Effect of the Organic Matter Content on the Mechanical Properties of Soils Stabilized with Xanthan Gum
Abstract
:1. Introduction
- (i)
- (ii)
- (iii)
- (iv)
- Some one-dimensional compression tests with a bentonite and a kaolinite stabilized with XG show a decrease in the compressibility after the stabilization with xanthan gum [31]. However, it should be emphasized that not all the results published are consistent with each other; indeed, results of a soft marine soil [30], kaolinite clay [35], sandy soil [23], and silt sand [29] show an increase in the compressibility after stabilization with XG. In terms of the coefficient of consolidation (Cv), results of the treatment of a marine soft soil [30], high plastic soil [36], and kaolinite clay [35] with XG promotes a significant reduction in the Cv; i.e., the stabilization with XG prolongs the time required to the end of the primary consolidation. Additionally, the coefficient of secondary compression of a kaolinite clay increases after the stabilization with xanthan gum [35];
- (v)
- (vi)
- (vii)
- Increases the undrained shear strength of a kaolinite clay, but decreases the undrained shear strength of a montmorillonite clay [38];
- (viii)
- Decreases the cumulative variation in moisture loss and mass loss in freeze–thaw tests [36];
- (ix)
- Decreases the swelling potential of a high plastic soil [36].
2. Materials and Methods
2.1. Characteristics of the Soils
2.2. Characteristiques of the Biopolymer (Xanthan Gum)
2.3. Specimen Preparation and Testing
- (i)
- This soil subjected to loss-on-ignition at 400 °C (with an OM content of 1.5%) was mixed with the “natural” soil (OM = 7.7%) in different amounts to obtain the samples of artificial soil with the desired OM content, between 1.5% (lower OM) and 7.7% (natural OM). Naturally, the process of adjustment of the OM content had some iterations, with the re-evaluation and eventual re-adjustment of the OM content;
- (ii)
- In the case of the stabilized samples, an XG content of 1% (ratio of the dry weight of XG to the dry weight of the soil) in powder form was added to the dry artificial soil and mixed well;
- (iii)
- The artificial soil (with the required OM content), with or without XG, was mixed with the distilled water, to obtain a liquidity index of 1.1, during the time necessary to obtain a homogeneous soil-water-XG paste;
- (iv)
- The mixture was introduced into the UCS molds (38 mm in diameter, 76 mm height) and oedometer molds (70 mm in diameter, 19 mm height) in 3 layers and 1 layer, respectively;
- (v)
- Each layer was subjected to tapping (10 times) to remove air bubbles and compacted with 100 kPa for 10 s;
- (vi)
- A superficial scarification of the previous layer was performed to improve the connection between two successive layers in the molds;
- (vii)
- Based on the results of Venda Oliveira and Cabral [29], the stabilized specimens were stored in a plastic bag during 14 days of curing time (only stabilized specimens) inside a room with controlled temperature (20 ± 2 °C) and humidity (95 ± 5%), in order to reduce the suction phenomenon. The unstabilized specimens were not submitted to a curing time;
- (viii)
- After that, the specimens were removed from the molds, both surfaces were trimmed and the quality of the samples was analyzed visually;
- (ix)
- The specimens with the required quality were accepted for testing (UCS and oedometer tests);
- (x)
- The oedometer ring (polished stainless steel) was coated with a thin film of grease prior to the oedometer tests to minimize the friction between it and the soil;
- (xi)
- The oedometer ring was assembled with the specimen, and they were saturated by immersion;
- (xii)
- The displacement transducers (both tests) and the load cell (UCS tests) were set up and adjusted;
- (xiii)
- The UCS and oedometer tests were carried out. The vertical displacement (both tests) and the vertical pressure (UCS test) were recorded by an automatic data acquisition system;
- (xiv)
- A strain controlled test was used in the UCS tests under a strain rate of 1%/min (ASTM2166-05);
- (xv)
- In accordance with ASTM D2435-04, stress increments with a load ratio of 2 were applied in the loading path of the oedometer tests, while in the unloading path a load ratio of 4 was used during the time required to the end of the primary consolidation. The coefficient of consolidation (Cv) was evaluated using Casagrande’s methodology.
3. Results and Discussion
3.1. UCS Tests
3.2. Oedometer Tests
- (i)
- a progressive increase in the compressibility with the increase in the vertical stress.
- (ii)
- The increase in the void ratio with the OM content, which agrees with the findings of Venda Oliveira et al. [48].
- (iii)
- The upward movement of the e-logσ’v curves after the stabilization with XG due to the hydration of the biopolymer’s hydrogels, which induces an increase in the void ratio; this tendency matches with the results of Venda Oliveira et al. [29].
