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Article

Composite Copolymer Beads Incorporating Red Mud for Water Amendment by Adsorption—Oxidation Processes

by
Teodor Sandu
1,
Elena Alina Olaru
2,
Raul-Augustin Mitran
3,
Andreea Miron
1,
Sorin-Viorel Dolana
1,
Anamaria Zaharia
1,
Ana-Mihaela Gavrilă
1,
Marinela-Victoria Dumitru
1,
Anita-Laura Chiriac
1,
Andrei Sârbu
1,* and
Tanța-Verona Iordache
1,*
1
National Institute for Research and Development in Chemistry and Petrochemistry—ICECHIM, Splaiul Independenței 202, 6th District, 060021 Bucharest, Romania
2
PROTMED Research Centre, University of Bucharest, Splaiul Independenței 91-95, 5th District, 050107 Bucharest, Romania
3
Ilie Murgulescu Institute of Physical Chemistry, Splaiul Independenței 202, 6th District, 060021 Bucharest, Romania
*
Authors to whom correspondence should be addressed.
Appl. Sci. 2024, 14(14), 6386; https://doi.org/10.3390/app14146386 (registering DOI)
Submission received: 14 June 2024 / Revised: 8 July 2024 / Accepted: 19 July 2024 / Published: 22 July 2024
(This article belongs to the Special Issue Pollution Control Chemistry II)

Abstract

We face significant environmental pollution problems due to various industries, such as the aluminum industry, which generates large amounts of red mud (RM) waste, or agriculture, in which case the use of pesticides creates huge water pollution problems. In this context, the present study offers a better perspective to originally solve both environmental issues. Thus, the main target of the study referred to using RM waste as a filler for preparing composite copolymer beads. Thereafter, this can achieve significant removal of water pollutants due to their adsorption/oxidation characteristics. As evidenced by the changes in chemical structure and composition, thermal stability, morphology, and porosity, RM was homogenously incorporated in poly(acrylonitrile-co-acrylic acid) beads prepared by wet phase inversion. The final assessment for the removal of pesticides by adsorption and oxidation processes was proven successful. In this regard, 2,4-dichlorophenoxyacetic acid was chosen as a model pollutant, for which an adsorption capacity of 16.08 mg/g composite beads was achieved.
Keywords: composite copolymer beads; red mud; 2,4-dichlorophenoxyacetic acid; water amendment; adsorption; oxidation composite copolymer beads; red mud; 2,4-dichlorophenoxyacetic acid; water amendment; adsorption; oxidation

Share and Cite

MDPI and ACS Style

Sandu, T.; Olaru, E.A.; Mitran, R.-A.; Miron, A.; Dolana, S.-V.; Zaharia, A.; Gavrilă, A.-M.; Dumitru, M.-V.; Chiriac, A.-L.; Sârbu, A.; et al. Composite Copolymer Beads Incorporating Red Mud for Water Amendment by Adsorption—Oxidation Processes. Appl. Sci. 2024, 14, 6386. https://doi.org/10.3390/app14146386

AMA Style

Sandu T, Olaru EA, Mitran R-A, Miron A, Dolana S-V, Zaharia A, Gavrilă A-M, Dumitru M-V, Chiriac A-L, Sârbu A, et al. Composite Copolymer Beads Incorporating Red Mud for Water Amendment by Adsorption—Oxidation Processes. Applied Sciences. 2024; 14(14):6386. https://doi.org/10.3390/app14146386

Chicago/Turabian Style

Sandu, Teodor, Elena Alina Olaru, Raul-Augustin Mitran, Andreea Miron, Sorin-Viorel Dolana, Anamaria Zaharia, Ana-Mihaela Gavrilă, Marinela-Victoria Dumitru, Anita-Laura Chiriac, Andrei Sârbu, and et al. 2024. "Composite Copolymer Beads Incorporating Red Mud for Water Amendment by Adsorption—Oxidation Processes" Applied Sciences 14, no. 14: 6386. https://doi.org/10.3390/app14146386

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