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Recycling, Volume 10, Issue 5 (October 2025) – 2 articles

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14 pages, 4168 KB  
Article
Manufacturing and Recycling of 3D-Printed All-Polymer Composites
by Itsari Phuangmali, Yao Xu, Leyu Lin and Alois K. Schlarb
Recycling 2025, 10(5), 168; https://doi.org/10.3390/recycling10050168 - 26 Aug 2025
Viewed by 140
Abstract
The reinforcement of polymers with carbon or glass fibers is the reason for their incredible success as ideal lightweight construction materials. However, one challenge with these materials is their recyclability. True recycling, meaning achieving the same performance level as virgin material, is impossible, [...] Read more.
The reinforcement of polymers with carbon or glass fibers is the reason for their incredible success as ideal lightweight construction materials. However, one challenge with these materials is their recyclability. True recycling, meaning achieving the same performance level as virgin material, is impossible, especially with mechanical recycling processes, because the reinforcement structure is destroyed. Additionally, thermoplastics undergo molecular degradation and changes in the properties of the materials. Therefore, polymer fiber-reinforced plastics may have an advantage here, as polymer fibers are much more flexible than glass or carbon fibers. We investigated the production and recyclability of microfibrillar composites (MFCs) made of polypropylene (PP) and polyethylene terephthalate (PET). The samples were produced using extrusion-based 3D printing with different parameters, and their morphology and mechanical properties were examined. The samples were crushed, and the residue was fed back into the production line. The process was repeated with the samples produced from regenerate. The results prove that the printing process can be controlled to ensure the presence of fibers in samples made from recycled material. However, it is important to note that the mechanical properties decrease with each additional processing cycle. The choice of manufacturing parameters, especially in 3D printing, is crucial for achieving good properties. Full article
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12 pages, 1894 KB  
Article
Pyrometallurgical Process to Recover Lead and Silver from Zinc Leaching Residue
by Cancio Jiménez-Lugos, Manuel Flores-Favela, Antonio Romero-Serrano, Aurelio Hernández-Ramírez, Alejandro Cruz-Ramírez, Enrique Sanchez-Vite, José Ortiz-Landeros and Eduardo Colin-García
Recycling 2025, 10(5), 167; https://doi.org/10.3390/recycling10050167 - 25 Aug 2025
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Abstract
During the roasting, leaching, and electrodeposition of zinc ores, lead–silver residues are produced. These residues contain valuable metals (Pb, Zn, and Ag) and toxic metals (Cd and As). In this study, a pyrometallurgical process is proposed for treating Pb-Ag residues, consisting of drying, [...] Read more.
During the roasting, leaching, and electrodeposition of zinc ores, lead–silver residues are produced. These residues contain valuable metals (Pb, Zn, and Ag) and toxic metals (Cd and As). In this study, a pyrometallurgical process is proposed for treating Pb-Ag residues, consisting of drying, roasting, and reduction steps to recover valuable metals, such as silver in a metallic Pb phase, while converting the waste into an environmentally friendly slag. First, the Pb-Ag residue is dried at 100 °C, then roasted at 700 °C, and finally reduced at a high temperature, with Na2CO3 as a flux and CaSi as a reducing agent, rather than carbon-based reducing agents (carbon or carbon monoxide), to minimize greenhouse gas production. The effects of the reduction temperature and the mass of the reducing agent were investigated on a laboratory scale. The metallic phase and slag obtained in the reduction step were characterized by their chemical composition and mineralogy via chemical analysis, X-ray diffraction, and SEM-EDS. The results showed that silver and lead formed a metallic phase, and that silver content decreased from 1700 ppm in the Pb-Ag residue to 32 ppm in the final slag at 1300 °C. The Pb-Ag residue and final slag were leached with an aqueous acetic acid solution to evaluate their chemical stability. Full article
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