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Article

Comparison of Battery Electrical Vehicles and Internal Combustion Engine Vehicles–Greenhouse Gas Emission Life Cycle Assessment

1
CIDEM, ISEP, Polytechnic of Porto, Rua Dr. António Bernardino de Almeida, 4249-015 Porto, Portugal
2
INEGI—Instituto de Ciência e Inovação em Engenharia Mecânica e Engenharia Industrial, 4200-465 Porto, Portugal
3
ProMetheus—Escola Superior de Tecnologia e Gestão, Instituto Politécnico de Viana do Castelo, Rua Escola Industrial e Comercial de Nun’Álvares, 4900-347 Viana do Castelo, Portugal
*
Author to whom correspondence should be addressed.
Appl. Sci. 2025, 15(6), 3122; https://doi.org/10.3390/app15063122
Submission received: 28 November 2024 / Revised: 7 March 2025 / Accepted: 11 March 2025 / Published: 13 March 2025
(This article belongs to the Special Issue Recent Developments in Electric Vehicles)

Abstract

:
Battery electrical vehicle (BEV) ownership has increased in recent years. There is a general concern over the life cycle of the batteries used in such vehicles. This study provides a comprehensive overview of electric vehicles, encompassing their technical evolution, autonomy, and ownership. The analysis delved into the various types of batteries utilized in these vehicles, examining the composition of their constituent materials and the mechanisms underlying their operation. Additionally, it assessed their performance in terms of energy density storage, recharge capabilities, autonomy, and prospects. A critical evaluation of electric vehicles and their internal combustion engine vehicle (ICEV) counterparts, considering the Life Cycle Assessment (LCA) criterion, was conducted. The LCA criterion encompasses emissions during the entire lifecycle, from the “cradle” to the “tank” (WTT) and the “tank” until the end of its cycle (TTW). The findings of this study indicate that BEVs consistently outperformed ICEVs in terms of greenhouse gas (GHG) emissions in all the sizes of vehicles studied.

1. Introduction

1.1. Autonomy

Electric vehicles are a pioneering technology for combustion engines, which date back to 1876 when Nicolau Otto built the first internal combustion engine [1]. While ICEs obtain their energy from the combustion of petrol or diesel, BEVs obtain energy directly from a large set of batteries. Figure 1 shows the evolution of the autonomy of BEVs from 2011 to the present; due to technical improvements, the autonomy of BEVs has noticeably increased [2].
Despite technological advances, most contemporary battery systems have significantly lower specific energies than liquid fuels, which often limits the maximum autonomy of these electric vehicles. Lithium-ion and lithium-polymer batteries are the most common types used in modern electric vehicles due to their favorable energy density-to-weight ratio [3].

1.2. Batteries

The batteries in BEVs differ from starting, lighting, and ignition batteries in that they are designed as deep cycle batteries intended to provide power for extended periods. These batteries are characterized by their relatively high power/weight ratio, specific energy, and energy density.
Table 1 presents a comparative analysis of the main characteristics of different batteries based on data from several authors [4,5,6]. The battery emissions referred to in this table include emissions from the extraction of the materials that make up the battery up to its assembly in the vehicle.
Current electric vehicle technologies are predominantly based on lithium-ion batteries due to their superior performance. Such batteries account for 85.6% of the energy storage systems used in the global market in 2015; despite being the most expensive, they have the lowest cost per cycle [9]. Electric vehicles require a battery system that is made up of hundreds or thousands of individual cells grouped to provide the necessary voltage, power, and energy.
Although lithium-ion batteries have a greater environmental impact during production due to material extraction and processing, ongoing advancements and recycling efforts are mitigating their global carbon footprint, and solid-state batteries have the potential to further reduce emissions, although they are not yet commercially viable [10,11].
In 2020, the highest gravimetric energy density for lithium-ion cells was 304 Wh/kg using NMC 811 cathodes [12]. Recent developments include 400 Wh/kg cells with nickel-rich cathodes and 720 Wh/kg cells with LiCoMnO4 cathodes [13]. The EU and Asia aim to produce batteries with a gravimetric energy density of more than 400 Wh/kg by 2030 [12,13]. Innovations in battery packaging, such as CTP designs, can also improve performance.
The prices of lithium-ion batteries have been reduced from USD 1200 to 132 per kWh of battery. This reduction is mainly due to advances in battery technology and manufacturing efficiency.
Table 2 and Table 3 show the amount of emissions for each kWh battery produced in different countries, the actual values in 2023, and forecasts for 2030. Sweden, with its low emissions, serves as a model for sustainable production.
The total CO2e emission of 97 kgCO2e/kWh shown in Table 2 is a weighted average that was calculated considering the battery-manufacturing countries. The weight given to each country for the calculation of that average is directly related to the number of batteries produced in that country. Therefore, the value shown is closer to the Chinese value than to the Swedish value.

