Application of TiO2 Nanotube in Electrocatalysis/Photocatalysis

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (31 July 2021) | Viewed by 12656

Special Issue Editors


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Guest Editor
National Institute for Laser, Plasma and Radiation Physics, Bucharest, Romania
Interests: stress and associated strain effects developed at the interface in oxide multilayers

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Guest Editor
National Institute for Lasers, Plasma and Radiation Physics, Atomistilor Str. No. 409, 077125 Bucharest-Magurele, Romania
Interests: advanced materials; nanotechnology; energy storage and production

Special Issue Information

Dear Colleagues,

In the context of continuous technological development and human population growth, the consumption of energy as a result of the burning of fossil fuels, which are depleting at an accelerating pace, represents a major problem for human well-being and ecosystem health. In that regard, comprehensive research has been dedicated to both electrocatalysis and photocatalysis, broad topics related to energy production and storage and water and air pollution treatment. Electrocatalysis plays a pivotal role in the fields of wastewater treatment and energy conversion devices like batteries, fuel, and solar cells, while photocatalysis deals with the removal of environmental pollutants (self-cleaning surfaces, NOx and volatile organic compounds oxidation, etc.) and green energy production (hydrogen generation, CO2 conversion to biofuels, etc).

Of paramount importance for the development and advancement of these fields is the use of suitable catalyst materials that fulfill a list of requirements, like biological and chemical inertness, suitable bandgap, low cost and nontoxicity, long term stability, high mobility of charge carriers, and the predictable correlation between physical and photo/electrochemical properties. TiO2 is by far the most explored material, research around its properties spans over more than four decades and, recently, its structuration in the form of nanotubes has gained substantial interest. Both experimental and theoretical research findings dealing with the synthesis and tailoring of properties of TiO2 nanotubes through various techniques (heat treatment, doping, tube decoration, etc.), and their application in electrocatalysis and photocatalysis are of prime importance for this Special Issue.

Dr. Cristian Nicolae Mihailescu
Dr. Mihai-Robert Zamfir
Guest Editors

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Keywords

  • TiO2 nanotubes synthesis techniques
  • Physical and chemical properties tailoring
  • Bandgap engineering
  • Suppression of photogenerated carriers recombination
  • Electrochemical performances
  • Li-ion batteries
  • Pollutant degradations
  • Water splitting
  • Fuel conversion

Published Papers (2 papers)

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Research

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13 pages, 4267 KiB  
Article
TiO2@MOF Photocatalyst for the Synergetic Oxidation of Microcystin-LR and Reduction of Cr(VI) in Aqueous Media
by Yarui Wang, Wanchao Yu, Fanglan Geng, Lixia Zhao and Yawei Wang
Catalysts 2021, 11(10), 1186; https://doi.org/10.3390/catal11101186 - 29 Sep 2021
Cited by 13 | Viewed by 3201
Abstract
The coexistence of pollutants presents a great challenge to the implementation of photocatalysts. In this work, a novel MIL-101(Fe)/TiO2 composite prepared by in situ growth of MIL-101(Fe) on TiO2 was developed for the synergetic oxidation of MC-LR and Cr(VI) reduction. The [...] Read more.
The coexistence of pollutants presents a great challenge to the implementation of photocatalysts. In this work, a novel MIL-101(Fe)/TiO2 composite prepared by in situ growth of MIL-101(Fe) on TiO2 was developed for the synergetic oxidation of MC-LR and Cr(VI) reduction. The heterojunction material shows elevated photocatalytic behavior under ultraviolet compared with the unary pollutant system. Furthermore, quenching experiments and electron spin resonance confirm that the enhanced photodegradation behavior is related to the synergistic effect between the photocatalytic reduction and oxidation process, in which MC-LR consumes the holes and Cr(VI) captures electrons, followed by efficient charge separation through the conventional double-transfer mechanism between MIL-101(Fe) and TiO2. This investigation provides a deeper understanding of the construction of MOFs/semiconductor heterojunctions for the pollutants removal in multi-component contaminants system. Full article
(This article belongs to the Special Issue Application of TiO2 Nanotube in Electrocatalysis/Photocatalysis)
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Review

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82 pages, 1853 KiB  
Review
A Review on Metal Ions Modified TiO2 for Photocatalytic Degradation of Organic Pollutants
by Dafu Jiang, Tunmise Ayode Otitoju, Yuanyuan Ouyang, Noor Fazliani Shoparwe, Song Wang, Ailing Zhang and Sanxi Li
Catalysts 2021, 11(9), 1039; https://doi.org/10.3390/catal11091039 - 27 Aug 2021
Cited by 55 | Viewed by 8841
Abstract
TiO2 is a semiconductor material with high chemical stability and low toxicity. It is widely used in the fields of catalysis, sensing, hydrogen production, optics and optoelectronics. However, TiO2 photocatalyst is sensitive to ultraviolet (UV) light; this is why its photocatalytic [...] Read more.
TiO2 is a semiconductor material with high chemical stability and low toxicity. It is widely used in the fields of catalysis, sensing, hydrogen production, optics and optoelectronics. However, TiO2 photocatalyst is sensitive to ultraviolet (UV) light; this is why its photocatalytic activity and quantum efficiency are reduced. To enhance the photocatalytic efficiency in the visible light range as well as to increase the number of the active sites on the crystal surface or inhibit the recombination rate of photogenerated electron–hole pairs electrons, various metal ions were used to modify TiO2. This review paper comprehensively summarizes the latest progress on the modification of TiO2 photocatalyst by a variety of metal ions. Lastly, the future prospects of the modification of TiO2 as a photocatalyst are proposed. Full article
(This article belongs to the Special Issue Application of TiO2 Nanotube in Electrocatalysis/Photocatalysis)
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