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Catalysts, Volume 14, Issue 7

2024 July - 75 articles

Cover Story: ERI and SSZ-13 were subjected to post-synthetic treatments (depending on the zeolite topology) to create micro/mesoporous materials. The post-synthetic modification of the investigated zeolites varied their catalytic activity in the selective catalytic reduction of NO with ammonia (NH3-SCR-DeNOx). Regarding the Cu-containing ERI, the NO conversion was higher for catalysts with modified supports. For the Cu-containing SSZ-13 catalysts (with post-modified zeolites), a lower NO conversion in NH3-SCR-DeNOx was observed. According to the physico-chemical characterization, the modification of the supports resulted in the presence of different amounts and kinds of copper species (especially isolated Cu2+ and aggregated Cu species) of ERI- and SSZ-13-based samples. View this paper
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Articles (75)

  • Communication
  • Open Access
4 Citations
2,728 Views
16 Pages

22 July 2024

The mechanism of the electrochemical CO2 reduction reaction on a Cu(110) surface has yet to be fully revealed. In this work, based on first-principles calculations, we investigate the mechanisms of the CO2 reduction reaction to produce C1 (including...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,062 Views
9 Pages

Synthesis of Propiolic and Butynedioic Acids via Carboxylation of CaC2 by CO2 under Mild Conditions

  • Xiao-Min Zhao,
  • Xiaoteng Zang,
  • Yingzhou Lu,
  • Hong Meng and
  • Chunxi Li

22 July 2024

Carbon dioxide (CO2) is a greenhouse gas, and its resource use is vital for carbon reduction and neutrality. Herein, the nucleophilic addition reaction of calcium carbide (CaC2) to CO2 was studied for the first time to synthesize propiolic and butyne...

  • Article
  • Open Access
9 Citations
2,754 Views
14 Pages

One-Pot Phyto-Mediated Synthesis of Fe2O3/Fe3O4 Binary Mixed Nanocomposite Efficiently Applied in Wastewater Remediation by Photo-Fenton Reaction

  • Amr A. Essawy,
  • Tamer H. A. Hasanin,
  • Modather. F. Hussein,
  • Emam F. El Agammy and
  • Abd El-Naby I. Essawy

20 July 2024

A binary Fe2O3/Fe3O4 mixed nanocomposite was prepared by phyto-mediated avenue to be suited in the photo-Fenton photodegradation of methylene blue (MB) in the presence of H2O2. XRD and SEM analyses illustrated that Fe2O3 nanoparticles of average crys...

  • Feature Paper
  • Article
  • Open Access
5 Citations
1,623 Views
16 Pages

Effect of Support Functionalization on Catalytic Direct Hydrogenation and Catalytic Transfer Hydrogenation of Muconic Acid to Adipic Acid

  • Elisa Zanella,
  • Stefano Franchi,
  • Narmin Jabbarli,
  • Ilaria Barlocco,
  • Marta Stucchi and
  • Carlo Pirola

19 July 2024

The liquid-phase hydrogenation of muconic acid (MA) to produce bio-adipic acid (AdA) is a prominent environmentally friendly chemical process, that can be achieved through two distinct methodologies: catalytic direct hydrogenation using molecular hyd...

  • Article
  • Open Access
1 Citations
1,368 Views
15 Pages

19 July 2024

In this study, Ag-AgCl/attapulgite (Ag-AgCl/ATP) composites were synthesized via a direct precipitation method using ATP nanorods as a catalyst supporter. ATP nanorods helped to increase the dispersion of Ag-AgCl particles and broaden the light absor...

  • Article
  • Open Access
1 Citations
1,963 Views
15 Pages

α-Alkylation of Aliphatic Ketones with Alcohols: Base Type as an Influential Descriptor

  • Rasika Mane,
  • Li Hui,
  • Ander Centeno-Pedrazo,
  • Alexandre Goguet,
  • Nancy Artioli and
  • Haresh Manyar

19 July 2024

Current global challenges associated with energy security and climate emergency, caused by the combustion of fossil fuels (e.g., jet fuel and diesel), necessitate the accelerated development and deployment of sustainable fuels derived from renewable...

