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Minerals, Volume 11, Issue 5

2021 May - 110 articles

Cover Story: Geological carbon capture and sequestration (CCS) can reduce the overall carbon footprint of human activities. One important issue affecting the long-term success of CCS operations is the degradation of cement wellbore casings due to carbonation reactions in the underground CO2 storage environment. We use ab initio molecular dynamic (AIMD) simulations to quantitatively explore the reactivity of supercritical CO2 with the surfaces of portlandite—a model hydrated cement phase. CO2 undergoes a concerted reaction with H2O and surface –OH groups to form bicarbonate complexes. The free-energy barriers of their formation are controlled by the molecular structure of the surface water layer, which is, in turn, dictated by the surface chemistry and the degree of nanoconfinement. View this paper
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Articles (110)

  • Article
  • Open Access
8 Citations
4,199 Views
13 Pages

Tamuraite, Ir5Fe10S16, a New Species of Platinum-Group Mineral from the Sisim Placer Zone, Eastern Sayans, Russia

  • Andrei Y. Barkov,
  • Nadezhda D. Tolstykh,
  • Robert F. Martin and
  • Andrew M. McDonald

20 May 2021

Tamuraite, ideally Ir5Fe10S16, occurs as discrete phases (≤20 μm) in composite inclusions hosted by grains of osmium (≤0.5 mm across) rich in Ir, in association with other platinum-group minerals in the River Ko deposit of the Sisim Placer Zone, sout...

  • Feature Paper
  • Article
  • Open Access
9 Citations
3,869 Views
7 Pages

Lead Recovery from Solid Residues of Copper Industry Using Triethylenetetramine Solution

  • Mateusz Ciszewski,
  • Andrzej Chmielarz,
  • Zbigniew Szołomicki,
  • Michał Drzazga and
  • Katarzyna Leszczyńska-Sejda

20 May 2021

Industrial processing of mineral ores and concentrates generates large amounts of solid residues, which can be landfilled or further processed to recover selected elements depending on its economical profitability. Pressure leaching is a technology e...

  • Article
  • Open Access
3,056 Views
25 Pages

20 May 2021

Phlogopite flakes strewn on the soil of Caldara di Manziana (Italy) display multiple minute perforations. The site is a caldera linked to recent volcanism (90 ka to 0.8 Ma) with present emanations of CO2 (~150 t d−1) and H2S (~2.55 t d−1). Stereomicr...

  • Erratum
  • Open Access
1 Citations
2,234 Views
1 Page
  • Article
  • Open Access
11 Citations
3,858 Views
15 Pages

Mechanical Performance of Concrete Exposed to Sewage—The Influence of Time and pH

  • Justyna Czajkowska,
  • Maciej Malarski,
  • Joanna Witkowska-Dobrev,
  • Marek Dohojda and
  • Piotr Nowak

20 May 2021

Contact of concrete with aggressive factors, technological structures, reduces their durability through microstructural changes. This work presents the results of research on determining the influence of post grit chamber sewage and sewage from the a...

  • Article
  • Open Access
5 Citations
6,372 Views
17 Pages

Simulation-Based Analysis of Hydrometallurgical Processes. Case Study: Small-Scale Gold Mining in Ecuador

  • Santiago D. Salas,
  • Yris González,
  • Pamela Cango,
  • Jean Carlos Gómez,
  • Ronald Koepke and
  • Elizabeth Peña-Carpio

19 May 2021

In this work, two hydrometallurgical processes for gold recovery are explored for a small-scale gold mining case study located at Ponce Enriquez, Azuay, Ecuador. The hydrometallurgical systems consider the use of sodium cyanide and sodium thiosulfate...

  • Article
  • Open Access
9 Citations
3,016 Views
17 Pages

19 May 2021

Lacustrine mudrocks are composed of minerals and organic matter (OM). The origin and preservation of OM are two controlling factors of the hydrocarbon generation capacity of mudrocks. It is a key method in source rock research to study the deposition...