1.3. Electric Car Ownership

BEVs are an important part of achieving global climate change goals. Figure 2 shows the market share of new vehicle registrations in the 27 EU countries, by type of energy, in 2023.
Achieving the European Union’s target of around 35% of sales of new zero- or low-emission tourism vehicles by 2030 will have a significant impact on the entire EV value chain and ecosystem, considering that in 2023 such sales were around 23% (including BEVs and plug-in hybrids). Of note is Norway, where an EV market share of up to 95% is projected to be within reach by 2024. According to statistics from the Norwegian EV Association [16], Norway will experience another year of record electric vehicle sales in 2023, with a market share of 82.4%.
Figure 3 shows the evolution of electric vehicle ownership in some regions of the world from 2013 to 2023.

1.4. EU Climate Goals

Table 4 lists the GHG emission objectives of the EU. The adoption of EVs is due to a combination of political, economic, environmental, and technological factors. Politically, stringent environmental objectives such as the Kyoto Protocol, the EU’s 2020 Climate and Energy Package, the Paris Agreement, the European Green Deal, and the EU’s “Fit for 55” Package, all include reductions in GHG emissions, promoting EV adoption [18,19,20]. Financial subsidies and tax breaks also make EVs more affordable, stimulating market growth in countries such as Norway, Germany, and China.
The EU’s strategic plan includes achieving a 100% zero-emission vehicle fleet in urban areas by 2050 [5].
Beyond 2030, the disparity between the objectives and the expected impact of current and planned measures is pronounced. Considering the measures that have been adopted and those that are currently planned, net emissions are expected to be reduced by 60% compared to 1990 levels by 2040 and reduced by 64% by 2050 [21].
Figure 4 shows the carbon intensity of electricity production in some countries from 1990 to 2030. Sweden has emerged as a hub for future big factories, with the intention of increasing the European battery production capacity and reducing the dependence on non-EU sources [22].
Of the EU countries, as shown in Figure 4, Portugal is the only one that, in 2023, was already below the target to be achieved by 2030, corresponding to a 55% (see Table 4) reduction in the 1990 emission level. So, in this case, it makes sense to review, for Portugal, the targets proposed for GHG emissions presented in Table 4. It must be noted that the low GHG emissions in France are due to nuclear energy, due to renewable energy, namely hydraulic energy, in Norway, while in Sweden, they are due to both nuclear energy and renewable energy.

