Genesis of the Yingzuihongshan Tungsten Deposit, Western Inner Mongolia Autonomous Region, North China: Constraints from In Situ Trace Elements Analyses of Scheelite
Abstract
:1. Introduction
2. Geological Background and Mineralization Characteristics
3. Sample Descriptions and Analytical Methods
4. Analytical Results of Trace Elements in Scheelite
5. Discussions
5.1. Ore-Forming Materials and Parent-Fluid Source of the Yingzuihongshan Tungsten Deposit
5.2. Inhomogeneous Distribution of REEs in Scheelite
5.3. Ore-Forming Hydrothermal System of the Yingzuihongshan Tungsten Deposit
5.4. Ore Genesis of the Yingzuihongshan Tungsten Deposit
6. Conclusions
- (1)
- The high Nb, Ta and Mo contents of scheelite from the Yingzuihongshan tungsten deposit suggest that the ore-forming materials mainly came from the crust, while the ore-forming fluid is pneumato-hydrothermal in an oxidizing environment and is derived from the granitic magma.
- (2)
- Scheelite from the Yingzuihongshan tungsten deposit has much higher REE contents and ∑REE values compared with those of scheelite from other mineral deposits in the world. Most of them have well-developed internal zoning that is closely related to the high REE contents. The inhomogeneous distribution of REEs exists in different scheelite grains, or even in different parts of the same grain. The chondrite-normalized REE distribution patterns of scheelite from the Yingzuihongshan tungsten deposit can be classified into the MREEs-enriched type, REE-flat type and MREEs-depleted type, probably revealing a complete dynamic evolution process with very dynamic conditions that reflect this scheelite formation.
- (3)
- The Yingzuihongshan tungsten deposit is the quartz-vein-hosted tungsten type associated with monzonitic granite.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Ba | Sr | Nb | Ta | Mo | Sample | Ba | Sr | Nb | Ta | Mo |
---|---|---|---|---|---|---|---|---|---|---|---|
13BS032h-1 | 0.333 | 87.06 | 740.63 | 18.93 | 3.91 | 13BS033h-10 | 0.0207 | 48.73 | 595.78 | 16.06 | 3.36 |
13BS032h-2 | 0.226 | 67.3 | 825.91 | 45.81 | 8.15 | 13BS033h-11 | 0.0164 | 44.21 | 462.96 | 9.16 | 3.29 |
13BS032h-3 | 0.389 | 57.35 | 647.74 | 33.57 | 9.66 | 13BS033h-12 | 0.0055 | 44.79 | 490.39 | 10.55 | 2.82 |
13BS032h-4 | 0.0087 | 54.48 | 839.54 | 27.24 | 3.41 | 13BS033h-13 | 0.0112 | 47.02 | 455.37 | 9.85 | 2.71 |
