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Magnetochemistry, Volume 7, Issue 10

2021 October - 8 articles

Cover Story: The known scope of transition-metal compounds that undergo spin crossover (SCO) is overwhelmingly dominated by complexes of the Fe(II) ion in octahedral coordination of six N-donor atoms. The discovery of SCO behavior in novel coordination environments promises to offer new opportunities for the design of materials and devices that rely on spin-state switching. To that end, we demonstrate the usefulness of S-coordinating ligands for the synthesis of SCO complexes and compare the relative strength of topologically similar tetradentate ligands with the {N4} and {N2S2} coordination environments.View this paper
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Articles (8)

  • Feature Paper
  • Review
  • Open Access
8 Citations
3,780 Views
16 Pages

Magnetic Functionalization of Scanning Probes by Focused Electron Beam Induced Deposition Technology

  • Javier Pablo-Navarro,
  • Soraya Sangiao,
  • César Magén and
  • José María de Teresa

The fabrication of nanostructures with high resolution and precise control of the deposition site makes Focused Electron Beam Induced Deposition (FEBID) a unique nanolithography process. In the case of magnetic materials, apart from the FEBID potenti...

  • Article
  • Open Access
2 Citations
3,260 Views
12 Pages

Magnetic Properties of a Ni Nanonet Grown in Superfluid Helium under Laser Irradiation

  • Oksana Koplak,
  • Elizaveta Dvoretskaya,
  • Maxim Stepanov,
  • Alexander Karabulin,
  • Vladimir Matyushenko and
  • Roman Morgunov

A nanonet consisting of ultrathin Ni nanowires (diameter <4 nm) and Ni nanoballs (diameter <20 nm) has been grown through laser ablation of a Ni target in superfluid helium. At a low Ni concentration, the nanonet consists mainly of nanowires an...

  • Article
  • Open Access
2 Citations
3,250 Views
12 Pages

In this study, we performed a quantum mechanical examination of thermodynamic, structural, elastic, and magnetic properties of single-phase ferromagnetic Fe2CoAl with a chemically disordered B2-type lattice with and without antiphase boundaries (APBs...

  • Review
  • Open Access
9 Citations
4,157 Views
13 Pages

The effective combination of chirality and magnetism in a single crystalline material can lead to fascinating cross-effects, such as magneto-chiral dichroism. Among a large variety of chiral ligands utilized in the design and synthesis of chiral magn...

  • Review
  • Open Access
10 Citations
4,002 Views
17 Pages

In this review, the technique of resonant soft X-ray reflectivity in the study of magnetic low-dimensional systems is discussed. This technique is particularly appealing in the study of magnetization at buried interfaces and to discriminate single el...

  • Feature Paper
  • Article
  • Open Access
9 Citations
3,411 Views
12 Pages

Magnetic Field Perturbations to a Soft X-ray-Activated Fe (II) Molecular Spin State Transition

  • Guanhua Hao,
  • Alpha T. N’Diaye,
  • Thilini K. Ekanayaka,
  • Ashley S. Dale,
  • Xuanyuan Jiang,
  • Esha Mishra,
  • Corbyn Mellinger,
  • Saeed Yazdani,
  • John W. Freeland and
  • Peter A. Dowben
  • + 3 authors

The X-ray-induced spin crossover transition of an Fe (II) molecular thin film in the presence and absence of a magnetic field has been investigated. The thermal activation energy barrier in the soft X-ray activation of the spin crossover transition f...

  • Feature Paper
  • Article
  • Open Access
2 Citations
3,316 Views
14 Pages

Pyridyl-Thioethers as Capping Ligands for the Design of Heteroleptic Fe(II) Complexes with Spin-Crossover Behavior

  • Ökten Üngör,
  • Dilyara Igimbayeva,
  • Alina Dragulescu-Andrasi,
  • Sandugash Yergeshbayeva,
  • Teresa Delgado,
  • Samuel M. Greer,
  • Gabrielle Donalson,
  • Minyoung Jo,
  • Rakhmetulla Erkasov and
  • Michael Shatruk

Mononuclear heteroleptic complexes [Fe(tpma)(bimz)](ClO4)2 (1a), [Fe(tpma)(bimz)](BF4)2 (1b), [Fe(bpte)(bimz)](ClO4)2 (2a), and [Fe(bpte)(bimz)](BF4)2 (2b) (tpma = tris(2-pyridylmethyl)amine, bpte = S,S′-bis(2-pyridylmethyl)-1,2-thioethane, bimz = 2,...

  • Review
  • Open Access
41 Citations
5,361 Views
22 Pages

Environmental concerns, along with oil shortages, have increased industrial interest in biomass conversion to produce biofuels and other valuable chemicals. A green option in biomass processing is the use of enzymes, such as cellulases, hemicellulase...

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Magnetochemistry - ISSN 2312-7481