2. Method for Comparing ICEVs and BEVs—Life Cycle Assessments (LCAs)

Understanding the lifecycle emissions of different vehicle types is essential for assessing their environmental impact and guiding consumer policy and choice. Life Cycle Assessments (LCAs) provide a comprehensive assessment covering raw material extraction, vehicle manufacturing, energy production, and end-of-life processes, including recycling and reuse. It provides a comprehensive comparison of the environmental impacts of BEVs and ICEVs and identifies critical areas for environmental improvement throughout the vehicle life cycle. This comprehensive approach uses metric tonnes of CO2e as the standardized unit, considering several greenhouse gases and their global warming potential [24].
The BEV production phase is around 40% more intensive in terms of emissions than that of hybrid and ICE vehicles [25]. This disparity is mainly due to the extraction and refining of raw materials such as lithium, cobalt, and nickel, which are essential for battery production, and the energy-intensive manufacturing processes involved [25]. These factors significantly contribute to the higher production emissions associated with BEVs [26]. However, by 2050, these BEV production emissions are expected to be only marginally higher than those of conventional vehicles. Batteries are responsible for around 60% of the GHG emissions from the production of electric vehicles [14].
This paper presents a Life Cycle Assessment (LCA) methodology, along with the framework, boundaries, limitations, assumptions, and rationale behind it. It provides key findings from each stage of the life cycle phase, highlights the method’s sensitivity to assumptions, and concludes with recommendations. The study examined a range of vehicle configurations, including traditional internal combustion engines and electrified powertrains, assessing their environmental performance under current and future market scenarios. The study also assessed the environmental footprint of BEVs and ICE vehicles over their entire life cycle, from raw material extraction to end-of-life processes. It identified the critical factors influencing emissions and the conditions under which BEVs become environmentally advantageous. The key objectives included the following:
Comparing the total life cycle emissions for BEVs and ICE vehicles;
Evaluating the impact of energy sources and battery production on GHG emissions;
Assessing the role of recycling and maintenance in emission reductions.
The scope focused on light-duty passenger vehicles of various sizes (small, medium, and large) and using different energy sources (petrol, diesel, and electricity), considering regional variations in electricity production and battery manufacturing. This research followed the ISO 14040 standard’s four-step process, as shown in Figure 5.
Step 1. Goal and Scope Definition.
  • Establish clear objectives for comparing BEVs and ICE vehicles.
  • Define boundaries to include vehicle production, energy production, use phase, maintenance, and end-of-life processes.
  • Document assumptions, such as energy grid compositions and vehicle lifespans, ensuring that they are transparent and aligned with the study’s objectives.
Step 2. Life Cycle Inventory (LCI). Compile raw material, energy input, emission, and by-product data across all phases.
  • Production Phase: includes emissions from vehicle manufacturing (excluding and including battery production) and battery production (varying by country and battery chemistry).
  • Use Phase: combines Well-to-Wheel (WTW) emissions including WTT (Well-to-Tank; emissions from fuel extraction, refining, and transportation) and TTW (Tank-to-Wheel; combustion or electricity use during operation).
  • End-of-Life Phase: covers emissions from recycling, disposal, and remanufacturing.
Step 3. Impact Assessment. Quantify GHG emissions using CO2 equivalents (tCO2e) for the key phases:
  • Production, differentiating BEVs and ICE vehicles by material intensity.
  • Operation, analyzing energy losses in electricity generation, distribution, and use.
  • End of life, evaluating emissions savings from advanced recycling technologies.
  • Region-specific energy mix emission data were applied to refine the calculations.
Step 4. Interpretation and Sensitivity Analysis.
  • Analyze results to identify the critical phases and factors influencing emissions.
  • Evaluate scenarios under varying assumptions, such as grid decarbonization or advances in battery production and recycling.
WTT refers to the processes required to convert crude oil from the wells at the fuel depot into usable petrol or diesel fuel, and TTW refers to combustion in the engine, as shown in Figure 6. This terminology has also been adopted for BEVs, with WTT referring to all impacts of electricity generation that occur prior to vehicle charging, and TTW referring to the direct impacts of driving the vehicle [5].
The transition to electric vehicles has spurred interest in understanding their environmental impacts compared to conventional ICE vehicles. This study employed a Python 3.10.14-based model to conduct a comprehensive LCA of GHG emissions for BEVs and ICE vehicles (see Appendix A). The model’s results provided insights into the relative emissions performance of these vehicles under various scenarios, serving as a decision-making tool for policymakers and researchers.
The input data were (i) emissions due to vehicle production, excluding the battery, from Table 5; (ii) emissions associated with the maintenance of either ICEs or BEVs per km, with values of 8.34 × 10−6 and 4.17 × 10−6 tCO2e/km, respectively; (iii) direct CO2e emissions per km resulting from the combustion of petrol or diesel in ICEVs, using the average values in Table 7; (iv) emissions associated with the extraction/refining/transportation of fuel from Table 7; and (v) CO2e emissions per kWh of electricity generated, varying by country, from Table 8; (vi) emission intensity during the manufacture of batteries from Table 3; (vii) end-of-life emissions from Table 9. Additional parameters such as vehicle size, fuel type, and battery manufacturing location further defined the scenarios analyzed.