13BS032h-5 | 0.0377 | 53.94 | 644.67 | 18.31 | 3.27 | 13BS033h-14 | 1.289 | 49.36 | 446.43 | 9.93 | 4.69 |
13BS032h-6 | 0.0053 | 45.96 | 556.55 | 13.78 | 2.77 | 13BS033h-15 | 0.0206 | 44.17 | 478.23 | 9.76 | 3.32 |
13BS032h-7 | 0.0414 | 48.46 | 811.12 | 25.41 | 2.37 | 13BS033h-16 | 0.0148 | 51.61 | 689.52 | 37.47 | 5.49 |
13BS032h-8 | 0.0364 | 72.54 | 1325.15 | 44.25 | 1.99 | 13BS033h-17 | 2.32 | 55.74 | 978.04 | 60.31 | 4.41 |
13BS032h-9 | 0.0428 | 54.99 | 804.19 | 53.11 | 5.62 | 13BS033h-18 | 0.228 | 50.91 | 661.37 | 13.16 | 3.51 |
13BS032h-10 | 0.0078 | 48.56 | 710.7 | 38.28 | 3.86 | 13BS033h-19 | 0.181 | 49.16 | 484.02 | 9.21 | 3.76 |
13BS032h-11 | 0.0132 | 50.5 | 823.79 | 35.48 | 3.88 | 13BS034h-1 | 0.0446 | 55.01 | 874.33 | 48.18 | 4.26 |
13BS032h-12 | 0.0321 | 46.46 | 642.77 | 19.24 | 3.75 | 13BS034h-2 | 0.049 | 50.58 | 636.85 | 25.52 | 4.33 |
13BS032h-13 | 0.064 | 43.21 | 473.66 | 10.64 | 2.83 | 13BS034h-3 | 0.116 | 130.65 | 549.93 | 10.99 | 2.99 |
13BS032h-14 | 0.312 | 55.43 | 774.83 | 21.02 | 3.31 | 13BS034h-4 | 0.208 | 51.38 | 755.18 | 22.04 | 3.16 |
13BS033h-1 | 0.11 | 60.54 | 444.23 | 9 | 2.97 | 13BS034h-5 | 0.0029 | 48.68 | 449.33 | 8.91 | 2.4 |
13BS033h-2 | 0.0026 | 54.2 | 271.68 | 5.06 | 2.23 | 13BS036h-1 | 0.084 | 71.63 | 125.64 | 1.66 | 2.46 |
13BS033h-3 | 0.0028 | 50.95 | 55.55 | 0.864 | 2.87 | 13BS036h-2 | 0.0111 | 44.78 | 103.62 | 1.266 | 2.43 |
13BS033h-4 | 0.283 | 53.96 | 605.07 | 14.66 | 3.83 | 13BS036h-3 | 0.295 | 47.04 | 85.58 | 1.009 | 2.08 |
13BS033h-5 | 0.0273 | 54.57 | 464.74 | 12.04 | 3.52 | 13BS036h-4 | 0.0155 | 44.75 | 630.57 | 38.49 | 9.48 |
13BS033h-6 | 0.122 | 51.33 | 162.14 | 3.13 | 3.49 | 13BS036h-5 | 0.0156 | 50.65 | 925.56 | 38.3 | 6.34 |
13BS033h-7 | 0.138 | 52.93 | 488.74 | 9.42 | 2.34 | 13BS036h-6 | 0.127 | 44.7 | 813.17 | 20.63 | 7.8 |
13BS033h-8 | 0.0075 | 59.21 | 45.55 | 0.68 | 2.77 | 13BS036h-7 | 0.0449 | 46.58 | 913.87 | 49.18 | 6.27 |
13BS033h-9 | 0.045 | 63.6 | 2667.1 | 99.83 | 3.07 | 13BS036h-8 | 0.0415 | 49.37 | 627.52 | 34.8 | 4.66 |
Element | Daping Gold Deposit in Yunnan Province, China | Yangjingou Scheelite Deposit in Jilin Province, China | Archaean Greenstone Belt Gold Deposit in Western Australia | Yingzuihongshan Tungsten Deposit |
---|---|---|---|---|
Mo | 0.47–1.39 | 0.06–0.15 | LOD–3.71 | 1.97–9.66 |
