Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation and Characterization of Nickel Manganite Powder
2.3. Preparation and Characterization of Nickel Manganite-Alginate Nano-Biocomposite Films
2.4. Temperature Sensing Experiment
3. Results and Discussion
3.1. Structure and Morphology of NiMn2O4 Powder
3.2. Structure and Morphology of NiMn2O4-Alginate Nano-Biocomposite
3.3. NTC Thermistor Properties
3.4. Impedance Dependence on Frequency and Temperature at a Constant RH of 50%
3.5. Influence of Change in RH 40–90% on Impedance at a Constant Temperature of 25 °C
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Feteira, A. Negative temperature coefficient resistance (NTCR) ceramic thermistors: An industrial perspective. J. Am. Ceram. Soc. 2009, 92, 967–983. [Google Scholar] [CrossRef]
- Guan, F.; Wu, Y.; Milisavljevic, I.; Cheng, X.; Huang, S. Valence-induced effects on the electrical properties of NiMn2O4 ceramics with different Ni sources. J. Am. Ceram. Soc. 2021, 104, 5148–5156. [Google Scholar] [CrossRef]
- Li, H.; Zhang, H.; Chang, A.; Ma, X.; Rong, J.; Yang, L. A novel core-shell structure NTC ceramic with high stability fabricating by an in-situ ink-jet printing method. J. Eur. Ceram. Soc. 2021, 41, 4167–4174. [Google Scholar] [CrossRef]
- Schubert, M.; Münch, C.; Schuurman, S.; Poulain, V.; Kita, J.; Moos, R. Novel method for NTC thermistor production by aerosol co-deposition and combined sintering. Sensors 2019, 19, 1632. [Google Scholar] [CrossRef] [Green Version]
- Schmidt, R.; Basu, A.; Brinkman, A.W. Small polaron hopping in spinel manganites. Phys. Rev. B 2005, 72, 115101. [Google Scholar] [CrossRef] [Green Version]
- Fritsch, S.; Sarrias, J.; Brien, M.; Conderc, J.J.; Bandour, J.L.; Snoek, E.; Rousset, A. Correlation between the structure, the microstructure and the electrical properties of nickel manganite negative temperature coefficient (NTC) thermistors. Solid State Ion. 1998, 109, 229–237. [Google Scholar] [CrossRef]
- Schubert, M.; Munch, C.; Schuman, S.; Poulain, V.; Kita, J.; Moos, R. Characterization of nickel manganite NTC thermistor films prepared by aerosol deposition at room temperature. J. Eur. Ceram. Soc. 2018, 38, 613–619. [Google Scholar] [CrossRef]
- Liang, S.; Cao, C.; Yuan, Y.; Li, H.; Luo, M.; Gao, M.; Zhang, X. Hydrothermal synthesis of Zn-doped Ni-Mn-Al-O thin films toward high-performance negative temperature coefficient thermistor. J. Mater. Sci. Mater. Electron. 2018, 29, 9025–9032. [Google Scholar] [CrossRef]
- Aleksic, O.S.; Nikolic, M.V.; Lukovic, M.D.; Nikolic, N.; Radojcic, B.M.; Radovanovic, M.; Djuric, Z.Z.; Mitric, M.; Nikolic, P.M. Preparation and characterization of Cu and Zn modified nickel manganite NTC powders and thick film thermistors. Mater. Sci. Eng. B 2013, 178, 202–210. [Google Scholar] [CrossRef]
- Ma, C.; Liu, Y.; Lu, Y.; Gao, H.; Qian, H.; Ding, J. Effect of Zn substitution on the phase, microstructure and electrical properties of Ni0.6Cu0.5ZnxMn1.9-xO4 (0 ≤ x ≤ 1) NTC ceramics. Mater. Sci. Eng. B 2014, 188, 66–71. [Google Scholar] [CrossRef]
- Katerinopolou, D.; Zalar, P.; Sweelssen, J.; Kiriakidis, G.; Rentorp, C.; Groen, P.; Gelinck, G.H.; van den Brand, J.; Smits, E.C.P. Large-area all-printed temperature sensing surfaces using novel composite thermistor materials. Adv. Electron. Mater. 2019, 5, 1800605. [Google Scholar] [CrossRef] [Green Version]
- Shin, J.; Jeong, B.; Kim, J.; Nam, V.B.; Yoon, Y.; Jung, J.; Hong, S.; Lee, H.; Eom, H.; Yeo, J.; et al. Sensitive wearable temperature sensor with seamless monolithic integration. Adv. Mater. 2019, 2019, 19055271. [Google Scholar] [CrossRef] [PubMed]