The outputs after comparing the emissions for each scenario are displayed, and the code prints the scenarios where BEVs become more environmentally friendly than ICE vehicles. The results include the vehicle size, fuel type, country, battery production location, the distance at which BEVs become greener, and the emissions for both vehicles at that distance. Finally, the code also calculates and shows the total emissions after 240,000 km (this mileage was used in [24,28,29]) for each scenario.
The initial emissions are a significant factor in the overall Life Cycle Assessment, highlighting the initial environmental cost of BEVs compared to ICEVs (see Table 5).
Table 5. Emissions from vehicle production, excluding battery production and depending on vehicle dimensions (adapted from [25]).
Table 5. Emissions from vehicle production, excluding battery production and depending on vehicle dimensions (adapted from [25]).
BEVsICEVs-PetrolICEVs-Diesel
SmallMediumLargeSmallMediumLargeSmallMediumLarge
tCO2e/vehicle5.06.07.05.56.77.85.87.08.2
The intensity of emissions from battery production depends on the country where this manufacturing takes place and the type of battery used (see Table 3). For example, battery production in Sweden is associated with relatively low emissions of 45 kg CO2e/kWh, while in countries such as China, the emissions range between 79 and 108 kg CO2e/kWh, depending on the specific battery chemistry. Notably, the higher values are based on battery types that do not contain nickel, while others with higher nickel content generally have lower emissions. As mentioned above, the average global emissions amount to 97 kg CO2e/kWh, highlighting variability based on geography and material composition.
The average vehicle’s fuel and energy consumption values vary according to the size of the vehicle (small, medium, or large), influencing the operational emissions throughout the vehicle’s useful life (see Table 6).
Table 6. The average vehicle’s fuel and energy consumption values (adapted from [30]).
Table 6. The average vehicle’s fuel and energy consumption values (adapted from [30]).
Size of VehicleICEVs-Petrol (L/100 km)ICEVs-Diesel (L/100 km)BEVs (kWh/100 km)Battery Capacity of BEVs (kWh)
Small6.55.416.045.0
Medium7.56.217.560.0
Large8.86.719.075.0
The ICE operational emissions were derived from both the production and combustion of the fuel. Together, the WTT and TTW emissions form the WTW emissions. Table 7 provides these values for Europe.
Table 7. WTT and TTW GHG emissions in Europe from petrol and diesel (adapted from [30]).
Table 7. WTT and TTW GHG emissions in Europe from petrol and diesel (adapted from [30]).
FuelWTT (gCO2e/L)TTW (gCO2e/L)WTW (gCO2e/L)
Petrol68022402920
Diesel98024403420
The emissions per kWh from electricity production vary significantly from country to country, reflecting differences in the energy sources used in the electricity mix (see Table 8). Countries with a greater dependence on fossil fuels for electricity production will have higher emissions per kWh, while those using more renewable energy will have lower emissions.
Table 8. Emissions in grams of CO2eq for every kWh of electricity produced in different countries in 2023 (adapted from [23]).
Table 8. Emissions in grams of CO2eq for every kWh of electricity produced in different countries in 2023 (adapted from [23]).
Emissions [gCO2e/kWh]PortugalUSAChinaNorwayPolandSwedenEU 27France
166369582306624122956
The emissions from electricity consumption during vehicle operation were adjusted for charging inefficiencies. To reflect real-world conditions, the energy drawn from the grid was adjusted by a factor of 1/0.857 (approximately 1.167) because only 85.7% of the grid electricity is efficiently stored in the vehicle’s battery. This adjustment ensures that the total emission calculation reflects the grid electricity consumed, not just the net battery energy. In fact, during the process of charging a BEV, in 95% of the energy inflow at home (95%, not 100% due to WTT losses), there is a loss of 5% of the 95%, resulting in 90.25%, and the AC/DC inversion causes a loss of an addition 5% of the 90.25%; thus, the battery charging efficiency is 85.7% [30].
Maintenance emissions represent the GHG emissions produced during vehicle maintenance throughout its lifetime. These values reflect the lower maintenance requirements of BEVs, around 4.17 g of CO2 equivalent per km, as they have fewer moving parts and typically require less frequent maintenance compared to ICE-powered vehicles (around 8.34 g of CO2 equivalent per km) [24].
Recycling a BEV at the end of its useful life can reduce its total carbon footprint. The end-of-life emissions, expressed in tonnes of CO2e, are shown in Table 9.
Table 9. End-of-life emissions depending on vehicle dimensions (adapted from [24]).
Table 9. End-of-life emissions depending on vehicle dimensions (adapted from [24]).
Type of VehicleBEVsICEVs-PetrolICEVs-Diesel
SmallMediumLargeSmallMediumLargeSmallMediumLarge
tCO2e/vehicle1.62.02.41.11.31.61.11.31.6
The code used in the current study was designed to compare the life cycle CO2e emissions of BEVs and ICEVs in various scenarios. It calculates the total emissions for both types of vehicles over a given distance, allowing us to identify when BEVs become more environmentally friendly than ICE-powered vehicles using various constants and data sets.
In the calculations performed, the Python code, shown in Appendix A, implements a modular framework to compute the total emissions for BEVs and ICE vehicles using Equation (1):
E t o t a l = E m a n u f a c t u r i n g + E b a t t e r y   p r o d u c t i o n + E o p e r a t i o n + E m a i n t e n a n c e + E e n d o f l i f e
For BEVs, E b a t t e r y   p r o d u c t i o n accounts for the battery’s emissions based on its production location and capacity. E o p e r a t i o n incorporates electricity emissions adjusted for charging inefficiencies, calculated as
E e l e c t r i c i t y = c o n s u m p t i o n × d i s t a n c e × 1.167 × E e l e c t r i c i t y   m i x   e m i s s i o n s
For ICE vehicles, E o p e r a t i o n is derived from tailpipe and WTT emissions based on the fuel type and distance traveled.
The Python model evaluates emissions across a wide array of parameters, such as vehicle size, fuel type (for ICE vehicles), electricity mix (for BEVs), and battery production location (for BEVs).
Using Python’s iterative calculation capabilities, the model determines the distance at which the cumulative BEV emissions fall below those of ICE vehicles for each scenario. This iterative approach ensures accurate cross-over distances to account for real-world variability in conditions.