Sr | 1127–1610 | 168–238 | 341–4280 | 43.21–130.65 |
Nb | 0.01–0.02 | 0.08–0.32 | 0.06–3.18 | 45.55–2667.10 |
Ta | 0.10–0.11 | 0.03–0.04 | 85.3–1142 | 0.68–99.83 |
data sources | [38] | [12] | [14] | This paper |
Sample | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | Y | ∑REE | δEu | δCe |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
scheelite | ||||||||||||||||||
13BS032h-1 | 79.5 | 442.36 | 104.86 | 745.34 | 314.19 | 9.68 | 292.71 | 40.46 | 196.36 | 33.68 | 73.98 | 9.19 | 60.11 | 7.67 | 653.9 | 2410.09 | 0.10 | 1.00 |
13BS032h-2 | 87.49 | 491.59 | 111.59 | 707.41 | 267.37 | 8.26 | 216.28 | 30.2 | 141.66 | 22.48 | 51.18 | 6.59 | 40.87 | 4.84 | 624.9 | 2187.81 | 0.10 | 1.04 |
13BS032h-3 | 77.25 | 432.58 | 99.47 | 632.34 | 237.98 | 8.64 | 197.27 | 27.66 | 132.87 | 21.68 | 50.33 | 6.54 | 41.98 | 5.14 | 622.6 | 1971.73 | 0.12 | 1.03 |
13BS032h-4 | 100.4 | 548.2 | 131.27 | 866.98 | 374.83 | 8.75 | 322.72 | 42.39 | 190.61 | 29.5 | 66.46 | 8.8 | 57.69 | 6.94 | 615.8 | 2755.51 | 0.08 | 0.99 |
13BS032h-5 | 87.95 | 481.55 | 104.73 | 666.64 | 271.02 | 7.54 | 251.42 | 35.18 | 174.71 | 30.15 | 72.13 | 9.98 | 67.44 | 8.47 | 666.6 | 2268.91 | 0.09 | 1.07 |
13BS032h-6 | 81.65 | 437.24 | 95.58 | 614.02 | 258.35 | 3.98 | 227.39 | 30.2 | 137.98 | 22.75 | 54.05 | 7.78 | 56 | 7.16 | 486.5 | 2034.13 | 0.05 | 1.06 |
13BS032h-7 | 74.41 | 433.17 | 101.24 | 670.07 | 301.04 | 5.46 | 258.88 | 34.3 | 151.02 | 23.16 | 53.31 | 7.56 | 52.86 | 6.81 | 520.6 | 2173.29 | 0.06 | 1.03 |
13BS032h-8 | 103.7 | 524.6 | 120.08 | 762.11 | 345.38 | 6.46 | 311.57 | 43.92 | 202.65 | 33.33 | 83 | 12.96 | 101.19 | 14.07 | 664.1 | 2664.97 | 0.06 | 1.01 |
13BS032h-9 | 107.5 | 561.18 | 142.49 | 868.78 | 326.62 | 8.84 | 304.24 | 47.38 | 245.57 | 40.53 | 87.4 | 9.96 | 55.36 | 6.23 | 760.4 | 2812.10 | 0.08 | 0.94 |
13BS032h-10 | 85.39 | 499.79 | 113.87 | 714.1 | 277.4 | 7.45 | 263.66 | 40.91 | 216.82 | 37.06 | 83.42 | 9.89 | 57.52 | 6.61 | 777.7 | 2413.89 | 0.08 | 1.05 |
13BS032h-11 | 98.32 | 539.6 | 135.48 | 871.55 | 342.78 | 6.52 | 281.02 | 39.57 | 192.05 | 31.57 | 71.31 | 8.84 | 54 | 6.4 | 698.7 | 2679.01 | 0.06 | 0.96 |
13BS032h-12 | 92.12 | 505.76 | 111.95 | 676.22 | 245.83 | 9.96 | 209.98 | 31.19 | 163.32 | 29.83 | 73.96 | 10.04 | 65.63 | 8.18 | 711.9 | 2233.97 | 0.13 | 1.05 |