- Baldo, T.A.; Felipe de Lima, L.; Mendes, L.F.; de Araujo, W.R.; Paixao, T.R.L.C.; Coltro, W.K.T. Wearable and biodegradable sensors for clinical and environmental applications. ACS Appl. Electron. Mater. 2021, 3, 68–100. [Google Scholar] [CrossRef]
- Majumder, S.; Mondal, T.; Jamal Deen, M. Wearable sensors for remote health monitoring. Sensors 2017, 17, 1301. [Google Scholar] [CrossRef]
- Su, Y.; Ma, C.; Chen, J.; Wu, X.; Luo, W.; Peng, Y.; Luo, Z.; Peng, Y.; Luo, Z.; Li, L.; et al. Printable, highly sensitive flexible temperature sensors for human body temperature monitoring: A review. Nanoscale Res. Lett. 2020, 15, 200. [Google Scholar] [CrossRef] [PubMed]
- Silva, A.F.; Tavakoli, M. Domiciliary hospitalization through wearable biomonitoring patches: Recent advances, technical challenges and the relation to COVID-19. Sensors 2020, 20, 6835. [Google Scholar] [CrossRef]
- Kuzubasoglu, B.A.; Bahadir, S.K. Flexible temperature sensors: A review. Sens. Actuators A 2020, 315, 112282. [Google Scholar] [CrossRef]
- Barmpakos, D.; Kaltsas, G. A review on humidity, temperature and strain printed sensors—Current trends and future perspectives. Sensors 2021, 21, 739. [Google Scholar] [CrossRef]
- Chen, L.; Zhang, J. Designs of conductive polymer composites with exceptional reproducibility of positive temperature coefficient effect: A review. J. Appl. Polym. Sci. 2021, 138, e49677. [Google Scholar] [CrossRef]
- Jeon, J.; Lee, H.B.R.; Bao, Z. Flexible wireless temperature sensors based on Ni microparticle filled binary polymer composite. Adv. Mater. 2013, 25, 850–855. [Google Scholar] [CrossRef]
- Bibi, A.; Rehman, S.; Yaseem, A. Alginate nanoparticles composites: Kinds, reactions and applications. Mater. Res. Express 2019, 6, 092001. [Google Scholar] [CrossRef]
- Liu, S.; Li, Y.; Li, L. Enhanced stability and mechanical strength of sodium alginate composite films. Carbohydr. Polym. 2017, 160, 62–70. [Google Scholar] [CrossRef]
- Biondi, M.; Borzacchiello, A.; Mayol, L.; Ambrosio, L. Nanoparticle integrated hydrogels as multifunctional composite materials for biomedical applications. Gels 2015, 1, 162–178. [Google Scholar] [CrossRef] [Green Version]
- Varaprasad, K.; Raghavendra, G.M.; Jayaramudu, T. Nano zinc oxide—sodium alginate antibacterial cellulose fibres. Carbohyrd. Polym. 2014, 135, 349–355. [Google Scholar] [CrossRef] [PubMed]
- Aristazabal-Gil, M.V.; Santiago-Toro, S.; Sanchez, L.T.; Pinzon, M.I.; Gutierez, J.A.; Viela, C.C. ZnO and ZnO/CaO nanoparticles in alginate films. Synthesis, mechanical characterization, barrier properties and release kinetics. LWT Food. Sci. Technol. 2019, 112, 108217. [Google Scholar] [CrossRef]
- Buk, V.; Euregul, E.; Euregul, K.C. Alginate copper oxide nano-biocomposite as a novel material for amperometric glucose biosensing. Mater. Sci. Eng. C 2017, 74, 307–314. [Google Scholar] [CrossRef] [PubMed]
- Varma, A.; Mukasyan, A.S.; Rogachev, A.S.; Manukyan, K.V. Solution combustion synthesis of nanoscale materials. Chem. Rev. 2016, 116, 14493–14586. [Google Scholar] [CrossRef] [PubMed]
- Vamsi Krishna, B.N.; Bhagwan, J.; Yu, J.S. Sol-gel routed NiMn2O4 nanofabric electrode materials for supercapacitors. J. Electrochem. Soc. 2019, 166, A1950. [Google Scholar] [CrossRef]
- Al-Senani, G.M.; Abd-Elkader, O.H.; Al-Kadhi, N.S.; Deraz, N.M. Effect of glycine treatment on synthesis and physicochemical characteristics of nanosized Ni-Mn mixed oxides. Crystals 2021, 11, 487. [Google Scholar] [CrossRef]
- Momma, K.; Izumi, F. VESTA 3 for three dimensional visualization of crystal, volumetric and morphology data. J. Appl. Crystallogr. 2011, 44, 1271–1276. [Google Scholar] [CrossRef]
- Sodium Alginate, 2D Structure. Available online: https://pubchem.ncbi.nlm.nih.gov/compound/5102882#section=2D-Structure (accessed on 17 March 2021).