3. Results

Several simulations were carried out to obtain the best scenario regarding GHG emissions.
BEVs outperformed diesel and petrol vehicles in all possible scenarios for 240,000 km of mileage, as can be seen in Figure 7. Higher GHG emissions were indeed produced in the supply of raw materials and the manufacture of BEVs compared to ICEVs. The net life cycle impacts depended on the operation of the vehicle and on the electricity mix used to recharge the BEVs.
It can be seen from Figure 7 that, on average, an electric vehicle in the EU emitted almost 3 times less CO2e than a conventional, either diesel or petrol, vehicle in 2023.
In the best-case scenario where a BEV is powered by clean, renewable electricity from Norway, its GHG impact dropped to 9.2 tCO2e, which is 6.37 and 6.52 times lower than that of equivalent vehicles powered by diesel and petrol, respectively. In the worst-case scenario where the battery was produced in China and the electric vehicle was operating in one of the most carbon-intensive grids in the EU (Poland), the lifetime emission increased to 43.9 tCO2e but electric vehicles were still 16% cleaner than diesel vehicles and 18% cleaner than the equivalent petrol vehicles.
The carbon intensity of the electricity used to charge a BEV has a significant impact on its overall CO2e emissions. In the current study, it was assumed that the battery was produced using the average global value, around 97 kg CO2e for each kWh of battery [9] (see Figure 8).
In Poland, which has one of the most carbon-intensive grid energy mixes in Europe (mostly due to coal), a BEV was still 26% and 28% cleaner than a diesel-powered or petrol-powered ICEV, respectively, as can be ascertained from the values in Figure 7 and Figure 8.
Figure 9 shows that after production, BEVs quickly offset their carbon debt compared to ICE cars. Considering an annual mileage of 12,000 km (according to the median mileage in the USA, similar to the European value), it takes around two to three years of driving for a BEV to reach parity with diesel and petrol ICEVs [31]. Figure 9 also shows the CO2e emissions per kilometer accumulated for the distance travelled.
BEVs are initially more polluting than ICEVs since the BEV production phase is around 40% more intensive in terms of emissions than that of ICEVs, mainly owing to the emissions released during battery production.
In the best-case scenario, for BEVs with a battery produced with clean electricity in Sweden and running on clean electricity in Norway, the excess carbon debt would be repaid after around 5990 and 6189 km for an ICEV using petrol and -diesel, respectively. In the worst case, for a BEV with a battery produced in China and powered with the most polluting electricity in the EU (from Poland), it will be necessary to travel around 62,694 km compared to an ICEV using diesel, and for an ICEV using petrol, it will be necessary to reach 50,234 km.
The energy consumption varied for different BEV weights between 16 and 19 kWh/100 km for small and large cars, respectively [30]. For petrol and diesel ICEVs, the energy consumption varied between 6.5 and 8.8 L/100 km and 5.4 and 6.7 L/100 km, respectively. The equivalent CO2e emissions for each kWh of electricity produced in mainland Portugal in 2023 is 166 gCO2e/kWh, and emission values to produce the battery, according to the global average, is around 97 kg CO2e for each kWh of battery. Figure 10 shows the Portuguese CO2 equivalent emission results.
Figure 10 shows that BEVs are approximately 70% less polluting when compared to ICE vehicles with the same dimensions, and even when comparing a large BEV with a small ICEV, the large BEV is approximately 60% less polluting. Considering only exhaust pipe emissions for ICEVs and total emissions for BEVs, it appears that BEVs are 2.3 and 2.1 times less polluting than petrol and diesel ICEVs, respectively. This calculation assumed the best-case scenario for battery manufacturing (see Table 3).
In Figure 11, carrying out the same calculations but for BEVs in Portugal in the best- and worst-case scenarios and considering the segment and location of battery production. The analysis considered the production of BEV batteries. In the best-case scenario, the batteries produced in Sweden had a carbon intensity of 45 kg CO2e/kWh, while in the worst-case scenario, they were manufactured in China and had a density of 108 kg CO2e/kWh.
Table 10 shows the mileage required for BEVs to reach environmental parity with diesel and petrol ICEVs in Portugal in the various scenarios in Figure 9.
From another point of view, the greater carbon intensity of battery production leads to a considerable increase in the initial emissions associated with BEVs, which may require wider use to offset the environmental impact.

4. Conclusions

The objective of this study was to compare BEVs with ICEVs using LCAs.
The study showed that the relevance of BEVs is increasing as the number of vehicles in circulation has increased. In addition, the operation of BEVs is becoming easier as the autonomy of these vehicles has increased significantly.
BEVs showed significant environmental benefits compared to ICE vehicles, even in scenarios where the electrical grid is carbon intensive, such as in Poland. In several scenarios, BEVs consistently outperformed diesel and petrol vehicles in terms of GHG emissions.
In the best-case scenario, in which BEVs are recharged using clean electricity and equipped with batteries produced using renewable energy, the environmental impact was reduced by up to six times compared to conventional ICE vehicles.
It is important to highlight that BEVs can offset the initial “carbon debt” incurred during battery production in just over a year of operation on average, and in the best-case scenario, after half a year, it will have already paid off that “carbon debt”. Over their entire life cycle, BEVs are expected to save between 20 and 50 tCO2e for the worst-case and best-case scenarios, respectively, compared to their ICEV counterparts, highlighting their critical role in mitigating climate change. It was also observed that pollutant emissions from these vehicles were lower for smaller vehicle sizes/weights.
In short, from both environmental and financial perspectives, BEVs offer superior performance and long-term benefits, making them a critical element in the transition to sustainable transportation.
These analyses and results are critical to guiding policymakers and original equipment manufacturers (OEMs) in designing policies and strategic decisions based on long-term goals for countries, states, and cities.
To build on this work, it seems appropriate, as a next step, to compare BEVs and ICEVs using other criteria, such as total cost of ownership.

Author Contributions

Conceptualization, V.V. and L.R.; methodology, V.V.; software, V.V.; validation, J.M., A.B. and A.C.; formal analysis, A.C.; investigation, V.V.; writing—original draft preparation, V.V.; writing—review and editing; supervision, G.F.P., A.B. and L.R. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The original contributions presented in this study are included in the article. Further inquiries can be directed to the corresponding author.