13BS032h-13 | 110.2 | 537.29 | 100.1 | 499.18 | 152.24 | 6.88 | 122.32 | 19.89 | 120.8 | 25.27 | 78.55 | 13.25 | 97.96 | 12.85 | 666 | 1896.77 | 0.15 | 1.16 |
13BS032h-14 | 119.8 | 616.2 | 132.63 | 739.76 | 250.98 | 9.66 | 189.1 | 27.33 | 142.45 | 25.89 | 69.85 | 10.77 | 73.27 | 9.15 | 626.3 | 2416.83 | 0.13 | 1.06 |
13BS033h-1 | 137 | 562.24 | 102.76 | 496.14 | 162.83 | 11.41 | 138.19 | 24.02 | 145.99 | 30.39 | 91.59 | 15.14 | 112.35 | 14.47 | 648.9 | 2044.47 | 0.23 | 1.11 |
13BS033h-2 | 159.3 | 540.17 | 84.78 | 401.13 | 136.35 | 5.43 | 119.47 | 20.56 | 126.21 | 27.61 | 90.07 | 16.38 | 134.85 | 18.71 | 539.9 | 1880.98 | 0.13 | 1.13 |
13BS033h-3 | 74.41 | 170.57 | 20.6 | 78.18 | 23.41 | 6.35 | 22.3 | 5.41 | 48.26 | 13.91 | 60.73 | 14.56 | 151.88 | 25.29 | 315.2 | 715.86 | 0.84 | 1.05 |
13BS033h-4 | 132.4 | 553.89 | 118.54 | 541.9 | 146.15 | 13.59 | 122.29 | 23.5 | 151.93 | 31.58 | 91.83 | 14.18 | 95.2 | 11.68 | 752.9 | 2048.67 | 0.30 | 1.00 |
13BS033h-5 | 102.1 | 506.36 | 91.81 | 437.72 | 126.15 | 9.58 | 110.62 | 20.53 | 131.45 | 27.47 | 80.5 | 12.54 | 85.38 | 10.75 | 758.6 | 1752.91 | 0.24 | 1.18 |
13BS033h-6 | 105.5 | 204.05 | 21 | 72.33 | 18.01 | 4.94 | 17.79 | 4.95 | 45.61 | 13.33 | 57.84 | 14.27 | 150.99 | 24.95 | 333.8 | 755.58 | 0.83 | 1.00 |
13BS033h-7 | 175.9 | 410.07 | 44.18 | 149.85 | 36.48 | 10.38 | 30.79 | 7.07 | 58.77 | 15.97 | 66.86 | 15.89 | 162.88 | 24.47 | 462.5 | 1209.60 | 0.92 | 1.11 |
13BS033h-8 | 107.7 | 227.39 | 26.49 | 105.5 | 29.55 | 3.77 | 27.16 | 6.07 | 50.28 | 14.02 | 60.37 | 14.59 | 155.63 | 25.77 | 358.9 | 854.30 | 0.40 | 1.01 |
13BS033h-9 | 241.2 | 932.07 | 183.65 | 880.51 | 268.54 | 20.58 | 282.33 | 57.78 | 388.42 | 81.25 | 236.41 | 39 | 296.99 | 39.23 | 1691 | 3947.95 | 0.23 | 1.03 |
13BS033h-10 | 102.4 | 542.42 | 110.24 | 601.48 | 199.39 | 10.94 | 193.04 | 33.05 | 199.79 | 39.51 | 102.96 | 13.88 | 90.56 | 11.28 | 856.7 | 2250.97 | 0.17 | 1.11 |
13BS033h-11 | 144 | 569.22 | 94.26 | 465.83 | 139.2 | 8.23 | 133.77 | 24.49 | 167.17 | 38.86 | 118.7 | 18.78 | 136.58 | 18.13 | 777.6 | 2077.17 | 0.18 | 1.16 |
13BS033h-12 | 116.3 | 549.96 | 107.41 | 596.83 | 198.94 | 8.36 | 173.8 | 27.12 | 155.13 | 30.71 | 88.4 | 14.22 | 107.14 | 14.14 | 709.3 | 2188.49 | 0.13 | 1.11 |
13BS033h-13 | 102.9 | 505.17 | 101.35 | 595.34 | 214.87 | 10.84 | 191.52 | 28.84 | 161.01 | 31.75 | 89.82 | 14.1 | 101.97 | 13.26 | 681.2 | 2162.69 | 0.16 | 1.10 |
