case of a spring that is active during seismic-induced recharge,
Figure 6 presents the results of various simulations for the same Fuentetoba Spring. Different recharge values are considered for hypothetical earthquakes without aftershocks occurring on 30 October 2010. As expected, we observe the immediate effect of seismic recharge in all cases, and later, the aquifer emptying law is reflected according to its α, which prevails for seismic recharges with higher values. The separation in the hydrograph of the two effects, rainfall recharge and seismic recharge, is very clear. We highlight that the use of these models enables this differentiation even during intense rainfall events that could obscure a co-seismic increase. We also observe how the seismic effect persists for more than 15 days in all cases. The persistence time increases with seismic recharge, but it does not influence as much. It is assumed that aftershocks contribute to the persistence time.
The last simulation assumed a 200 mm recharge, corresponding to the main earthquake, along with aftershocks 5 and 10 days later with 50 mm and 25 mm, respectively.
Figure 7 depicts how the persistence time remains significantly longer, and the slopes vary based on the juxtaposition of events.
3.2.6. Effects of Seismic-Induced Recharge Actions Using Analytical Solutions Derived from Precipitation–Runoff Mathematical Models
After a spring has been previously simulated using a rainfall–runoff model, including its iterative formulas and once discretized, there are analytical solutions to calculate the effects on its flow from deep seismic-origin recharges. Pressure buildups (piezometric levels) can also be calculated. In these cases, the aquifer is considered homogeneous, and it is assumed that deep seismic-origin recharges are instantaneous and uniformly distributed along the aquifer or around its center of gravity. These induced actions consist of seismic-origin recharges, as mentioned (similar to artificial recharges in conventional hydrogeology), or effects of seismic pumping on the aquifer that lead to the decrease or drying up of springs (similar to groundwater pumping through wells in conventional hydrogeology). The mathematical treatment is analogous in both cases, but the sign of these recharges is changed.
For one of the most well-known mathematical models (SIMERO), these solutions are given in Sanz Pérez [
23,
25,
27] and adapted to the case of fluid flow or pressure from an earthquake, summarized in the following iterative formula, where
is the actual contribution of the spring, considering the effect of seismic recharges up to period
.
where
is the flow that the spring would have if there were no seismic-origin recharges in period
or the preceding ones, and
is the difference between the two aforementioned values, i.e., the increase in the historical flow of the spring due to all seismic-origin recharges made up until period
.
These formulas can be applied to the extreme case of a significant spring decrease and drying up due to earthquakes. It is a case opposite to those seen in this study but will serve to verify the possible mechanism that originates it. As an illustrative example, Vozmediano is a spring with an average flow of about 1100 L/s. This spring is located in the Iberian Mountain Range (Spain) and drains a large limestone aquifer over 1500 m thick with significant confinement. Its hydrodynamic volume at the average initial date of the depletion curves has been estimated as 25 hm
3, with a flow rate of 870 L/s. Its hydrograph was simulated for 20 years using the SIMERO model [
23,
25,
27], and presents an analysis of the effects on its flow from a possible artificial recharge made at the center of gravity of its aquifer.
According to Sanz et al. [
32,
33], this spring exhibits the same behavior during earthquakes: a sudden post-seismic decrease (never an increase) lasting several hours (no more than 24 h) and a rapid, progressive increase until the previous flow is restored. During recovery, the water comes out with white turbidity for no more than 24 h. This behavior repeats itself for strong or moderate earthquakes in both the far field—like the Lisbon earthquake of 1755, M (8.5–9)—and the near field (like the one on 3 September 1961 in Aguilar del Rio Alhama, La Rioja, Spain, M5). The flow modification depends on the felt intensity at the site, regardless of its magnitude and distance. In the nearby earthquake of Aguilar del Rio Alhama on 3 September 1961 (M5), the Vozmediano Spring, which had a flow rate of 780 L/s, gradually dried up within 20 min to an hour after the earthquake and two minutes after an aftershock. It remained completely dry for nine hours, leading to a lack of electrical production in the power plants until, also gradually, it recovered its previous flow. During the Lisbon earthquake of 1755, this spring dried up completely for approximately one day [
34].
The consequences of these seismic events on the discharge of the Vozmediano Spring can be evaluated using Equation (7). This analysis helps confirm that achieving its desiccation would necessitate pumping a volume of water approximately equivalent to its hydrodynamic capacity within a single day, which is practically unattainable. To elucidate the potential desiccation mechanism of this spring, there is no need to invoke significant alterations in the hydraulic parameters of the aquifer. In this scenario, it appears evident that stress variations induced by earthquakes can lead to changes in elastic parameters and temporary deformations in the rock. Consequently, the storage coefficient, contingent upon the vertical compressibility coefficient of the aquifer and its substantial thickness in this instance, can undergo a temporary increment, enabling the retention of water that would otherwise discharge through the spring over a day.
3.3. Confirmation of Faults as Principal Pathways for Fluid Pressure Transmission Due to Earthquakes
While the fact that faults serve as preferential conduits for transmitting fluid pressure during seismic events is established, employing the depletion coefficient as a hydraulic parameter offers a quantifiable confirmation of this assertion. As demonstrated by Sanz de Ojeda et al. [
14], the significance of faults as sensitive geological discontinuities for transmitting fluid pressure surpasses other lithologies during seismic events, particularly evident in the Lisbon earthquake of 1755, M (8.5–9).