  • Review
  • Open Access
8 Citations
2,710 Views
17 Pages

Mn-Based Catalysts in the Selective Reduction of NOx with CO: Current Status, Existing Challenges, and Future Perspectives

  • Dianxing Lian,
  • Mohaoyang Chen,
  • Huanli Wang,
  • Chenxi Li,
  • Botao Liu,
  • Guiyao Dai,
  • Shujun Hou,
  • Yuxi Liu and
  • Yongjun Ji

18 July 2024

The technology for the selective catalytic reduction of NOx by CO (CO-SCR) has the capability to simultaneously eliminate CO and NOx from industrial flue gas and automobile exhaust, thus making it a promising denitrification method. The advancement o...

  • Article
  • Open Access
4 Citations
2,531 Views
7 Pages

Methanol to Aromatics on Hybrid Structure Zeolite Catalysts

  • Maria V. Magomedova,
  • Ekaterina G. Galanova,
  • Anastasia V. Starozhitskaya,
  • Mikhail I. Afokin,
  • David V. Matevosyan,
  • Sergey V. Egazaryants,
  • Dmitry E. Tsaplin and
  • Anton L. Maximov

18 July 2024

A study on the reaction of methanol to aromatic hydrocarbons using catalysts based on hybrid zeolites MFI-MEL, MFI-MTW, and MFI-MCM-41 at a temperature of 340 °C and a pressure of 10.0 MPa was carried out. It is shown that in the synthesis of hyd...

  • Review
  • Open Access
6 Citations
4,686 Views
19 Pages

16 July 2024

This investigation confirms that the existence of the hydrogen spillover effect (HSPE) in the case of metal catalysts supported on non-reducible monoxides or zeolites is based on a strong corpus of experimental studies, enlarging and deepening previo...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,486 Views
19 Pages

Post-Synthetically Treated ERI and SSZ-13 Zeolites Modified with Copper as Catalysts for NH3-SCR-DeNOx

  • Alejandro Mollá Robles,
  • Gabriele Deplano,
  • Kinga Góra-Marek,
  • Marek Rotko,
  • Anna Wach,
  • Muhammad Fernadi Lukman,
  • Marko Bertmer,
  • Matteo Signorile,
  • Silvia Bordiga and
  • Magdalena Jabłońska
  • + 2 authors

16 July 2024

ERI and SSZ-13 were subjected to post-synthetic treatments (depending on the zeolite topology) to create micro-/mesoporous materials. The results in terms of NH3-SCR-DeNOx show that the applied treatments improved the catalytic activity of the Cu-con...

  • Article
  • Open Access
7 Citations
2,422 Views
13 Pages

16 July 2024

Catalytic conversion of CO2 to CO via the reverse water gas shift (RWGS) reaction has been identified as a promising approach for CO2 utilization and mitigation of CO2 emissions. Bare Pt shows low activity for the RWGS reaction due to its low oxophil...

  • Article
  • Open Access
7 Citations
1,758 Views
17 Pages

Benefit of LDH-Derived Mixed Oxides for the Co-Oxidation of Toluene and CO Exhausted from Biomass Combustion

  • Caroline Paris,
  • Hadi Dib,
  • Charf Eddine Bounoukta,
  • Eric Genty,
  • Christophe Poupin,
  • Stéphane Siffert and
  • Renaud Cousin

16 July 2024

The proposed study is devoted to highlighting the importance of mixed oxides preparation through the layered double hydroxide route for undesirable gas pollutants abatement. Different series of Cu/Al/Ce mixed oxides with similar or different stoichio...

  • Article
  • Open Access
9 Citations
2,364 Views
16 Pages

Electrocatalytic Hydrogen Evolution Reaction of Cobalt Triaryl Corrole Bearing Nitro Group

  • Jie Zeng,
  • Xu-You Cao,
  • Shi-Yin Xu,
  • Yi-Feng Qiu,
  • Jun-Ying Chen,
  • Li-Ping Si and
  • Hai-Yang Liu

15 July 2024

The use of non–precious metals for electrocatalytic hydrogen reaction (HER) is particularly important for energy conservation and environmental protection. In this work, three new cobalt corroles containing o−, m−, and p−nitro...