13BS033h-14 | 105.1 | 515.33 | 101.07 | 592.18 | 209.06 | 10.64 | 184.15 | 28.69 | 161.36 | 31.67 | 90.28 | 14.15 | 102.29 | 13.29 | 681.4 | 2159.26 | 0.16 | 1.12 |
13BS033h-15 | 134.1 | 562.72 | 96.39 | 506.78 | 160.14 | 8.17 | 146.17 | 25.37 | 162.57 | 36.41 | 107.96 | 16.66 | 123.91 | 16.3 | 822.7 | 2103.60 | 0.16 | 1.16 |
13BS033h-16 | 63.33 | 377.67 | 91.71 | 647.31 | 371.14 | 11.76 | 423.79 | 66.77 | 322.53 | 49.56 | 101.12 | 10.88 | 57.72 | 6.32 | 912.2 | 2601.61 | 0.09 | 1.00 |
13BS033h-17 | 88.43 | 539.5 | 130.73 | 846.89 | 380.38 | 8.82 | 380.98 | 60.8 | 315.31 | 51.65 | 108.37 | 11.82 | 63.26 | 6.78 | 947.9 | 2993.72 | 0.07 | 1.01 |
13BS033h-18 | 198.7 | 639.2 | 90.17 | 366.78 | 78.98 | 6.47 | 52.28 | 8.92 | 58.29 | 13.12 | 48.73 | 10.74 | 100.05 | 14.07 | 372.8 | 1686.52 | 0.29 | 1.17 |
13BS033h-19 | 199.1 | 627.63 | 117.19 | 559.69 | 134.81 | 8.41 | 92.04 | 14.32 | 87.97 | 19.35 | 63.92 | 11.74 | 94.23 | 12.2 | 392.6 | 2042.62 | 0.22 | 0.99 |
13BS034h-1 | 70.8 | 427.79 | 105.54 | 742.18 | 394.75 | 9.17 | 374.66 | 52.24 | 240.15 | 35.81 | 72.71 | 8.01 | 42.93 | 4.68 | 766.3 | 2581.42 | 0.07 | 0.99 |
13BS034h-2 | 82.7 | 456.55 | 102.29 | 622.96 | 241.56 | 8 | 200.65 | 29.12 | 149.31 | 25.56 | 61.75 | 8.33 | 53.16 | 6.56 | 716.5 | 2048.50 | 0.11 | 1.05 |
13BS034h-3 | 71.77 | 395.18 | 86.45 | 529.04 | 221.06 | 6.59 | 177.99 | 23.56 | 106.68 | 16.81 | 41.43 | 6.11 | 42.66 | 5.29 | 353.1 | 1730.62 | 0.10 | 1.06 |
13BS034h-4 | 101 | 546.9 | 124.62 | 726.28 | 255.85 | 10.24 | 202.81 | 30.22 | 161.13 | 29.58 | 77.76 | 11.11 | 74.19 | 9.05 | 724.4 | 2360.75 | 0.13 | 1.03 |
13BS034h-5 | 74.74 | 400.25 | 84.17 | 489.16 | 184.06 | 5.29 | 147.96 | 20.61 | 103.5 | 18.27 | 49.3 | 7.6 | 54.35 | 7.05 | 413.1 | 1646.31 | 0.09 | 1.09 |
13BS036h-1 | 49.04 | 174.54 | 29.12 | 157.03 | 58.2 | 7.91 | 60.04 | 10.37 | 63.76 | 13.64 | 44.5 | 8.55 | 71.5 | 10.15 | 390.5 | 758.35 | 0.41 | 1.11 |
13BS036h-2 | 75.66 | 240.53 | 34.51 | 157.91 | 44.99 | 13.6 | 44.75 | 9.25 | 71.73 | 17.71 | 65 | 13.21 | 116.2 | 16.76 | 563.6 | 921.81 | 0.92 | 1.15 |
13BS036h-3 | 73.05 | 203.95 | 27.01 | 109.59 | 34.89 | 22.11 | 37.8 | 8.32 | 63.8 | 15.32 | 57.49 | 11.98 | 109.05 | 15.56 | 496 | 789.92 | 1.85 | 1.12 |
13BS036h-4 | 78.79 | 449.6 | 98.41 | 601.16 | 233.67 | 7.3 | 228.63 | 37.11 | 203.45 | 35.09 | 82.35 | 10.24 | 61.41 | 7.28 | 884.3 | 2134.49 | 0.10 | 1.07 |