  • Article
  • Open Access
9 Citations
5,044 Views
17 Pages

~25 Ma Ruby Mineralization in the Mogok Stone Tract, Myanmar: New Evidence from SIMS U–Pb Dating of Coexisting Titanite

  • Di Zhang,
  • Shun Guo,
  • Yi Chen,
  • Qiuli Li,
  • Xiaoxiao Ling,
  • Chuanzhou Liu and
  • Kyaing Sein

19 May 2021

Ruby (red corundum) is one of the most prominent colored gemstones in the world. The highest-quality ruby (“pigeon blood” ruby) comes from marbles of the Mogok Stone Tract in central Myanmar. Although Mogok ruby has been exploited since the 6th centu...

  • Article
  • Open Access
7 Citations
4,125 Views
19 Pages

Long-Term Arsenic Sequestration in Biogenic Pyrite from Contaminated Groundwater: Insights from Field and Laboratory Studies

  • Alicia Fischer,
  • James Saunders,
  • Sara Speetjens,
  • Justin Marks,
  • Jim Redwine,
  • Stephanie R. Rogers,
  • Ann S. Ojeda,
  • Md Mahfujur Rahman,
  • Zeki M. Billor and
  • Ming-Kuo Lee

19 May 2021

Pumping groundwater from arsenic (As)-contaminated aquifers exposes millions of people, especially those in developing countries, to high doses of the toxic contaminant. Previous studies have investigated cost-effective techniques to remove groundwat...

  • Feature Paper
  • Article
  • Open Access
9 Citations
4,004 Views
13 Pages

Growth Interruptions in Arctic Rhodoliths Correspond to Water Depth and Rhodolith Morphology

  • Moritz Schlüter,
  • Ines Pyko,
  • Max Wisshak,
  • Christian Schulbert and
  • Sebastian Teichert

19 May 2021

Coralline algae that form rhodoliths are widespread globally and their skeletal growth patterns have been used as (paleo-) environmental proxies in a variety of studies. However, growth interruptions (hiati) within their calcareous skeletons are rega...

  • Article
  • Open Access
9 Citations
4,351 Views
15 Pages

19 May 2021

The objective of this work was to study the effect of muscovite and biotite on the flotation of chalcopyrite and molybdenite in seawater, and the use of sodium hexametaphosphate and sodium silicate to improve copper and molybdenum recoveries. The imp...

  • Article
  • Open Access
9 Citations
4,244 Views
32 Pages

Ultramafic Alkaline Rocks of Kepino Cluster, Arkhangelsk, Russia: Different Evolution of Kimberlite Melts in Sills and Pipes

  • Alexey Vladimirovich Kargin,
  • Anna Andreevna Nosova,
  • Ludmila Vyacheslavovna Sazonova,
  • Vladimir Vasilievich Tretyachenko,
  • Yulia Olegovna Larionova and
  • Elena Vladimirovna Kovalchuk

19 May 2021

To provide new insights into the evolution of kimberlitic magmas, we have undertaken a detailed petrographic and mineralogical investigation of highly evolved carbonate–phlogopite-bearing kimberlites of the Kepino cluster, Arkhangelsk kimberlite prov...

  • Article
  • Open Access
3 Citations
6,723 Views
17 Pages

The Features of Native Gold in Ore-Bearing Breccias with Realgar-Orpiment Cement of the Vorontsovskoe Deposit (Northern Urals, Russia)

  • Sergey Y. Stepanov,
  • Roman S. Palamarchuk,
  • Dmitry A. Varlamov,
  • Darya V. Kiseleva,
  • Ludmila N. Sharpyonok,
  • Radek Škoda and
  • Anatoly V. Kasatkin

19 May 2021

This paper describes native gold in ore-bearing breccias with realgar-orpiment cement from the Vorontsovskoe gold deposit (Northern Urals, Russia). Particular attention is paid to the morphological features of native gold and its relation to other mi...