Conflicts of Interest

The authors declare no conflicts of interest.

Nomenclature

BEVBattery Electric Vehicle
EUEuropean Union
EVElectric Vehicle
GHGGreenhouse Gases
HEVHybrid Electrical Vehicle
ICEInternal Combustion Engine
ICEVInternal Combustion Engine Vehicle
PHEVPlug-In Hybrid Electrical Vehicle
SoCState of Charge
SoHState of Health
TTWTank-to-Wheel
WTTWeel-to-Tank
WTWWeel-to-Wheel

Appendix A

Python code.
# Manufacturing emissions in tCO2e per vehicle
manufacturing_ICEV = {
        "gasoline": {
                "small": 5.5,
                "medium": 6.7,
                "large": 7.8,
        } ,
        "diesel": {
                "small": 5.8,
                "medium": 7.0,
                "large": 8.2,
        }
}
manufacturing_BEV = {"small": 5.0, "medium": 6.0, "large": 7.0}

# Battery capacity in kWh per vehicle
battery_capacity = {"small": 45, "medium": 60, "large": 75}

# Emissions from battery production in kgCO2e per kWh of battery
battery_production_emissions = {
        "Sweden": 45,
        "South Korea": 72,
        "USA": 74,
        "China": 108,
        "Battery Average": 97
}

# End-of-life emissions in tCO2e per vehicle
end_of_life_emissions = {
        "small_BEV": -1.6,
        "medium_BEV": -2,
        "large_BEV": -2.4,
        "small_ICEV": -1.1,
        "medium_ICEV": -1.3,
        "large_ICEV": -1.6
}

# TTW emissions
tailpipe_emissions_per_liter_ICEV = {
        "gasoline": 2240/1000/1000,    # tCO2e/L
        "diesel": 2440/1000/1000    # tCO2e/L
}

# WTT emissions
# WTT Maintenance emissions in tCO2e/km
maintenance_emissions_per_km_ICEV = 8.34/1000/1000
maintenance_emissions_per_km_BEV = 4.17/1000/1000

# WTT emissions, extraction refining and transportation
wtt_per_liter_ICEV = {
        "gasoline": 680/1000/1000,    # tCO2e/L
        "diesel": 980/1000/1000    #    tCO2e/L
}

# WTT electricity mix
electricity_generation_emissions_per_kWh = {
        "Portugal": 166/1000/1000,    # tCO2e/kWh
        "USA": 369/1000/1000,    # tCO2e/kWh
        "China": 582/1000/1000,    # tCO2e/kWh
        "Germany": 381/1000/1000,    # tCO2e/kWh
        "Poland": 662/1000/1000,    # tCO2e/kWh
        "Sweden": 41/1000/1000,    # tCO2e/kWh
        "EU27 Average": 229/1000/1000,    # tCO2e/kWh
        "Norway": 30/1000/1000,    # tCO2e/kWh
        "France": 56/1000/1000    # tCO2e/kWh
}

# Vehicle fuel and electricity consumption
consumption_per_100km = {
        "gasoline": {
                "small": 6.5/100,    # l/km
                "medium": 7.5/100,    # l/km
                "large": 8.8/100,    # l/km
        } ,
        "diesel": {
                "small": 5.4/100,    # l/km
                "medium": 6.2/100,    # l/km
                "large": 6.7/100,    # l/km
        },
        "BEV": {
                "small": 16/100,    # kWh/km
                "medium": 17.5/100,    # kWh/km
                "large": 19/100    # kWh/km
        }
}

# Function to calculate total emissions for a given distance
def calculate_emissions(vehicle_type, size, distance, fuel_type=None, battery_prod_loc=None, elec_mix=None):
        if vehicle_type == "ICEV":
                manufacturing = manufacturing_ICEV[fuel_type][size]
                maintenance = maintenance_emissions_per_km_ICEV * distance
                wtt = wtt_per_liter_ICEV[fuel_type] * distance * consumption_per_100km[fuel_type][size]
                tailpipe = tailpipe_emissions_per_liter_ICEV[fuel_type] * distance * consumption_per_100km[fuel_type][size]
                end_of_life = end_of_life_emissions[f"{size}_ICEV"]
                return manufacturing + wtt + maintenance + tailpipe + end_of_life
        elif vehicle_type == "BEV":
                manufacturing = manufacturing_BEV[size]
                battery_production = battery_capacity[size] * battery_production_emissions[battery_prod_loc]/1000    # tCO2e
                maintenance = maintenance_emissions_per_km_BEV * distance
                # Adjust electricity use for charging losses
                electricity_use = consumption_per_100km["BEV"][size] * distance * electricity_generation_emissions_per_kWh[elec_mix]*(1/0.857)
                end_of_life = end_of_life_emissions[f"{size}_BEV"]
                return manufacturing + battery_production + maintenance + electricity_use + end_of_life

