Mitigating Global Methane Emissions Using Metal-Organic Framework Adsorbents
Abstract
:1. Introduction
2. Materials and Methods
3. Results
MOF | VP (cm3 g−1) a | BET Surface Area (m2 g−1) | Lang. Surface Area (m2 g−1) | T (K) | P (bar) | Methane Uptake (mmol g−1) | Qst (kJ mol−1) | Ref. |
---|---|---|---|---|---|---|---|---|
UTSA-110a | 1.263 | 3241 | - | 273.15 | 1 | - | 14.5 | [56] |
HKUST-1 | 0.78 | 1850 | - | 298 | 1 | 1.0 c | 17 | [57] |
ATC-Cu | 0.23 | 600 | - | 298 | 1 | 2.8 c | 26.8 | [35] |
NU-1501-Al | - | 7310 | - | 270 | 1 | - | - | [58] |
Al-soc-MOF-1 | 2.3 | 5585 | - | 298 | 1 | 0.33 c | 10.5 | [59] |
PCN-14 | 0.85 | 2170 | - | 298 | 1 | - | 17.6 | [32] |
NJU-Bai 43 | 1.22 | 3090 | - | 298 | 1 | 0.20 c | 14.45 | [60] |
PCN-61 | 1.36 | 3000 | - | 298 | 1 | - | - | [44] |
MOF-950 | 1.3 | 3440 | - | 298 | 1 | 0.38 c | 11.9 | [61] |
NJU-Bai 42 | 1.07 | 2830 | - | 298 | 1 | 0.80 c | 14.49 | [60] |
Fe(bpd) | - | - | - | 298 | 1 | 0.1 c | - | [62] |
NU-135 | 1.02 | 2530 | - | 298 | 1 | 0.9 c | 16.6 | [63] |
NU-125 | 1.29 | 3120 | - | 298 | 1 | - | 15.5 | [64] |
ZJU-25 | 1.183 | 2124 | - | 300 | 1 | - | 15.1 | [64] |
MOF-519 | 0.938 | 2400 | - | 298 | 1 | 0.49 c | 14.6 | [65] |
MOF-5 | 1.4 | - | - | 298 | 1 | - | 12.3 | [66] |
NJU-Bai 19 | 1.063 | 2803 | - | 298 | 1 | 0.85 c | 14.8 | [67] |
Cu-tbo-MOF-5 | 0.595 | 3971 | - | 298 | 1 | 1.29 c | 20.4 | [68] |
MOF-905-Me2 | - | - | - | 298 | 1 | 0.47 b | - | [61] |
MOF-905 | 1.34 | 3490 | 3770 | 298 | 1 | 0.33 b | 11.7 | [61] |
MOF-905-Naph | 1.25 | 3310 | 3540 | 298 | 1 | 0.45 b | 11.3 | [61] |
MOF-905-NO2 | 1.29 | 3380 | 3600 | 298 | 1 | 0.403 b | 10.7 | [61] |
NJU-Bai-41 | 0.92 | 2370 | - | 298 | 1 | 0.969 c | 17.77 | [60] |
Al4(OH)8(btec) MIL-120 | 0.11 | 308 | 432 | 303 | 10 | 1.7 d | 27 | [69] |
Cu2(tdm) [PCN-26] | 0.84 | 1854 | 2545 | 298 | 1.07 | 1.1 d | - | [70] |
Cu2(ebtc) | - | 1852 | 2844 | 273 | 1 | 0.6 c | - | [71] |
Mg(tcpda) [SNU-25] | 0.368 | 795 | - | 298 | 1.01 | 0.4 c | - | [72] |
Zn(Pur)2 [ZIF-20] | 0.27 | - | 800 | 273 | 1.01 | 0.7 b | - | [73] |
Zn(bIm)(nIm) [ZIF-68] | - | - | 1090 | 298 | 1.01 | 0.4 b | - | [74] |
Zn(cbIm)(nIm) [ZIF-69] | - | - | 950 | 298 | 1.01 | 0.6 b | - | [74] |
Zn(Im)1.13(nIm)0.87 [ZIF-70] | - | - | 1730 | 298 | 1.01 | 0.4 b | - | [74] |
Zn(nbIm)(nIm) [ZIF-78] | - | - | 620 | 298 | 1.01 | 0.6 b | - | [74] |
Zn(mbIm)(nIm) [ZIF-79] | - | - | 810 | 298 | 1.01 | 0.5 b | - | [74] |
Zn(bbIm)(nIm) [ZIF-81] | - | - | 760 | 298 | 1.1 | 0.5 b | - | [74] |
Zn(cnIm)(nIm) [ZIF-82] | - | - | 1300 | 298 | 1.01 | 0.5 b | - | [74] |
[H2O][Zn7(μ3-OH)3(bbs)6] | 0.24 | - | 649 | 273 | 1.01 | 0.6 d | - | [75] |
Co3(2,4-pdc)2(μ3-OH)2 [CUK-1] | 0.26 | 630 | - | 298 | 1.01 | 0.4 d | - | [76] |
Mn(2,6-ndc) | 0.068 | - | 191 | 273 | 1.01 | 0.8 d | - | [77] |
Cu(tip) | 0.34 | 810 | 1063 | 298 | 1.01 | 1.0 d | - | [78] |
Cu(bdc-OH) | 0.214 | - | 584 | 296 | 1.01 | 0.6 d | 18.5 | [79] |
Zn5(bta)6(tda)2 | 0.24 | 414 | 607 | 295 | 1.01 | 0.4 d | - | [80] |
