Advanced Alloy Degradation and Implants, 2nd Edition

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Coatings for Biomedicine and Bioengineering".

Deadline for manuscript submissions: 10 February 2025 | Viewed by 1806

Special Issue Editors


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Guest Editor
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
Interests: biomaterials; biomedical magnesium alloy; metallic implants; surface modification for biomaterials
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
School of Materials and Chemical Engineering, Zhongyuan University of Technology, Zhengzhou 450007, China
Interests: biomaterials; biomaterials magnesium alloy; metallic implants; surface modification for biomaterials; first-principles calculation; molecular dynamics simulation

Special Issue Information

Dear Colleagues,

Metals and their alloys are some of the oldest biomedical materials in human history and continue to play an irreplaceable role in modern clinical treatment due to their excellent mechanical load-bearing properties, chemical stability, and biocompatibility. In recent years, the R&D and design of metal implants and devices; the further exploration of their powerful functions; and the in-depth exploration of their interaction with the body’s microenvironment have progressed significantly. In particular, the design of biodegradable alloys; the elaboration of their degradation mechanisms in different environments; research on their degradation behavior and degradation products; and the prospect of their advanced exclusive coating have attracted the attention of scholars.

Previously, we published the Special Issue “https://www.mdpi.com/journal/coatings/special_issues/Degradation_Implants” online. This Special Issue has now closed and achieved great success. Building on this collaboration, we are keen to launch a second volume of the existing Special Issue, “Advanced Alloy Degradation and Implants, 2nd Edition”, the aim of which is to publish full-length research articles, short communications, and review articles covering the latest studies, progress, and challenges in the design, fabrication, degradation, and surface modification of metal alloy implants for their future biomedical applications.

Topics addressed in this Special Issue may include, but are not limited to, the following:

  1. The design, fabrication, and characterization of new alloy implants and devices;
  2. Coatings of metallic implants or biomaterials;
  3. Biomedical alloy degradation;
  4. Computational modeling and numerical simulation of alloy implants and their surfaces;
  5. Composite materials composed of metals and other materials;
  6. The interactions between alloy implants and cells.

Prof. Dr. Jing'an Li
Dr. Zhe Fang
Guest Editors

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Keywords

  • biomaterials
  • alloys
  • coatings
  • degradation
  • surface
  • interface
  • biocompatibility

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Published Papers (2 papers)

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Research

15 pages, 20333 KiB  
Article
Elastoplastic and Electrochemical Characterization of xTiB2 Strengthened Ti Porous Composites for Their Potential Biomedical Applications
by David Israel Bravo-Bárcenas, Reynier Suárez-Martínez, Jonatan Pérez-Alvarez, Omar Jiménez-Alemán, Iván Gerardo Farias-Velazquez, Marco Aurelio Gonzaléz-Albarrán and Jorge Chávez
Coatings 2024, 14(8), 991; https://doi.org/10.3390/coatings14080991 - 6 Aug 2024
Viewed by 575
Abstract
The microstructure, elastoplastic properties, and corrosive response of induced porous Ti-TiH2 materials reinforced with TiB2 particles were investigated. Samples were fabricated using CP-Ti Grade1, Titanium Hydride (TiH2), TiB2 powders (0, 3, 10, and 30 vol.%), and ammonium bicarbonate [...] Read more.
The microstructure, elastoplastic properties, and corrosive response of induced porous Ti-TiH2 materials reinforced with TiB2 particles were investigated. Samples were fabricated using CP-Ti Grade1, Titanium Hydride (TiH2), TiB2 powders (0, 3, 10, and 30 vol.%), and ammonium bicarbonate salt (40 vol.%) as a space holder. Composites were fabricated using the Powder Metallurgy technique under high-vacuum conditions (HVS) at 1100 °C. Scanning electron microscopy, X-ray diffraction, nanoindentation tests, and electrochemical assays were used to investigate the pore formation, pore distribution, phase formation, elastoplastic properties, and electrochemical behavior of the compounds, respectively. With a mean pore diameter of 50–900 µm and Young’s modulus of less than 100 GPa, which is close to the properties of human bone, the pore structures of the compounds processed here are shown to be a potential biomaterial for osseointegration. In addition, their H/Er and H3/Er2 ratios for the reinforced samples are higher than those of the unreinforced sample (1.5 and 4 times higher than the unreinforced sample, respectively), suggesting a better wear resistance of the Ti-TiH2/xTiB2 composites. Electrochemical experiments demonstrated that the Ti-TiH2/xTiB2 composites exhibited superior passivation properties compared to the Ti-TiH2 sample. Additionally, the corrosion rates exhibited by the 3 and 10 vol.% of TiB2 samples were found to be within an acceptable range for potential biomedical applications (29.26 and 185.82 E-3 mm·y−1). The elastoplastic properties combined with the electrochemical behavior place the Ti-TiH2/3-10TiB2 composites as potential candidates for the biomedical application of CP-Ti. Full article
(This article belongs to the Special Issue Advanced Alloy Degradation and Implants, 2nd Edition)
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9 pages, 717 KiB  
Article
Activity of Fluoride Varnishes Containing Micrometric or Nanosized Sodium Trimetaphosphate against Early Enamel Erosive Lesions In Vitro
by Liliana Carolina Báez-Quintero, Juliano Pelim Pessan, Mariana Emi Nagata, Luigi Pedrini Guisso, Alberto Carlos Botazzo Delbem, Daniela Rios, Caio Sampaio and Thayse Yumi Hosida
Coatings 2024, 14(7), 855; https://doi.org/10.3390/coatings14070855 - 8 Jul 2024
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Abstract
This study aimed to assess the effects of fluoridated varnishes supplemented with micrometric or nanosized sodium trimetaphosphate (TMPmicro or TMPnano, respectively) against enamel softening in an early erosive model in vitro. Bovine enamel blocks (with mean surface hardness [SH] between 330.0 and [...] Read more.
This study aimed to assess the effects of fluoridated varnishes supplemented with micrometric or nanosized sodium trimetaphosphate (TMPmicro or TMPnano, respectively) against enamel softening in an early erosive model in vitro. Bovine enamel blocks (with mean surface hardness [SH] between 330.0 and 380.0 kgf/mm2) were selected and randomly assigned according to their SH (n = 8) into the following groups: Placebo (no fluoride/TMP; negative control), 5% NaF (positive control), 5% NaF + 5%TMPmicro, 5% NaF + 2.5%TMPnano and 5% NaF + 5%TMPnano. Blocks received a single application of the varnishes and were immersed in artificial saliva (6 h). Thereafter, the varnishes were removed and the blocks were subjected to four individual erosive challenges (1 min, citric acid, 0.75%, pH = 3.5, under agitation); SH was determined after each challenge. Data were subjected to ANOVA and Student–Newman–Keuls’ test (p < 0.05). Overall, the highest %SH loss was observed for the Placebo, followed by 5% NaF, 5% NaF + 5% TMPmicro, and both varnishes containing TMPnano, without significant differences between 2.5% and 5% TMPnano. It was concluded that TMP enhanced the effects of a 5% NaF varnish against enamel softening in an early erosive model in vitro, with an additional benefit from the use of nanoparticles over microparticles. Full article
(This article belongs to the Special Issue Advanced Alloy Degradation and Implants, 2nd Edition)
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