# Finding the exact distance where BEV becomes more eco-friendly than ICEV
max_distance = 240000
countries = ["Portugal", "USA", "China", "Germany", "Poland", "Sweden", "EU27 Average", "Norway", "France"]
battery_locations = ["Sweden", "South Korea", "USA", "China", "Battery Average"]
results = []
for size in ["small", "medium", "large"]:
        for fuel_type in ["gasoline", "diesel"]:
                for country in countries:
                        for battery_loc in battery_locations:
                                for distance in range(0, max_distance + 1):
                                        emissions_ICEV = calculate_emissions("ICEV", size, distance, fuel_type=fuel_type)
                                        emissions_BEV = calculate_emissions("BEV", size, distance, battery_prod_loc=battery_loc, elec_mix=country)
                                        if emissions_BEV <= emissions_ICEV:
                                                results.append((size, fuel_type, country, battery_loc, distance, emissions_BEV, emissions_ICEV))
                                                break
print("Results for each scenario where BEV becomes more eco-friendly than ICEV:")
for record in results:
        size, fuel_type, country, battery_loc, distance, emissions_BEV, emissions_ICEV = record
        print(f"Vehicle Size: {size.capitalize()}, Fuel Type: {fuel_type.capitalize()}, Country: {country}, Battery Location: {battery_loc}, Distance: {distance} km, BEV Emissions: {emissions_BEV:.2f} tCO2e, ICEV Emissions: {emissions_ICEV:.2f} tCO2e")

# Calculate emissions at 240000 km for each scenario
distance = 240000
results = []
for size in ["small", "medium", "large"]:
        for fuel_type in ["gasoline", "diesel"]:
                for country in countries:
                        for battery_loc in battery_locations:
                                emissions_ICEV = calculate_emissions("ICEV", size, distance, fuel_type=fuel_type)
                                emissions_BEV = calculate_emissions("BEV", size, distance, battery_prod_loc=battery_loc, elec_mix=country)
                                results.append((size, fuel_type, country, battery_loc, emissions_BEV, emissions_ICEV))
print("Total CO2e emissions after 240,000 km for each scenario:")
for record in results:
        size, fuel_type, country, battery_loc, emissions_BEV, emissions_ICEV = record
        print(f"Vehicle Size: {size.capitalize()}, Fuel Type: {fuel_type.capitalize()}, Country: {country}, Battery Location: {battery_loc}, BEV Emissions: {emissions_BEV:.2f} tCO2e, ICEV Emissions: {emissions_ICEV:.2f} tCO2e")