  • Article
  • Open Access
28 Citations
3,343 Views
13 Pages

19 May 2021

As mining depth increases, the backfill mining method is more and more widely used in underground mines. The dynamic load generated by the blasting can affect the stability of the cemented tailings backfill (CTB). The CTB samples were prepared to con...

  • Article
  • Open Access
11 Citations
3,942 Views
18 Pages

18 May 2021

From the 1950s and 1960s of the last century, a parish church dating back to the 6th century AD was identified during reclamation works of Valle Pega. The archaeological investigation allowed the recovery of the parish and the attached baptistery, as...

  • Feature Paper
  • Article
  • Open Access
16 Citations
5,164 Views
13 Pages

Occurrence and Distribution of Moganite and Opal-CT in Agates from Paleocene/Eocene Tuffs, El Picado (Cuba)

  • Jens Götze,
  • Klaus Stanek,
  • Gerardo Orozco,
  • Moritz Liesegang and
  • Tanja Mohr-Westheide

18 May 2021

Agates in Paleocene/Eocene tuffs from El Picado/Los Indios, Cuba were investigated to characterize the mineral composition of the agates and to provide data for the reconstruction of agate forming processes. The volcanic host rocks are strongly alter...

  • Article
  • Open Access
16 Citations
4,431 Views
23 Pages

18 May 2021

The relationship of sedimentary organic matter, oil-gas and sandstone-type uranium (U) deposits is the key problem of U-mineralization. Whether migrate hydrocarbons participate in U-mineralization is still a controversy. Typical U deposits of the Erl...

  • Feature Paper
  • Review
  • Open Access
30 Citations
10,862 Views
17 Pages

Challenges Related to the Processing of Fines in the Recovery of Platinum Group Minerals (PGMs)

  • Kirsten C. Corin,
  • Belinda J. McFadzean,
  • Natalie J. Shackleton and
  • Cyril T. O’Connor

18 May 2021

In order to increase the recovery of PGMs by flotation, it is necessary to optimise the liberation of the key minerals in which the platinum group elements (PGEs) are contained which include sulphides, arsenides, tellurides, and ferroalloys among oth...

  • Article
  • Open Access
11 Citations
3,798 Views
18 Pages

17 May 2021

The Lower Cretaceous Dalazi Formation in the Yanji Basin, eastern Jilin Province is of particular interest because it contains key fresh water fossil taxa, oil and gas resources, a potential terrestrial Albian–Cenomanian boundary, and regional unconf...

  • Article
  • Open Access
7 Citations
3,242 Views
15 Pages

17 May 2021

In this study, two auxiliary collectors (methyl naphthalene and naphthalene) of molybdenite and the traditional collector (kerosene) were mixed for molybdenite flotation, respectively. According to the selection and analysis of the auxiliary collecto...

  • Article
  • Open Access
14 Citations
7,547 Views
13 Pages

Recovery of Iron from Mill Scale by Reduction with Carbon Monoxide

  • Krzysztof Nowacki,
  • Tomasz Maciąg and
  • Teresa Lis

17 May 2021

The mill scale is a waste from the iron and steel industry. Due to the high content of iron in the form of oxides, it is an attractive material for the recovery of metallic iron by reduction. The product of mill scale reduction is an iron with a very...

  • Review
  • Open Access
24 Citations
6,467 Views
15 Pages

16 May 2021

The term asbestos refers to a group of serpentine (chrysotile) and amphibole (amosite, crocidolite, anthophyllite, tremolite and actinolite) minerals with a fibrous habit. Their chemical-physical properties make them one of the most important inorgan...