Anticipating such behavior from faults seems reasonable, given their typical attributes as confined aquifers characterized by a very small storage coefficient (
) and a substantial length (
). Consider a fault F discharging through a spring (see
Figure 8). This fault exhibits a small saturated thickness
(a few meters), a length
(hundreds of meters), and a subvertical (non-vertical) dip, ensuring that the aquifer in the fault zone becomes confined at shallow depths. Assigning standard values to the variables in Equation (2), and defining the depletion coefficient, such as
for fractured zones (Hoek and Bray, 1981),
for confined aquifers like this one, and
10 m for major faults, gives us the following results:
If m ⇒ α = 2131.83 days−1.
If m ⇒ α = 85.27 days−1.
If m ⇒ α = 21.31 days−1.
It is evident that all α values are greater than 0.1 days−1, and as the fault length decreases, α (its hydraulic sensitivity to earthquakes) increases. While other factors (, , ) could be varied, these calculations suffice to verify that faults generally exhibit elevated α values. In conclusion, depletion coefficient (α) values corresponding to faults of considerable length, such as those connecting the Earth’s surface to the depths of the crust where earthquakes originate, tend to be high (α > 0.1 days−1). This heightened sensitivity to pore pressure renders faults more responsive than other lithologies.
3.4. On the Water Temperature Rise during an Earthquake
It has been observed that variations in the chemical composition and temperature of many springs that increase their flow due to earthquakes are not as substantial as might be expected initially (e.g., Rojstaczer and Wolf, in the 1989 Loma Prieta earthquake [
36]). However, as depicted in
Figure 1 and
Figure 2 and the equations derived here from a laminar Darcian regime, everything indicates a piston-type flow, where the fault rupture acts as a fluid pressure pump pushing groundwater upwards, with minimal mixing with the lower part. Despite this, the uplift eventually results in an increase in piezometric levels or surface spring flows. In other words, the water emerging originates from the upper part, which is similar in composition and temperature to that exiting the spring.
As the regime is laminar, the actual velocity is , where is hydraulic conductivity, is the hydraulic gradient (the modification of is crucial in the case of an earthquake), and is the effective porosity. For an earthquake at a depth of 5 km, for instance, a velocity of 5 km/day (5.78 cm/s) would be required for water to reach the surface in accordance with the observed rapid increase in hydrographs. However, even assuming this velocity, and with values for the dynamic viscosity of water at 100 °C and a fault width of 2 mm, for example, the Reynolds number would exceed the laminar regime. For greater depths, necessary velocities would demand turbulent regimes.
In summary, the bottom-up piston flow model and the Darcian laminar regime seem to explain why the water increment in springs after an earthquake does not significantly raise its temperature or alter its chemical composition.
3.5. Groundwaters Mobilized by Earthquakes and the Origin of Hydrothermal Mineral Deposits
As known, structural evidence indicating that the mineralization of hydrothermal deposits was synchronous with ancient host faults led many researchers to propose the connection between episodes of hydrothermal precipitation and increased seismic ruptures when those faults were active. The presence of fluids at high temperatures and high mineralization in the upper half of the seismogenic continental crust, the generation of permeability associated with rupture, and mineral precipitation due to sudden pressure reductions or fluid mixing at specific structural sites all indicate the significant role played by seismic pumping flow. This not only explains many deep hydrothermal deposits but also shallower deposits like those of the Mississippi Valley (ore type), whose source of mineralized thermal water is attributed to seismic origins associated with specific faults. The works of Sibson et al. are crucial in this regard [
37,
38]. However, this is not yet well-quantified. The application of groundwater hydraulics and mathematical models can shed light on the subject. For instance, estimating the hydrodynamic volumes mobilized by an earthquake over geological history is fundamental to understanding the mineralizing potential and capacity that seismic pumping can produce. This section only aims to initiate the topic.
Direct evidence of fluid involvement with earthquakes comes from post-seismic discharges near active faults. In the Chi-Chi earthquake alone, over 2 km
3 of groundwater expelled through some streams was estimated [
18,
19,
22]. One must consider that the water mobilized by an earthquake can surpass that expelled by springs and watercourses hydraulically connected to aquifers, as not all water can be drained by gravity to the exterior. As seen in
Section 3.2.1, the water mobilized above the drainage level, which can be consistently drained through a spring activated by an earthquake, can be calculated in its hydrograph by the difference in hydrodynamic volumes before and after the earthquake. For instance, for a spring with a flow rate of 100 L/s and a constant depletion coefficient of α = 0.0033 days
−1 that increases to 500 L/s due to an earthquake, the volume of water mobilized and drainable by gravity, calculated by the formula
, would increase from 2.6 hm
3 to 13.09 hm
3, which is five times more. The time “
” it would take for this spring to return to 100 L/s without recharge would be determined by the equation:
where
500 L/s (0.5 m
3/s) and
100 L/s (0.1 m
3/s), resulting in
days. The volume evacuated during this period would be 8.4 hm
3.
The recurrence intervals between successive main earthquakes typically range from one decade to many thousands of years, depending on the fault’s activity level. Consider, for instance, an active fault with a return period of 500 years mobilizing 1 km3 in each event; this would be equivalent to a continuous flow of approximately 63 L/s over those 500 years. Moreover, a significant portion of the mobilized water expelled externally is likely to be from the upper part. Therefore, the hot and mineralized water is not renewed but rather stirred near the fault. This water fractures the rock, increases its porosity, mineralizes, and, in turn, refills it.