4. Main Conclusions
- (i)
- For an OM content in the range of 1.5–5.5%, there is a positive impact resulting from the stabilization with XG on the mechanical properties, with a significant increase in strength (from 130% to 270%) and stiffness (from 109% to 204%). Moreover, the stabilization with XG induces a decrease in the ductility of the stress-strain behavior characterized by a loss of strength after the peak;
- (ii)
- There is a detrimental impact of the stabilization with XG in terms of mechanical properties for an OM content of 7.7%, while the stress-strain behavior remains ductile. These results seem to indicate that this OM content is sufficient to coat the soil particles, which prevents bonds (i.e., a micro-reinforcement network) being established between the soil particles and the XG, and simultaneously the hydration of the biopolymer hydrogels tends to minimize the friction between the soil particles;
- (iii)
- The stabilization of the soil with XG induces an increase in the initial void ratio; this effect is enhanced by the increase in the OM content, which reflects the effect of two cumulative factors, the ability of the organic matter to retain water, and the hydration of the hydrogels of the XG in the presence of water;
- (iv)
- The stabilization with XG increases the change in the void ratio both in compression (i.e., Cc) and swelling (i.e., Cs), with more significant effects in terms of compression; this behavior is amplified with the increase in the OM content;
- (v)
- In compression, the increase in the OM content induces an increase in the change in the void ratio (i.e., the Cc). The void ratio variation (and the Cs) is negligible for the swelling relative to the change in OM content;
- (vi)
- The coefficient of consolidation (Cv) of the unstabilized soil decreases with the increase in OM content, which is due to the significant ability of the OM to absorb water;
- (vii)
- The stabilization process induces a significant decrease in the Cv, which is related to the considerable capacity of the biopolymers to retain water, due to the hydration of the hydrogels.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Organic Matter Content (%) | Xanthan Gum Content (%) | Curing Time (Days) | UCS Tests (N) | Oedometer Tests (N) |
---|---|---|---|---|
1.5 | 0.0 1 | --- | 3 | 2 |
1.0 2 | 14 | 3 | 2 | |
2.4 | 0.0 1 | --- | 3 | 2 |
1.0 2 | 14 | 3 | 2 | |
4.1 | 0.0 1 | --- | 3 | 2 |
1.0 2 | 14 | 3 | 2 | |
5.5 | 0.0 1 | --- | 3 | 2 |
1.0 2 | 14 | 3 | 2 | |
7.7 | 0.0 1 | --- | 3 | 2 |
1.0 2 | 14 | 3 | 2 |
Property | Organic Matter Content (%) | ||||
---|---|---|---|---|---|
1.5 | 2.4 | 4.1 | 5.5 | 7.7 1 | |
Grain size distribution: | |||||
Clay (%) | 23 | 23 | 23 | 23 | 23 |
Silt (%) | 57 | 57 | 57 | 57 | 57 |
Sand (%) | 20 | 20 | 20 | 20 | 20 |
Specific gravity, G | -- | -- | -- | -- | 2.32 |
Liquid limit, wL (%) | 36.3 | 40.9 | 46.6 | 54.1 | 71.0 |
Plastic limit, wP (%) | 15.3 | 33.1 | 33.2 | 33.0 | 44.3 |
Plasticity index, PI (%) | 21.0 | 7.8 | 13.4 | 21.1 | 26.7 |
Liquidity index | 1.09 | 1.09 | 1.09 | 1.09 | 1.09 |
Soil classification, USCS 2 | CL | CL | OL | OH | OH |
Chemical composition | |||||
pH (BSI337-3) | -- | -- | -- | -- | 3.6 |
SiO2 (%) | -- | -- | -- | -- | 62 |
Al2O3 (%) | -- | -- | -- | -- | 16 |
Fe2O3 (%) | -- | -- | -- | -- | 4.8 |
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Oliveira, P.J.V.; Reis, M.J.F.C.C. Effect of the Organic Matter Content on the Mechanical Properties of Soils Stabilized with Xanthan Gum. Appl. Sci. 2023, 13, 4787. https://doi.org/10.3390/app13084787
Oliveira PJV, Reis MJFCC. Effect of the Organic Matter Content on the Mechanical Properties of Soils Stabilized with Xanthan Gum. Applied Sciences. 2023; 13(8):4787. https://doi.org/10.3390/app13084787
Chicago/Turabian StyleOliveira, Paulo J. Venda, and Maria J. F. C. C. Reis. 2023. "Effect of the Organic Matter Content on the Mechanical Properties of Soils Stabilized with Xanthan Gum" Applied Sciences 13, no. 8: 4787. https://doi.org/10.3390/app13084787
APA StyleOliveira, P. J. V., & Reis, M. J. F. C. C. (2023). Effect of the Organic Matter Content on the Mechanical Properties of Soils Stabilized with Xanthan Gum. Applied Sciences, 13(8), 4787. https://doi.org/10.3390/app13084787