  • Article
  • Open Access
5 Citations
3,962 Views
17 Pages

Low Temperature Illitization through Illite-Dioctahedral Vermiculite Mixed Layers in a Tropical Saline Lake Rich in Hydrothermal Fluids (Sochagota Lake, Colombia)

  • Gabriel Ricardo Cifuentes,
  • Juan Jiménez-Millán,
  • Claudia Patricia Quevedo,
  • Fernando Nieto,
  • Javier Cuadros and
  • Rosario Jiménez-Espinosa

15 May 2021

In this investigation, we showed that high salinity promoted by hydrothermal inputs, reducing conditions of sediments with high content in organic matter, and the occurrence of an appropriate clay mineral precursor provide a suitable framework for lo...

  • Feature Paper
  • Article
  • Open Access
16 Citations
6,810 Views
16 Pages

15 May 2021

Systems for transport and processing of granular media are challenging to analyse, operate and optimise. In the mining and mineral processing industries, these systems are chains of processes with a complex interplay among the equipment, control and...

  • Review
  • Open Access
22 Citations
7,347 Views
22 Pages

Using Calcined Marls as Non-Common Supplementary Cementitious Materials—A Critical Review

  • Abdelmoujib Bahhou,
  • Yassine Taha,
  • Yassine El Khessaimi,
  • Rachid Hakkou,
  • Arezki Tagnit-Hamou and
  • Mostafa Benzaazoua

14 May 2021

This review summarizes the major research and scientific findings on the relevance of using calcined marl as supplementary cementitious material in developing eco-friendly cement for the next generation. Incorporation of calcined marl into cement can...

  • Article
  • Open Access
16 Citations
4,387 Views
22 Pages

Use of Natural Clinoptilolite in the Preparation of an Efficient Adsorbent for Ciprofloxacin Removal from Aqueous Media

  • Barbara Kalebić,
  • Jelena Pavlović,
  • Jelena Dikić,
  • Aleksander Rečnik,
  • Sašo Gyergyek,
  • Nikola Škoro and
  • Nevenka Rajić

14 May 2021

The adsorption of the antibiotic ciprofloxacin (CIP) from an aqueous solution by natural zeolite, the calcium-rich clinoptilolite (CLI), and magnetite-coated CLI (MAG-CLI) was investigated. Both CLI and MAG-CLI showed a high adsorption affinity towar...

  • Article
  • Open Access
2 Citations
3,214 Views
15 Pages

14 May 2021

Cretaceous volcano-sedimentary basins and successions in the Korean Peninsula are located along NE-SW- and NNE-SSW-trending sinistral strike–slip fault systems. Soft-sediment deformation structures (SSDS) of lacustrine sedimentary strata occur in the...

  • Review
  • Open Access
2 Citations
3,586 Views
29 Pages

14 May 2021

The kinetics of the dissolution of salts and minerals remains a field of active research because these reactions are important to many fields, such as geochemistry, extractive metallurgy, corrosion, biomaterials, dentistry, and dietary uptake. A nove...

  • Article
  • Open Access
10 Citations
3,726 Views
22 Pages

X-ray Total Scattering Study of Phases Formed from Cement Phases Carbonation

  • Ana Cuesta,
  • Angeles G. De la Torre and
  • Miguel A. G. Aranda

14 May 2021

Carbonation in cement binders has to be thoroughly understood because it affects phase assemblage, binder microstructure and durability performance of concretes. This is still not the case as the reaction products can be crystalline, nanocrystalline...

  • Article
  • Open Access
6 Citations
2,990 Views
19 Pages

Taloe—Sedimentation in an Intermittent Lake (Russian Federation, Republic of Khakassia)

  • Maria O. Khrushcheva,
  • Ekaterina M. Dutova,
  • Platon A. Tishin,
  • Alexander L. Arkhipov,
  • Alexei N. Nikitenkov and
  • Alexei I. Chernyshov

14 May 2021

This paper examines the mineral and geochemical features of lake sediments and waters in intermittent Lake Taloe, located in a semiarid climate. Minerals that belong to groups of oxides, sulfides, aluminosilicates, carbonates, sulfates, and halides a...

