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Open AccessArticle
Influence of Carbonated Pyrolysis Oil Recycled from Scrap Tires on Metallurgical Efficiency of Coal Flotation
by
Iman Hasanizadeh
Iman Hasanizadeh 1,
Hamid Khoshdast
Hamid Khoshdast 1,2,*,
Mehdi Safari
Mehdi Safari 3,4,*,
Kaveh Asgari
Kaveh Asgari 5 and
Ahmad Rahmanian
Ahmad Rahmanian 6
1
Department of Mining Engineering, Higher Education Complex of Zarand, Shahid Bahonar University of Kerman, Kerman 7761156391, Iran
2
Mineral Industries Research Center, Shahid Bahonar University of Kerman, Kerman 76169133, Iran
3
Minerals Processing Division, Mintek, Randburg 2125, South Africa
4
Faculty of Engineering and the Built Environment, University of the Witwatersrand, 1 Jan Smuts Ave., Johannesburg 2000, South Africa
5
Department of Mining Engineering, West Virginia University, Morgantown, WV 26505, USA
6
School of Chemical Engineering, The University of Queensland, Brisbane, QLD 4072, Australia
*
Authors to whom correspondence should be addressed.
Minerals 2024, 14(8), 765; https://doi.org/10.3390/min14080765 (registering DOI)
Submission received: 30 May 2024
/
Revised: 25 July 2024
/
Accepted: 26 July 2024
/
Published: 27 July 2024
Abstract
This research assesses the effect of carbonated pyrolysis oil (CPO) derived from scrap car tires on the metallurgical efficiency of coal flotation as a flotation additive. Using a statistical experimental design, the influence of various operational variables, including solid percent of feed pulp and dosages of reagents, i.e., CPO as an additive, diesel oil as a collector, and pine oil as a frother, on the ash content and yield of the final concentrate were investigated. Experimental data vary significantly based on operational conditions, ranging from 6.6% ash content with a 15% yield to 19.1% ash content with a 76.8% yield. The composition of the pyrolysis oil was identified by using Fourier transform infrared spectroscopy (FTIR). The analysis of variance (ANOVA) of experimental results demonstrated that almost all variables had a substantial effect on the flotation responses, positive or negative, depending on the variable or variable interaction. It was discovered that the usage of CPO intensified the total yield and ash content of concentrate in a nonlinear fashion in a range of 15% and 4%, respectively. The results revealed a non-selective interaction effect between CPO and pine oil, as well as competitive adsorption between diesel oil and CPO, which contributed to the curved behavior of flotation measurements. The detrimental effect of CPO on the flotation response of the studied coal sample was also related to the interaction of the hydrophilic groups in the CPO structure and the oxide groups of ash material in coal particles. This work shows the potential of carbonated pyrolysis oil to enhance coal flotation performance and sheds light on the underlying mechanisms.
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MDPI and ACS Style
Hasanizadeh, I.; Khoshdast, H.; Safari, M.; Asgari, K.; Rahmanian, A.
Influence of Carbonated Pyrolysis Oil Recycled from Scrap Tires on Metallurgical Efficiency of Coal Flotation. Minerals 2024, 14, 765.
https://doi.org/10.3390/min14080765
AMA Style
Hasanizadeh I, Khoshdast H, Safari M, Asgari K, Rahmanian A.
Influence of Carbonated Pyrolysis Oil Recycled from Scrap Tires on Metallurgical Efficiency of Coal Flotation. Minerals. 2024; 14(8):765.
https://doi.org/10.3390/min14080765
Chicago/Turabian Style
Hasanizadeh, Iman, Hamid Khoshdast, Mehdi Safari, Kaveh Asgari, and Ahmad Rahmanian.
2024. "Influence of Carbonated Pyrolysis Oil Recycled from Scrap Tires on Metallurgical Efficiency of Coal Flotation" Minerals 14, no. 8: 765.
https://doi.org/10.3390/min14080765
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