- Sodium Alginate, 3D Conformer. Available online: https://pubchem.ncbi.nlm.nih.gov/compound/5102882#section=3D-Conformer (accessed on 17 March 2021).
- Nikolic, M.V.; Vasiljevic, Z.Z.; Dojcinovic, M.P.; Tadic, N.B.; Radovanovic, M.; Stojanovic, G.M. Nanocrystalline nickel manganite synthesis by sol-gel combustion for flexible temperature sensors. In Proceedings of the 2020 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS), Manchester, UK, 16–19 August 2020. [Google Scholar] [CrossRef]
- Nikolic, M.V.; Dojcinovic, M.P.; Vasiljevic, Z.Z.; Lukovic, M.D.; Labus, N.J. Nanocomposite Zn2SnO4/SnO2 thick films as a humidity sensing material. IEEE Sens. J. 2020, 20, 7509–7516. [Google Scholar] [CrossRef] [Green Version]
- Vijaya Sankar, K.; Suren Idran, S.; Pandi, K.; Allin, A.M.; Nithya, V.D.; Lee, Y.S.; Kalai Selvan, R. Studies on the electrochemical intercalation/de-intercalation mechanism of NiMn2O4 for high stable pseudocapacitor electrodes. RSC Adv. 2015, 5, 27649–27656. [Google Scholar] [CrossRef]
- Mhin, S.; Han, H.; Kim, K.M.; Lim, J.; Kim, D.; Lee, J.I.; Ryu, J.H. Synthesis of (Ni, Mn,Co)O4 nanopowder with single cubic phase via combustion method. Ceram. Int. 2016, 42, 13654–13658. [Google Scholar] [CrossRef]
- Komova, O.V.; Simagina, V.I.; Mukha, S.S.; Netskina, O.V.; Odegova, G.V.; Bularchenko, O.A.; Ishchenko, A.V.; Pochtar, A.A. A modified glycine-nitrate combustion method for one-step synthesis of LaFeO3. Adv. Powder Technol. 2016, 27, 496–503. [Google Scholar] [CrossRef]
- Savic, S.M.; Nikolic, M.V.; Paraskevopoulos, K.M.; Zorba, T.T.; Nikolic, N.; Blagojevic, V.; Aleksic, O.S.; Brankovic, G. Far infrared and microstructural studies of mechanically activated nickel manganite. Ceram. Int. 2013, 39, 1241–1247. [Google Scholar] [CrossRef]
- Moulder, J.F.; Stickle, W.F.; Sobol, P.E.; Bomben, K.D. Handbook of X-ray Photoelectron Spectroscopy; Physical Electronics Inc.: Eden Prairie, MN, USA, 1995. [Google Scholar]
- Zhang, M.; Guo, S.; Zheng, L.; Zhang, G.; Hao, Z.; Kang, L.; Liu, Z.H. Preparation of NiMn2O4 with large specific surface area from an epoxide driven sol-gel process and its capacitance. Electrochim. Acta 2013, 87, 546–553. [Google Scholar] [CrossRef]
- Toepfer, J.; Feltz, A.; Graef, D.; Hacke, B.; Rampach, L.; Weissbrodt, P. Cation valences and distribution in the spinels NiMn2O4 and MzNiMn2-zO4 (M = Li, Cu) studied by XPS. Phys. Stat. Sol. 1992, 134, 405. [Google Scholar] [CrossRef]
- Lisboa-Filho, P.N.; Bahout, M.; Barahora, P.; Moure, C.; Pena, O. Oxygen stoichiometry effects in spinel type NiMn2O4-δ samples. J. Phys. Chem. Sol. 2005, 66, 1206–1212. [Google Scholar] [CrossRef]
- Papageorgiu, S.K.; Kouvelos, E.P.; Favvas, E.P.; Sagalidis, A.A.; Romanos, G.E.; Katsavos, F.K. Metal-carboxylate interactions in metal-alginate complexes studied with FTIR spectroscopy. Carbohydr. Res. 2010, 345, 469–473. [Google Scholar] [CrossRef]