  • Feature Paper
  • Article
  • Open Access
5 Citations
2,412 Views
17 Pages

14 July 2024

With the abuse of antibiotics, its pollution poses an increasing threat to the environment and human health. Effective degradation of organic pollutants in water bodies is urgent. Compared to traditional treatment methods, advanced oxidation processe...

  • Review
  • Open Access
17 Citations
9,564 Views
27 Pages

14 July 2024

The significance and challenges of hydrotreatment processes for vegetable oils have recently become apparent, encompassing various reactions like decarbonylation, decarboxylation, and hydrogenation. Heterogeneous noble or transition metal catalysts p...

  • Review
  • Open Access
7 Citations
2,739 Views
20 Pages

14 July 2024

The efficient detection of lead ions (Pb2⁺) is significant for environmental protection and public health. Electrochemical detection has emerged as one of the most promising technologies due to its low detection limits, high sensitivity, and co...

  • Review
  • Open Access
12 Citations
4,731 Views
48 Pages

12 July 2024

The extensive use of plastics has led to a significant environmental threat due to the generation of waste plastic, which has shown significant challenges during recycling. The catalytic hydrocracking route, however, is viewed as a key strategy to ma...

  • Article
  • Open Access
9 Citations
1,874 Views
22 Pages

Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13

  • Muhammad Usman,
  • Muhammad Babar Taj,
  • Afaf Almasoudi,
  • Doaa F. Baamer,
  • Omar Makram Ali,
  • Muhammad Imran Khan,
  • Ismat Bibi,
  • Mobeen Ur Rehman,
  • Rabia Rasheed and
  • Javier Fernandez-Garcia
  • + 3 authors

12 July 2024

Water pollution has become a great challenge today. To address this problem regarding wastewater treatment by removing toxic synthetic dyes from wastewater, this research focused on the synthesis of a novel starch-modified NiCrMn-layered double hydro...

  • Article
  • Open Access
3 Citations
1,741 Views
19 Pages

12 July 2024

This study aimed to explore the impact of varying amounts of added Au (0.5 to 2 wt.%) and the structural characteristics of anatase TiO2 supports (nanoparticles (TP, SBET = 88 m2/g) and nanorods (TR, SBET = 105 m2/g)) on the catalytic efficiency of T...

  • Feature Paper
  • Review
  • Open Access
14 Citations
5,596 Views
36 Pages

12 July 2024

This comprehensive review covers recent advancements in utilizing various types of polymers and their modifications as photocatalysts for the removal of pharmaceutical contaminants from water. It also considers polymers that enhance the photocatalyti...

  • Article
  • Open Access
5 Citations
2,681 Views
19 Pages

12 July 2024

A novel alkaline serine protease, derived from the Staphylococcus aureus strain ALA1 previously isolated from dromedary milk, was subjected to purification and characterization. Optimal protease production occurred under specific culture conditions....

  • Article
  • Open Access
3 Citations
2,074 Views
12 Pages

Mixed Oxides as Catalysts for the Condensation of Cyclohexanol and Benzaldehyde to Obtain a Claisen–Schmidt Condensation Product

  • Tanya Stoylkova,
  • Tsveta Stanimirova,
  • Christo D. Chanev,
  • Petya Petrova and
  • Kristina Metodieva

11 July 2024

Acid–base M2+MgAlO and M2+AlO mixed oxides (where M2+ = Mg, Cu, Co, Zn, and Ni) were obtained by thermal decomposition of the corresponding layered double hydroxide (LDH) precursors and used as catalysts for cyclohexanol and benzaldehyde conden...