13BS036h-5 | 90.82 | 554.05 | 131.69 | 861.14 | 342.18 | 17.96 | 310.79 | 47.43 | 247.92 | 41.43 | 91.2 | 10.62 | 60.85 | 6.81 | 888.9 | 2814.89 | 0.17 | 1.02 |
13BS036h-6 | 315.6 | 881.85 | 136.93 | 500.45 | 103.42 | 7.54 | 87.82 | 18.91 | 137.76 | 31.08 | 99.09 | 16.96 | 126.77 | 16.32 | 872.3 | 2480.45 | 0.24 | 1.04 |
13BS036h-7 | 166.3 | 668.04 | 135.45 | 632.22 | 171.8 | 6.09 | 148.55 | 26.63 | 160.06 | 30.07 | 79.28 | 11.36 | 73.29 | 8.9 | 868.5 | 2318.05 | 0.11 | 1.03 |
13BS036h-8 | 95.2 | 509.07 | 103.88 | 578.5 | 199.2 | 6.93 | 191.51 | 32.76 | 187.76 | 33.68 | 81.82 | 10.67 | 66.7 | 7.88 | 884.3 | 2105.56 | 0.11 | 1.11 |
monzonitic granite | ||||||||||||||||||
13BS037h | 26.8 | 60.9 | 7.66 | 30.4 | 7.72 | 0.45 | 6.73 | 1.08 | 6.41 | 1.3 | 3.69 | 0.57 | 3.62 | 0.53 | 31.7 | 157.86 | 0.19 | 1.03 |
13BS038h | 40.5 | 81.9 | 10.1 | 41.8 | 10.9 | 0.81 | 9.92 | 1.6 | 10.1 | 2.11 | 5.88 | 0.91 | 5.77 | 0.82 | 55 | 223.12 | 0.23 | 0.97 |
13BS039h | 36.1 | 71.9 | 8.75 | 35.2 | 9.25 | 0.76 | 8.88 | 1.48 | 9.42 | 1.96 | 5.54 | 0.86 | 5.37 | 0.76 | 52.4 | 196.23 | 0.25 | 0.96 |
13BS040h | 41.7 | 88.1 | 10.8 | 43.6 | 12.3 | 0.65 | 11.7 | 1.92 | 11.5 | 2.28 | 6.16 | 0.91 | 5.55 | 0.78 | 59.6 | 237.95 | 0.16 | 0.99 |
13BS041h | 23 | 49.5 | 6.32 | 27.5 | 7.66 | 0.42 | 7.61 | 1.32 | 8.11 | 1.6 | 4.58 | 0.67 | 4.16 | 0.6 | 40.4 | 143.05 | 0.17 | 0.99 |
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Wang, G.; Li, X.; Zhang, D.; Yu, J.; Liu, Y. Genesis of the Yingzuihongshan Tungsten Deposit, Western Inner Mongolia Autonomous Region, North China: Constraints from In Situ Trace Elements Analyses of Scheelite. Minerals 2021, 11, 510. https://doi.org/10.3390/min11050510
Wang G, Li X, Zhang D, Yu J, Liu Y. Genesis of the Yingzuihongshan Tungsten Deposit, Western Inner Mongolia Autonomous Region, North China: Constraints from In Situ Trace Elements Analyses of Scheelite. Minerals. 2021; 11(5):510. https://doi.org/10.3390/min11050510
Chicago/Turabian StyleWang, Guoqiang, Xiangmin Li, Dongliang Zhang, Jiyuan Yu, and Yujie Liu. 2021. "Genesis of the Yingzuihongshan Tungsten Deposit, Western Inner Mongolia Autonomous Region, North China: Constraints from In Situ Trace Elements Analyses of Scheelite" Minerals 11, no. 5: 510. https://doi.org/10.3390/min11050510