- Xiao, Q.; Gu, X.; Tan, S. Drying process of sodium alginate films studied by two-dimensional correlation ATR-FTIR spectroscopy. Food. Chem. 2014, 164, 179–184. [Google Scholar] [CrossRef]
- Ionita, M.; Pandele, M.A.; Iovu, H. Sodium alginate/graphene oxide composite films with enhanced thermal and mechanical properties. Carbohydr. Polym. 2013, 94, 339–344. [Google Scholar] [CrossRef] [PubMed]
- Dojcinovic, M.P.; Vasiljevic, Z.Z.; Krstic, J.B.; Vujancevic, J.D.; Markovic, S.; Tadic, N.B.; Nikolic, M.V. Electrospun nickel manganite (NiMn2O4) nanocrystalline fibers for humidity and temperature sensing. Sensors 2021, 21, 4351. [Google Scholar] [CrossRef] [PubMed]
- Ryu, J.; Park, D.S.; Schmidt, R. In-plane impedance spectroscopy in aerosol deposited NiMn2O4 negative temperature coefficient thermistor films. J. Appl. Phys. 2011, 109, 113722. [Google Scholar] [CrossRef] [Green Version]
- Zhang, X.; Yao, S.; Zhao, D.; Liang, S. Nano-negative temperature coefficient thermistor with unique electrical properties of high B constant and low resistivity. J. Mater. Sci. Mater. Electron. 2021, 32, 5222–5232. [Google Scholar] [CrossRef]
- Zeng, Y.; Li, Z.; Shao, Z.; Wang, X.; Hao, W.; Zhang, H. Electrical properties of YFeO3 based ceramics modified by Cu/Nb ions as negative temperature coefficient thermistors. J. Mater. Sci. Mater. Electron. 2019, 30, 14528–14537. [Google Scholar] [CrossRef]
- Nikolic, M.V.; Sekulic, D.L.; Vasiljevic, Z.Z.; Lukovic, M.D.; Pavlovic, V.B.; Aleksic, O.S. Dielectric properties, complex impedance and electrical conductivity of Fe2TiO5 nanopowder compacts and bulk samples at elevated temperatures. J. Mater. Sci. Mater. Electron. 2017, 28, 4796–4806. [Google Scholar] [CrossRef] [Green Version]
- Bondarenko, A.S.; Ragoisha, G. EIS Spectrum Analyzer. Available online: https://www.abc.chemistry.bsu.by (accessed on 25 November 2016).
- He, L.; Ling, Z. Studies of temperature dependent ac impedance of a negative temperature coefficient Mn-Co-Ni-O thin film thermistor. Appl. Phys. Lett. 2011, 98, 242112. [Google Scholar] [CrossRef]
- Gawli, Y.; Badadhe, S.; Basu, A.; Guin, D.; Shelke, M.V.; Ogale, S. Evaluation of n-type ternary metal oxide NiMn2O4 nanomaterial for humidity sensing. Sens. Actuators B 2014, 191, 837–843. [Google Scholar] [CrossRef]
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Dojcinovic, M.P.; Vasiljevic, Z.Z.; Kovac, J.; Tadic, N.B.; Nikolic, M.V. Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing. Chemosensors 2021, 9, 241. https://doi.org/10.3390/chemosensors9090241
Dojcinovic MP, Vasiljevic ZZ, Kovac J, Tadic NB, Nikolic MV. Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing. Chemosensors. 2021; 9(9):241. https://doi.org/10.3390/chemosensors9090241
Chicago/Turabian StyleDojcinovic, Milena P., Zorka Z. Vasiljevic, Janez Kovac, Nenad B. Tadic, and Maria Vesna Nikolic. 2021. "Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing" Chemosensors 9, no. 9: 241. https://doi.org/10.3390/chemosensors9090241