  • Article
  • Open Access
2 Citations
1,931 Views
16 Pages

11 July 2024

This study presents a series of Cu-Mn/Al2O3 catalysts prepared by the polyol method to improve the toluene combustion process. The catalytic activity evaluation results showed that the different polyols have a great influence on catalyst activity, in...

  • Article
  • Open Access
5 Citations
2,878 Views
15 Pages

10 July 2024

The formation of heterojunctions for efficient charge separation has been practiced for the preparation of efficient semiconductor-based photocatalysts for applications such as hydrogen production and environmental remediation. In this study, we synt...

  • Article
  • Open Access
1 Citations
1,697 Views
11 Pages

Tuning a Cr-Catalyzed Ethylene Oligomerization Product Profile via a Rational Design of the N-aryl PNP Ligands

  • Samir Barman,
  • E. A. Jaseer,
  • Nestor Garcia,
  • Mohamed Elanany,
  • Motaz Khawaji,
  • Niladri Maity and
  • Abdulrahman Musa

10 July 2024

An approach towards incorporating varied degrees of steric profiles around the ligand’s backbone, which were envisaged to alter the catalytic paths leading to targeted 1-C8/1-C6 olefin products, were explored. Cr-pre-catalysts designed with PNP...

  • Article
  • Open Access
3 Citations
2,714 Views
11 Pages

9 July 2024

In 2022, Beller and coworkers achieved the reversible hydrogenation of CO2 to formic acid using a Mn(I)–PN5P complex with excellent activity and reusability of the catalyst. To understand the detailed mechanism for the reversible hydrogen relea...

  • Article
  • Open Access
2,217 Views
12 Pages

Autocatalyzed Kinetics of 6-Electron Electroreduction of Iodic Acid Studied by Rotating Disk Electrode Technique

  • Liliya Antipova,
  • Oleg Tripachev,
  • Alexandra Rybakova,
  • Vladimir Andreev,
  • Roman Pichugov,
  • George Sudarev,
  • Anatoly Antipov and
  • Alexander Modestov

9 July 2024

The 6-electron electrochemical reduction of IO3 to I represents a breakthrough for the development of next-generation redox flow batteries, offering substantially higher energy densities for oxidizer storage. Our study reveals that on a...

  • Article
  • Open Access
3 Citations
2,205 Views
13 Pages

La-Modified SBA-15 Prepared by Direct Synthesis: Importance of Determining Actual Composition

  • Gloribel Morales Hernández,
  • José Escobar,
  • José G. Pacheco Sosa,
  • Mario A. Guzmán Cruz,
  • José G. Torres Torres,
  • Paz del Ángel Vicente,
  • María C. Barrera,
  • Carlos E. Santolalla Vargas and
  • Hermicenda Pérez Vidal

8 July 2024

Lanthanum (La) integration (at various nominal contents) in SBA-15 prepared under acidic medium was intended from corresponding direct nitrate addition during mesoporous silica formation. Materials were impregnated with Pt (1.5 wt%) and studied throu...

  • Feature Paper
  • Article
  • Open Access
1 Citations
1,841 Views
27 Pages

Effect of TiO2 on Acidity and Dispersion of H3PW12O40 in Bifunctional Cu-ZnO(Al)-H3PW12O40/TiO2 Catalysts for Direct Dimethyl Ether Synthesis

  • Elena Millán Ordóñez,
  • Noelia Mota Toledo,
  • Bertrand Revel,
  • Olivier Lafon and
  • Rufino M. Navarro Yerga

8 July 2024

The performance of bifunctional hybrid catalysts based on phosphotungstic acid (H3PW12O40, HPW) supported on TiO2 combined with a Cu-ZnO(Al) catalyst in the direct synthesis of dimethyl ether (DME) from syngas has been investigated. In this work, dif...