Zn4(OH)2(1,2,4-btc) | 0.205 | 408 | 607 | 295 | 1.01 | 0.4 d | - | [81] |
Co3(ndc)(HCOO)3(μ3-OH) | 0.58 | 1386 | 1434 | 298 | 1 | 0.7 d | 19.4 | [82] |
Adsorbent | VP (cm3 g−1) a | BET Surface Area (m2 g−1) | Methane Uptake (mmol g−1) | T (K) | P (bar) | Qst (kJ mol−1) | Ref. |
---|---|---|---|---|---|---|---|
Carbonaceous materials | |||||||
MW-CNTs@JUC32-2 | - | 146 | 0.75 c | 273 | 1 | 23.9 | [83] |
KUA51751 | 1.48 | 3350 | 1.34 c | 298 | 1 | - | [84] |
KUB41701 | 0.92 | 2123 | 1.32 c | 298 | 1 | - | [84] |
Maxsorb-A | 1.38 | 3100 | 1.28 c | 298 | 1 | - | [84] |
FELT 1 | 0.81 | 1741 | 1.34 c | 298 | 1 | - | [84] |
LFC14 | 0.23 | 520 | 1.15 c | 298 | 1 | - | [84] |
LFC30 | 0.41 | 930 | 1.22 c | 298 | 1 | - | [84] |
CFC19 | 0.32 | 647 | 1.05 | 298 | 1 | - | [84] |
CFC54 | 0.84 | 1859 | 1.09 | 298 | 1 | - | [84] |
CFC74 | 0.92 | 2862 | 1.15 | 298 | 1 | - | [84] |
Zeolites | |||||||
NaX | 0.220 | 534 | 0.65 c | 303 | 1 | 20.1 | [55] |
NaA | - | 473 | 0.65 c | 303 | 1 | - | [55] |
CaA | 0.150 | 440 | 0.59 c | 303 | 1 | 29.0 | [55] |
Polymers | |||||||
p-Dichloroxylene (p-DCX) | 0.36 | 1307 | 0.73 c | 298 | 1 | 20.8 | [54] |
BCMBP/p-DCX | 0.54 | 1904 | 0.72 c | 298 | 1 | - | [54] |
4. Discussion
Enhancing Volumetric Energy Density and Cyclability in MOFs for Global Methane Emissions Mitigation
5. Conclusions
Funding
Conflicts of Interest
References
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Framework | Largest Cavity Diameter (Å) | Void Fraction of Accessible Probe-Occupiable Pore Volume | Ref. |
---|---|---|---|
HKUST-1 | 13.14982 | 0.67 | [57] |
DUT-13 | 18.4908 | 0.81 | [85] |
NU-125 | 19.37323 | 0.73 | [64] |
PCN-46 | 12.05622 | 0.72 | [87] |
PCN-61 | 18.70668 | 0.75 | [44] |
SNU-30 | 14.9209 | 0.83 | [88] |
UTSA-20 | 9.95246 | 0.57 | [40] |
Framework | −∆Hads (kJ/mol) | −∆Sads (J/mol K) | Ref. |
---|---|---|---|
HKUST-1 | 15.2 | 61.7 | [32] |
Ni-MOF-74 | 20.7 | 77.7 | [32] |
UTSA-20 | 17.8 | 72.3 | [32] |
PCN-14 | 11.4 | 47.39 | [32] |
NJU-Bai-41 | 16.1 | 54.2 | [60] |
MOF-905-Naph | 10.87 | 36.7 | [61] |
MOF-905-NO2 | 9.86 | 33.2 | [61] |
MFM-300 (In) | 16.49 | 55.66 | [89] |
ATC-Cu | 23.6 | 90.2 | [35] |
MOF-520 | 14.0 | 47.1 | [65] |
Al-soc-MOF-1 | 15.3 | 51.2 | [59] |
MOF-519 | 14.1 | 47.2 | [65] |
ZIF-68 | 16.7 | 61.2 | [74] |
ZIF-69 | 18.4 | 61.8 | [74] |
Cu-tbo-MOF-5 | 21.6 | 71.8 | [68] |
NJU-Bai-19 | 14.7 | 49.4 | [67] |
NJU-Bai-42 | 12.8 | 46.9 | [60] |
NJU-Bai-41 | 14.4 | 48.3 | [60] |
MOF-950 | 11.3 | 38.1 | [61] |
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Mahmoud, E. Mitigating Global Methane Emissions Using Metal-Organic Framework Adsorbents. Appl. Sci. 2020, 10, 7733. https://doi.org/10.3390/app10217733
Mahmoud E. Mitigating Global Methane Emissions Using Metal-Organic Framework Adsorbents. Applied Sciences. 2020; 10(21):7733. https://doi.org/10.3390/app10217733
Chicago/Turabian StyleMahmoud, Eyas. 2020. "Mitigating Global Methane Emissions Using Metal-Organic Framework Adsorbents" Applied Sciences 10, no. 21: 7733. https://doi.org/10.3390/app10217733