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Figure 1. Evolution of average range of BEVs (adapted from [2]).
Figure 1. Evolution of average range of BEVs (adapted from [2]).
Applsci 15 03122 g001
Figure 2. Market share for different types of vehicles in the EU 27 in 2023 (adapted from [15]).
Figure 2. Market share for different types of vehicles in the EU 27 in 2023 (adapted from [15]).
Applsci 15 03122 g002
Figure 3. Ownership of BEVs, 2013–2023 (adapted from [17]).
Figure 3. Ownership of BEVs, 2013–2023 (adapted from [17]).
Applsci 15 03122 g003
Figure 4. Carbon intensity over the life cycle of the electricity grid in different countries, 1990–2023 (adapted from [23]).
Figure 4. Carbon intensity over the life cycle of the electricity grid in different countries, 1990–2023 (adapted from [23]).
Applsci 15 03122 g004
Figure 5. LCA framework (adapted from [27]).
Figure 5. LCA framework (adapted from [27]).
Applsci 15 03122 g005
Figure 6. Life Cycle Assessment system for the Well-to-Wheel analysis of ICEVs and EVs.
Figure 6. Life Cycle Assessment system for the Well-to-Wheel analysis of ICEVs and EVs.
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Figure 7. GHG emissions (in tCO2e) from medium-sized vehicles over the life of BEVs in the best- and worst-case scenarios for a mileage of 240,000 km in the year 2023.
Figure 7. GHG emissions (in tCO2e) from medium-sized vehicles over the life of BEVs in the best- and worst-case scenarios for a mileage of 240,000 km in the year 2023.
Applsci 15 03122 g007
Figure 8. GHG emissions (in tCO2e) throughout the life cycle of medium-sized ICEVs and BEVS, showing the influence of the national electricity grid in the use phase.
Figure 8. GHG emissions (in tCO2e) throughout the life cycle of medium-sized ICEVs and BEVS, showing the influence of the national electricity grid in the use phase.
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Figure 9. Evolution of CO2e emissions until carbon parity is reached over the life of medium-sized BEVs and medium-sized ICEVs.
Figure 9. Evolution of CO2e emissions until carbon parity is reached over the life of medium-sized BEVs and medium-sized ICEVs.
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Figure 10. CO2 equivalent emissions over the life of a vehicle driven in Portugal by vehicle segment.
Figure 10. CO2 equivalent emissions over the life of a vehicle driven in Portugal by vehicle segment.
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Figure 11. CO2e equivalent emissions over the life cycle of a vehicle, per vehicle segment, driven in Portugal, for BEVs with batteries produced in China and Sweden.
Figure 11. CO2e equivalent emissions over the life cycle of a vehicle, per vehicle segment, driven in Portugal, for BEVs with batteries produced in China and Sweden.
Applsci 15 03122 g011
Table 1. Comparison of different types of batteries (adapted from [4,5,6,7,8]).
Table 1. Comparison of different types of batteries (adapted from [4,5,6,7,8]).
ParameterPb-PbO2Ni-CdNi-MHZnBr2Na-NiCl2Na-SLi-Ion
Temperature of operation [°C]−20–500–500–5010–40300–350300–350−20–60
Energy density [Wh/kg]30–4040–6060–12060–80120–150150–240150–260
Voltage of each cell [V]2.01.21.21.792.582.083.6
Max. No. of charging cycles200–300500–1000500–1000>20001500–20002500–4500400–3000
Emissions [gCO2e/kWh]200–300250–350300–400400–500500–600600–700150–200
Cost [EUR/Wh]55421.3–1.70.7–0.82
Table 2. Comparison of CO2e emissions in the production of batteries, actual values in 2023, and forecasted values for 2030 (adapted from [14]).
Table 2. Comparison of CO2e emissions in the production of batteries, actual values in 2023, and forecasted values for 2030 (adapted from [14]).
Stage in
Production of Batteries
2023
[kgCO2e/kWh]
Forecast for 2030
[kgCO2e/kWh]
Extraction and refining2610
Production of active materials3210
Logistics144
Manufacturing of cells250
Total9724
Table 3. CO2e emissions from producing batteries in several countries (adapted from [14]).
Table 3. CO2e emissions from producing batteries in several countries (adapted from [14]).
Country of ProductionIntensity of Emissions in [kgCO2e/kWh] 1
Sweden45
South Corea72
USA74
China 279
China108
1 Valid for small, medium, and large BEVs, with 45, 60, and 75 kWh, respectively. 2 Based on a battery without Ni; all the other values are for batteries rich in Ni.
Table 4. GHG emission objectives in the EU from 1990 to 2050 [18,19,20].
Table 4. GHG emission objectives in the EU from 1990 to 2050 [18,19,20].
YearThe Target for GHG Emissions in the EU Results and Forecasts
(Reference Year: 1990)
1990Reference year for most EU climate objectives.------------------------
2000No formal, binding EU-level target for this year.------------------------
2012Kyoto Protocol of 1997 to reduce GHG emissions by 8% (compared to 1990 levels) between 2008 and 2012.Reduction of 12.2%
2020A 20% reduction compared to 1990 levels in 2007 under the EU 2020 “Climate and Energy” package.Reduction of 24%
2030A 55% reduction compared to 1990 levels, in line with the “Fit for 55” objective achieved in 2021.Reduction of 51%
2050Net-zero emissions target.Reduction of 65%
Table 10. Mileage of a BEV up to parity in Portugal, considering the best- and worst-case scenarios for each segment, compared to diesel and petrol ICEVs.
Table 10. Mileage of a BEV up to parity in Portugal, considering the best- and worst-case scenarios for each segment, compared to diesel and petrol ICEVs.
Scenario ICEVs-Diesel (km)ICEVs-Petrol (km)
Best scenario (small BEVs)55355334
Worst scenario (small BEVs)20,84120,086
Best scenario (medium BEVs)71316864
Worst scenario (medium BEVs)27,86526,840
Best scenario (large BEVs)98949525
Worst scenario (large BEVs)36,23134,878
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MDPI and ACS Style

Vieira, V.; Baptista, A.; Cavadas, A.; Pinto, G.F.; Monteiro, J.; Ribeiro, L. Comparison of Battery Electrical Vehicles and Internal Combustion Engine Vehicles–Greenhouse Gas Emission Life Cycle Assessment. Appl. Sci. 2025, 15, 3122. https://doi.org/10.3390/app15063122

AMA Style

Vieira V, Baptista A, Cavadas A, Pinto GF, Monteiro J, Ribeiro L. Comparison of Battery Electrical Vehicles and Internal Combustion Engine Vehicles–Greenhouse Gas Emission Life Cycle Assessment. Applied Sciences. 2025; 15(6):3122. https://doi.org/10.3390/app15063122

Chicago/Turabian Style

Vieira, Vasco, Andresa Baptista, Adélio Cavadas, Gustavo F. Pinto, Joaquim Monteiro, and Leonardo Ribeiro. 2025. "Comparison of Battery Electrical Vehicles and Internal Combustion Engine Vehicles–Greenhouse Gas Emission Life Cycle Assessment" Applied Sciences 15, no. 6: 3122. https://doi.org/10.3390/app15063122

APA Style

Vieira, V., Baptista, A., Cavadas, A., Pinto, G. F., Monteiro, J., & Ribeiro, L. (2025). Comparison of Battery Electrical Vehicles and Internal Combustion Engine Vehicles–Greenhouse Gas Emission Life Cycle Assessment. Applied Sciences, 15(6), 3122. https://doi.org/10.3390/app15063122

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