  • Feature Paper
  • Article
  • Open Access
4 Citations
2,571 Views
18 Pages

Photocatalytic Degradation of Losartan with BiOCl/Sepiolite Nanocomposites

  • Konstantinos Kouvelis,
  • Evangelia E. Karavaka,
  • Dionisios Panagiotaras,
  • Dimitrios Papoulis,
  • Zacharias Frontistis and
  • Athanasia Petala

7 July 2024

Developing highly active and available, environmentally friendly, and low-cost photocatalytic materials is one of the most popular topics in photocatalytic degradation systems. In the present study, a series of BiOCl/Sepiolite composite photocatalyst...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,032 Views
18 Pages

7 July 2024

The fluidization of two different solids was investigated by varying the temperature and pressure conditions and the fluidizing gas. The solids are a novel catalyst and a water sorbent that could be used to perform sorption-enhanced methanol synthesi...

  • Article
  • Open Access
1 Citations
1,799 Views
15 Pages

6 July 2024

The interaction between point defects in (La1−xCax)MnO3−δ (x = 0, 0.2, 0.3, 0.4) perovskites and their redox catalytic properties in a three-reactor chemical looping hydrogen production process is investigated. During the reduction...

  • Article
  • Open Access
29 Citations
3,098 Views
16 Pages

Copper- and Manganese-Based Bimetallic Layered Double Hydroxides for Catalytic Reduction of Methylene Blue

  • Muhammad Altaf Nazir,
  • Aziz ur Rehman,
  • Tayyaba Najam,
  • Mohamed Farouk Elsadek,
  • M. Ajmal Ali,
  • Ismail Hossain,
  • Muhammad Khurram Tufail and
  • Syed Shoaib Ahmad Shah

5 July 2024

In this study, copper (Cu)- and manganese (Mn)-based layered double hydroxide (LDH) nanosheets were produced by modest and low-cost hydrothermal technique to display an improved photocatalytic performance toward the degradation of aqueous methylene b...

  • Review
  • Open Access
8 Citations
7,763 Views
18 Pages

Photocatalytic Production of Hydrogen Peroxide from Covalent-Organic-Framework-Based Materials: A Mini-Review

  • Jiayi Meng,
  • Yamei Huang,
  • Xinglin Wang,
  • Yifan Liao,
  • Huihui Zhang and
  • Weilin Dai

5 July 2024

Hydrogen peroxide (H2O2) is one of the most environmentally friendly and versatile chemical oxidizing agents, with only O2 and H2O as reaction products. It is widely used in environmental protection, industrial production, and medical fields. At pres...

  • Article
  • Open Access
3 Citations
1,958 Views
11 Pages

5 July 2024

Tetrahydrofurfuryl alcohol, a cost-effective biomass derivative, offers a sustainable path for synthesizing 1,5-pentanediol through hydrogenolysis. To develop the efficient production of 1,5-pentanediol from this alcohol, we have prepared a series of...

  • Article
  • Open Access
10 Citations
3,072 Views
23 Pages

Investigating the Potential of Green-Fabricated Zinc Oxide Nanoparticles to Inhibit the Foodborne Pathogenic Bacteria Isolated from Spoiled Fruits

  • Amr Fouda,
  • Mohammed Ali Abdel-Rahman,
  • Ahmed M. Eid,
  • Samy Selim,
  • Hasan Ejaz,
  • Muharib Alruwaili,
  • Emad Manni,
  • Mohammed S. Almuhayawi,
  • Soad K. Al Jaouni and
  • Saad El-Din Hassan

4 July 2024

In the current investigation, the antibacterial activity of zinc oxide nanoparticles (ZnO-NPs) formed by an aqueous extract of Psidium guajava leaves against foodborne pathogenic bacterial strains was investigated. To achieve this goal, 33 bacte...

  • Article
  • Open Access
4 Citations
2,978 Views
15 Pages

4 July 2024

Following the goals of the circular economy, this work demonstrates that an industrial by-product can be used in environmental remediation. Metallurgical slag and citric acid were used to form an Fe:Cit complex by simultaneously carrying out the lixi...

