Atmospheric Mercury Dynamics in Remote Regions

A special issue of Atmosphere (ISSN 2073-4433). This special issue belongs to the section "Air Quality".

Deadline for manuscript submissions: closed (28 March 2022) | Viewed by 5092

Special Issue Editors


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Guest Editor
Division of Environmental Science and Engineering, Pohang University of Science and Technology, 77 Cheongam-ro, Hyogok-dong, Nam-gu, Pohang-si 37673, Gyeongsangbuk-do, Republic of Korea
Interests: mercury; stable isotopes; aquatic ecosystem; source tracing; biogeochemistry

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Guest Editor
School of Architecture, Civil and Environmental Engineering, École Polytechnique Fédérale de Lausanne, Rue de l’Industrie, 1951 Sion, Switzerland.
Interests: atmospheric trace gases; surface-atmosphere gas exchange; polar regions

Special Issue Information

Dear Colleagues,

This Special Issue on “Atmospheric Mercury Dynamics in Remote Regions” is open to all aspects of atmospheric mercury science including, but not limited to, sources, transport, transformation, and atmosphere–surface exchange, with particular emphasis on remote regions. The rationale for this Special Issue is to understand mercury dynamics at baseline sites, i.e., in the absence of significant local/regional anthropogenic pressure, and to evaluate/predict variability in the context of global change.

Mercury has long been regarded as a global atmospheric pollutant, which can bioaccumulate to elevated levels in humans and wildlife upon exposure. The UNEP Minamata Convention on Mercury entered into force in 2017 and commits its 127 parties to curb anthropogenic emissions. Understanding the response of mercury dynamics to anthropogenic and natural perturbations (e.g., climate, land-use, atmospheric composition changes) is key to assessing the effectiveness of the Minamata Convention. Current and future climate change may for instance counterbalance international efforts to reduce mercury emissions by remobilizing legacy reservoirs. There is an urgent need to better understand and predict mercury dynamics in relatively pristine environments, where impacts of global environmental changes can be quantitatively assessed.

We are particularly open to process-based knowledge on atmospheric mercury in remote regions, including polar, open ocean, forest, or any locations surrounded by little point source emissions, which are representative of typical regional baseline atmospheric conditions and composition. The historical, present-day, and future evaluations of any changes regarded as global change such as climate change, land-use change, and changes in atmospheric composition, anthropogenic activities, and legacy emissions on atmospheric mercury are also welcome. The technical approach (concentration and isotope measurements, numerical modeling, trend analyses) to addressing these themes is unlimited.

Dr. Sae Yun Kwon
Dr. Hélène Angot
Guest Editors

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Keywords

  • mercury
  • atmosphere
  • remote regions
  • baseline
  • atmosphere–surface exchange
  • global change
  • climate change
  • legacy emissions

Published Papers (2 papers)

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Research

10 pages, 1797 KiB  
Article
Simultaneous Removal of Hg0 and H2S over a Regenerable Fe2O3/AC Catalyst
by Junwei Wang, Yao Fang, Huan Wang, Guoliang Bai, Wei Qin and Jianli Zhang
Atmosphere 2022, 13(3), 425; https://doi.org/10.3390/atmos13030425 - 6 Mar 2022
Cited by 6 | Viewed by 1516
Abstract
Simultaneous removal of Hg0 and H2S over a regenerable activated coke supported Fe2O3 catalyst (Fe2O3/AC) was studied in simulated coal-derived syngas. It was found that the Fe2O3/AC catalyst exhibited [...] Read more.
Simultaneous removal of Hg0 and H2S over a regenerable activated coke supported Fe2O3 catalyst (Fe2O3/AC) was studied in simulated coal-derived syngas. It was found that the Fe2O3/AC catalyst exhibited high capability for Hg0 and H2S removal, which was attributed to the catalytic oxidation activity of Fe2O3. Its capability for Hg0 and H2S removal increased with an increase of Fe2O3 loading amount, and the highest was at 150 °C for Hg0 removal. CO and H2 showed no obvious effect on Hg0 removal by Fe2O3/AC, while H2S had a promotion effect, which was due to S and FeSx produced by the H2S reaction on Fe2O3/AC. The results of SEM-EDX and the temperature programmed desorption experiment (TPD) revealed that Fe2O3 played a critical role in Hg0 oxidation, and HgS was generated upon the reaction of Hg0 with H2S on Fe2O3/AC. The used Fe2O3/AC catalyst after Hg0 and H2S removal could be effectively regenerated and still had high capability for Hg0 and H2S removal. Full article
(This article belongs to the Special Issue Atmospheric Mercury Dynamics in Remote Regions)
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16 pages, 2552 KiB  
Article
Assessment of Mercury Concentrations and Fluxes Deposited from the Atmosphere on the Territory of the Yamal-Nenets Autonomous Area
by Stella Eyrikh, Liliya Shol and Elena Shinkaruk
Atmosphere 2022, 13(1), 37; https://doi.org/10.3390/atmos13010037 - 27 Dec 2021
Cited by 6 | Viewed by 2476
Abstract
The problem of mercury input and its further distribution in the Arctic environment is actively debated, especially in recent times, due to the observed processes of permafrost thawing causing the enhanced release of mercury into the Arctic atmosphere and further distribution in the [...] Read more.
The problem of mercury input and its further distribution in the Arctic environment is actively debated, especially in recent times, due to the observed processes of permafrost thawing causing the enhanced release of mercury into the Arctic atmosphere and further distribution in the terrestrial and aquatic ecosystem. The atmospheric mercury deposition occurs via dry deposition and wet scavenging by precipitation events. Here we present a study of Hg in wet precipitation on the remote territory of the Russian Arctic; the data were obtained at the monitoring stations Nadym and Salekhard in 2016–2018. Mercury pollution of the Salekhard atmosphere in cold time is mainly determined by regional and local sources, while in Nadym, long-range transport of mercury and local fuel combustion are the main sources of pollutants in the cold season, while internal regional sources have a greater impact on the warm season. Total mercury concentrations in wet precipitation in Nadym varied from <0.5 to 63.3 ng/L. The highest Hg concentrations in the springtime were most likely attributed to atmospheric mercury depletion events (AMDE). The contributions of wet atmospheric precipitation during the AMDE period to the annual Hg deposition were 16.7% and 9.8% in 2016/2017 and 2017/2018, respectively. The average annual volume-weighted Hg concentration (VWC) in the atmospheric precipitation in Nadym is notably higher than the values reported for the remote regions in the Arctic and comparable with the values obtained for the other urbanized regions of the world. Annual Hg fluxes in Nadym are nevertheless close to the average annual fluxes for remote territories of the Arctic zone and significantly lower than the annual fluxes reported for unpolluted sites of continental-scale monitoring networks of the different parts of the world (USA, Europe, and China). The increase of Hg deposition flux with wet precipitation in Nadym in 2018 might be caused by regional emissions of gas and oil combustion, wildfires, and Hg re-emission from soils due to the rising air temperature. The 37 cm increase of the seasonally thawed layer (STL) in 2018 compared to the 10-year average reflects that the climatic changes in the Nadym region might increase Hg(0) evasion, considering a great pool of Hg is contained in permafrost. Full article
(This article belongs to the Special Issue Atmospheric Mercury Dynamics in Remote Regions)
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