  • Article
  • Open Access
10 Citations
5,062 Views
21 Pages

13 May 2021

Emeralds require the unusual association of typically compatible elements (Cr, V), with incompatible Be to form, and occur in complex tectonic settings associated with sediments (type IIB; Colombia) or, more commonly, with magmatism and regional meta...

  • Article
  • Open Access
8 Citations
4,747 Views
25 Pages

A New Constraint on the Physicochemical Condition of Mars Surface during the Amazonian Epoch Based on Chemical Speciation for Secondary Minerals in Martian Nakhlites

  • Hiroki Suga,
  • Keika Suzuki,
  • Tomohiro Usui,
  • Akira Yamaguchi,
  • Oki Sekizawa,
  • Kiyofumi Nitta,
  • Yasuo Takeichi,
  • Takuji Ohigashi and
  • Yoshio Takahashi

13 May 2021

Iddingsite in Martian nakhlites contains various secondary minerals that reflect water–rock interaction on Mars. However, the formation processes of secondary Fe minerals in iddingsite are unclear because they include carbonates precipitated under re...

  • Article
  • Open Access
20 Citations
3,058 Views
16 Pages

13 May 2021

Artificial rich ore for blast furnace use can be produced by sintering ultra-poor vanadium-titanium magnetite (PVTM) with a high-grade iron concentrate. Here, acid (R = 0.33, 0.50), self-fluxing (R = 1.10), and high-basicity (R = 2.60) PVTM sinters w...

  • Feature Paper
  • Article
  • Open Access
8 Citations
3,671 Views
8 Pages

Synthesis and Compressibility of Novel Nickel Carbide at Pressures of Earth’s Outer Core

  • Timofey Fedotenko,
  • Saiana Khandarkhaeva,
  • Leonid Dubrovinsky,
  • Konstantin Glazyrin,
  • Pavel Sedmak and
  • Natalia Dubrovinskaia

13 May 2021

We report the high-pressure synthesis and the equation of state (EOS) of a novel nickel carbide (Ni3C). It was synthesized in a diamond anvil cell at 184(5) GPa through a direct reaction of a nickel powder with carbon from the diamond anvils upon hea...

  • Communication
  • Open Access
4 Citations
2,365 Views
11 Pages

12 May 2021

The method of dividing the “three zones” of spontaneous combustion in goaf by oxygen volume fraction is the most widely used and effective method at present. However, the oxygen volume fraction method does not consider the influence of methane concen...

  • Article
  • Open Access
12 Citations
4,967 Views
20 Pages

Composition and Pressure Effects on Partitioning of Ferrous Iron in Iron-Rich Lower Mantle Heterogeneities

  • Susannah M. Dorfman,
  • Farhang Nabiei,
  • Charles-Edouard Boukaré,
  • Vitali B. Prakapenka,
  • Marco Cantoni,
  • James Badro and
  • Philippe Gillet

12 May 2021

Both seismic observations of dense low shear velocity regions and models of magma ocean crystallization and mantle dynamics support enrichment of iron in Earth’s lowermost mantle. Physical properties of iron-rich lower mantle heterogeneities in the m...

  • Article
  • Open Access
6 Citations
3,006 Views
15 Pages

11 May 2021

The paper presents the results of research on rare earth elements (REY) and selected radionuclides in barren rocks deposited on a heap at a mine belonging to the Polish Mining Group (the largest producer of hard coal in EU countries). The maximum con...

  • Article
  • Open Access
3 Citations
2,426 Views
11 Pages

11 May 2021

An ab initio density functional theory method (DFT) with D3 dispersion corrections (DFT-D3) was employed to study the 64 possible models of the structure of hectorite intercalated with tetramethylammonium (TMA) cations with the aim to find the additi...