  • Article
  • Open Access
1 Citations
1,596 Views
22 Pages

Patterns of Formation of Binary Cobalt–Magnesium Oxide Combustion Catalysts of Various Composition

  • Bolatbek Khussain,
  • Alexandr Sass,
  • Alexandr Brodskiy,
  • Kenzhegul Rakhmetova,
  • Ivan Torlopov,
  • Magira Zhylkybek,
  • Tolkyn Baizhumanova,
  • Svetlana Tungatarova,
  • Atabek Khussain and
  • Yernar Narimanov
  • + 4 authors

3 July 2024

In order to establish the formation patterns of the Co–Mg oxide system, samples with different Co:Mg ratios and heat treatment temperatures were synthesized and studied. A study of the samples confirmed the phase transition of MgxCo2–xO4...

  • Article
  • Open Access
16 Citations
2,890 Views
15 Pages

3 July 2024

Catalytic dechlorination of organic chlorides by palladium (Pd) with HCOOH represents one of the most effective and promising techniques for environmental remediation. In this study, we adopted alkaline-modified porous natural sponge as support of a...

  • Article
  • Open Access
6 Citations
2,851 Views
13 Pages

2 July 2024

The perpetually fluctuating economic and environmental climate significantly increases the demand for alternative fuel sources. The utilization of hydrogen gas is a viable option for such a fuel source. Hydrogen is one of the most energy-dense known...

  • Article
  • Open Access
4 Citations
1,932 Views
19 Pages

Development of a γ-Al2O3-Based Heterogeneous Fenton-like Catalyst and Its Application in the Advanced Treatment of Maotai-Flavored Baijiu Wastewater

  • Benfu Luo,
  • Yujing Yan,
  • Jinyin Li,
  • Fei Guo,
  • Weiwei Huang,
  • Xi Yang,
  • Haiyan Ning,
  • Qicheng Kang,
  • Haixing He and
  • Yuhang Liu
  • + 3 authors

1 July 2024

Heterogeneous Fenton technology was employed for the advanced treatment of Maotai-flavored Baijiu wastewater. Novel catalysts were prepared by loading different active ingredients (Mn, Fe, and Cu) on γ-Al2O3 using an impregnation method. The ef...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,332 Views
12 Pages

30 June 2024

Hydrogen peroxide (H2O2) is an important chemical with a diverse range of industrial applications in chemical synthesis and medical disinfection. The traditional anthraquinone oxidation process, with high energy consumption and complexity, is being r...

  • Review
  • Open Access
69 Citations
9,003 Views
36 Pages

Photocatalytic Activity of Metal- and Non-Metal-Anchored ZnO and TiO2 Nanocatalysts for Advanced Photocatalysis: Comparative Study

  • Hamad AlMohamadi,
  • Sameer A. Awad,
  • Ashwani Kumar Sharma,
  • Normurot Fayzullaev,
  • Arístides Távara-Aponte,
  • Lincoln Chiguala-Contreras,
  • Abdelfattah Amari,
  • Carlos Rodriguez-Benites,
  • Mohamed A. Tahoon and
  • Hossein Esmaeili

30 June 2024

This review article provides useful information on TiO2 and ZnO photocatalysts and their derivatives in removing organic contaminants such as dyes, hydrocarbons, pesticides, etc. Also, the reaction mechanisms of TiO2 and ZnO photocatalysts and their...

  • Article
  • Open Access
13 Citations
2,727 Views
22 Pages

Photocatalytic, Antimicrobial, and Cytotoxic Efficacy of Biogenic Silver Nanoparticles Fabricated by Bacillus amyloliquefaciens

  • Ahmed M. Eid,
  • Saad El-Din Hassan,
  • Mohammed F. Hamza,
  • Samy Selim,
  • Mohammed S. Almuhayawi,
  • Mohammed H. Alruhaili,
  • Muyassar K. Tarabulsi,
  • Mohammed K. Nagshabandi and
  • Amr Fouda

30 June 2024

The biomass filtrate of the endophytic bacterial strain Bacillus amyloliquefaciens Fa.2 was utilized for the eco-friendly production of silver nanoparticles (Ag-NPs). The yellowish-brown color’s optical properties showed a maximum surface plasm...

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Catalysts - ISSN 2073-4344