  • Communication
  • Open Access
46 Citations
9,285 Views
11 Pages

11 May 2021

Mineral identification is an important part of geological analysis. Traditional identification methods rely on either the experience of the appraisers or the various measuring instruments, and the methods are either easily influenced by appraisers’ e...

  • Article
  • Open Access
10 Citations
4,121 Views
20 Pages

11 May 2021

Determining aqueous sulfate sources in terrestrial cold environments can provide an insight into the surface hydrological conditions and sulfur cycle on Mars. In this study, we analyzed sulfur and oxygen isotope compositions of secondary sulfate salt...

  • Article
  • Open Access
6 Citations
5,021 Views
21 Pages

Analytical Approach for the Study of Teotihuacan Mural Paintings from the Techinantitla Complex

  • José Luis Ruvalcaba-Sil,
  • Luis Barba,
  • Edgar Casanova-González,
  • Alejandro Mitrani,
  • Margarita Muñoz,
  • Isaac Rangel-Chavez,
  • Miguel Ángel Maynez-Rojas and
  • Jaqueline Cañetas

11 May 2021

Techinantitla building complex, in the Amanalco neighborhood of the ancient city of Teotihuacan, is famous for the iconography and quality of the mural paintings found in this site. A significant part of this heritage has been lost due to looting. In...

  • Article
  • Open Access
26 Citations
6,885 Views
18 Pages

11 May 2021

Geological carbon capture and sequestration (CCS) is a promising technology for curbing the global warming crisis by reduction of the overall carbon footprint. Degradation of cement wellbore casings due to carbonation reactions in the underground CO2...

  • Article
  • Open Access
4 Citations
3,351 Views
15 Pages

11 May 2021

In situ analyses of trace elements and rare-earth elements (REEs) were performed by use of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) on scheelite samples from the Yingzuihongshan tungsten deposit in western Inner Mongoli...

  • Article
  • Open Access
7 Citations
4,498 Views
28 Pages

10 May 2021

The Duobaoshan (DBS)-Tongshan (TS) porphyry Cu–(Mo) deposit (4.4 Mt Cu, 0.15 Mt Mo) is located in the northeastern part of the central Asian orogenic belt (CAOB) in northeastern China. It is hosted by early Ordovician dioritic to granodioritic intrus...

  • Article
  • Open Access
5 Citations
3,629 Views
19 Pages

9 May 2021

Fluid inclusions were studied in rocks from different wells from the Barnówko–Mostno–Buszewo (BMB), the largest oil field in Poland and from the Lubiatów field. Sampling was performed at depths between about 3120–3220 m and 3221–3256 m, respectively....

  • Article
  • Open Access
15 Citations
5,292 Views
17 Pages

9 May 2021

Montmorillonite is one of the principal mineralogical phases in clay minerals, where its interaction with water and other molecules represents one of the most important aspects and properties for basic science and specific applications. In fact, mont...

  • Article
  • Open Access
27 Citations
3,821 Views
19 Pages

Health Risks and Source Analysis of Heavy Metal Pollution from Dust in Tianshui, China

  • Bo Tan,
  • Hongwei Wang,
  • Xinmin Wang,
  • Chen Ma,
  • Jing Zhou and
  • Xinyan Dai

9 May 2021

The purpose of this study is to explore the degree and spatial distribution of dust heavy metal pollution in Tianshui City, the health risks, and the sources of heavy metals. The geoaccumulation index and health risk assessment are used to study poll...

  • Article
  • Open Access
14 Citations
5,097 Views
20 Pages

8 May 2021

The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even...

  • Article
  • Open Access
20 Citations
4,259 Views
16 Pages

8 May 2021

Soil fertility is determined by biological diversity at all levels of life, from genes to entire biocenoses. The aim of this study was to evaluate bacterial diversity in soil contaminated with Cd2+, Co2+ and Ni2+ and sown with Brassica napus. This is...

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Minerals - ISSN 2075-163X